• Title/Summary/Keyword: Low-dimensional materials

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Frictional Properties of Two-dimensional Materials against Spherical and Flat AFM Tips (구형 및 평면 원자현미경 탐침에 대한 2차원 소재의 마찰 특성)

  • Tran-Khac, Bien-Cuong;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.35 no.4
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    • pp.199-205
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    • 2019
  • Two-dimensional materials such as graphene, h-BN, and $MoS_2$ have attracted increased interest as solid lubricant and protective coating layer for nanoscale devices owing to their superior mechanical properties and low friction characteristics. In this work, the frictional properties of single-layer graphene, h-BN, and $MoS_2$ are experimentally investigated under various normal forces using atomic force microscope (AFM) tips with a spherical and flat end, with the aim to gain a better understanding of frictional behaviors. The nonlinear relationship between friction and normal force friction was clearly observed for single-layer graphene, h-BN, $MoS_2$ specimens slid against the spherical and flat AFM tips. The results also indicate that single-layer graphene, h-BN, $MoS_2$ exhibit low frictional properties (e.g., friction coefficient below 0.1 under 70~100 nN normal force). In particular, graphene is found to be superior to h-BN and $MoS_2$ in terms of frictional properties. However, the friction of single-layer graphene, h-BN, $MoS_2$ against the flat tip is larger than that against the spherical tip, which may be attributed to the relatively large adhesion. Furthermore, it is shown that the fluctuation of friction is more significant for the flat tip than the spherical tip. The resutls of this study may be helpful to elucidate the feasibility of using two-dimensional materials as solid lubricant and protective coating layer for nanoscale devices.

Josephson effect of the superconducting van der Waals junction

  • Park, Sungyu;Kwon, Chang Il;Kim, Jun Sung
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.6-9
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    • 2021
  • Heterostructures fabricated by various combinations of van der Waals (vdW) materials enable us to investigate disorder-free physical properties and realize novel functional devices. Superconducting vdW junctions have attracted a lot of attention because of its simple structure without a barrier layer. In superconducting vdW junction, without extra fabrication effort, a natural barrier can be formed, whose character is sensitive to distance and angle of lattice between two superconducting vdW materials. Using high-quality single crystals and the dry transfer technique, we fabricated the vertically stacked NbSe2/NbSe2 and FeSe/FeSe vdW junctions and investigated their Josephson junction properties. We found that in the FeSe junctions, Josephson coupling is extremely sensitive to the fabrication conditions, in contrast to the NbSe2 junctions. We attributed this distinct character of the FeSe junctions to surface instability and small Fermi surface of FeSe.

Solution-based Synthesis of Two-dimensional Materials for Electrochemical Capacitors (전기화학 커패시터 응용을 위한 용액기반의 2차원 소재 제조)

  • Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.272-278
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    • 2017
  • Two-dimensional (2D) materials, especially graphene and $MoS_2$ sheets, have gained much attention and shown great promise for the application in supercapacitors. To widely use the 2D materials for supercapacitors, highly efficient, low cost, and environmentally friendly synthetic methods for the preparation of 2D materials should be developed. Here, we will review recently developed solution-based processes for preparing 2D materials for supercapacitors. Chemical exfoliation-reduction, chemical intercalation, and liquid phase exfoliation methods will be introduced. Moreover, the electrochemical characteristics of graphene and $MoS_2$-based electrodes for supercapacitors are summarized. In addition to solution-based processes, other challenges and opportunities are discussed in terms of controlling nanosheet compositions, sizes, and thicknesses.

Fabrication of 2-Dimensional ZnO Nanowall Structure (2차원 ZnO 나노벽 구조 제조)

  • Kim, Young-Jung;Cao, Guozhong;Kim, Yeong-Cheol;Ahn, Seung-Joon;Min, Joon-Won
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.521-524
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    • 2005
  • ZnO 2-D nanowall structure with around 100 nm thickness, which is composed of tens of nm scale ZnO single crystals, was fabricated through the low temperature chemical solution growth method. Electro Chemical Deposition (ECD) technique was applied to attach the ZnO seed crystals on ITO coated glass substrate. The ZnO nanowall structure was grown in the 0.015 mol$\%$ of aqueous solution of zinc nitrate and hexamethenamine at 60$^{\circ}C$ for 20 - 40 h. The nanowall structure depends on the ECD condition or the applied voltage and duration time. The nanowall shows a photoluminescence around 550 - 700 nm spectrum range.

Complex Chalcogenides as Thermoelectric Materials: A Solid State Chemistry Approach

  • 정덕영;Lykourgos Iordanidis;최경신;Mercouri G. Kanatzidis
    • Bulletin of the Korean Chemical Society
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    • v.19 no.12
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    • pp.1283-1293
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    • 1998
  • A solid state chemical approach to discover new mateials with enhanced thermoelectric properties is described. The aim is to construct three-dimensional bismuth chalcogenide framework structures which contain tonically interacting alkali or alkaline earth atoms. The alkali atoms tend to have soft "rattling" type phonon modes which result in very low thermal conductivity in these materials. Another desirable feature in this class of compounds is the low crystal symmetry and narrow band-gaps. Several promising materials such as BaBiTe3, KBi6.33S10, K2Bi8S13, β-K2Bi8Se13, K2.5Bi8.5Se14, Ba4Bi6Se13, Eu2Pb2Bi6Se13, Al1+xPb4-2xSb7+xSe15 (A=K, Rb), and CsBi4Te6 are described.

Lasing Characteristics of Dye-Doped Cholesteric Liquid Crystal

  • Porov, Preeti;Chandel, Vishal Singh;Manohar, Rajiv
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.117-123
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    • 2015
  • Cholesteric liquid crystals are one dimensional photonic band-gap materials due to their birefringence and periodic structure. Dye doped cholesteric liquid crystals are self-assembling, mirror-less, low threshold laser structures that exhibit distributed feedback. In this review paper, we have presented the development in the field of lasing characteristics of dye doped cholesteric liquid crystals.

Research Trends in Electromagnetic Shielding using MXene-based Composite Materials

  • Siyeon Kim;Jongmin Byun
    • Journal of Powder Materials
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    • v.31 no.1
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    • pp.57-76
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    • 2024
  • Recent advancements in electronic devices and wireless communication technologies, particularly the rise of 5G, have raised concerns about the escalating electromagnetic pollution and its potential adverse impacts on human health and electronics. As a result, the demand for effective electromagnetic interference (EMI) shielding materials has grown significantly. Traditional materials face limitations in providing optimal solutions owing to inadequacy and low performance due to small thickness. MXene-based composite materials have emerged as promising candidates in this context owing to their exceptional electrical properties, high conductivity, and superior EMI shielding efficiency across a broad frequency range. This review examines the recent developments and advantages of MXene-based composite materials in EMI shielding applications, emphasizing their potential to address the challenges posed by electromagnetic pollution and to foster advancements in modern electronics systems and vital technologies.

Fabrication and characterization of polymer-based carbon nanomaterial composites for thermal conductive adhesive application (열전도성 점착제 응용을 위한 고분자 기반 탄소나노소재 복합체 제조 및 특성 평가)

  • Lee, Byeong-Joo;Jo, Sung-Il;Yoon, Eun-Hye;Lee, Ae-Ri;Lee, Woo-Young;Heo, Sung-Gyu;Hwang, Jae-Sung;Jeong, Goo-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.160-168
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    • 2020
  • A polymer-based carbon nanomaterial composite was fabricated and characterized for the application of a thermal conductive adhesive. Low-dimensional carbon nanomaterials with excellent thermal conductivity such as carbon nanotube (CNT) and graphene were selected as a filler in the composite. Thermal, electrical and adhesive properties of the composite were investigated with respect to the morphology and content of the low-dimensional carbon nanomaterials. As a result, the composite-based adhesive fabricated by the loading of surface-treated MWCNTs of 0.4 wt% showed uniform dispersion, moderate adhesion and effective heat dissipation properties. Finally, it was confirmed through the thermal image analysis of LED module that the temperature reduction of 10℃ was achieved using the fabricated composite adhesive with MWCNT-6A. Expecially, heat dissipation performance of the optimized composite adhesive was evident at the hot spot in the module compared to other samples mixed with graphene or different MWCNT loading ratios.

Evaluation of Carbon Fiber distribution in Unidirectional CF/Al Composites by Two-Dimensional Spatial Distribution Method

  • Lee, Moonhee;Kim, Sungwon;Lee, Jongho;Hwang, SeungKuk;Lee, Sangpill;Sugio, Kenjiro;Sasaki, Gen
    • Journal of the Korean Society of Industry Convergence
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    • v.21 no.1
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    • pp.29-36
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    • 2018
  • Low pressure casting process for unidirectional carbon fiber reinforced aluminum (UD-CF/Al) composites which is an infiltration route of molten Al into porous UD-CF preform has been a cost-effective way to obtain metal matrix composites (MMCs) but, easy to cause non-uniform fiber distribution as CF clustering. Such clustered CFs have been a problem to decrease the density and thermal conductivity (TC) of composites, due to the existence of pores in the clustered area. To obtain high thermal performance composites for heat-sink application, the relationship between fiber distribution and porosity has to be clearly investigated. In this study, the CF distribution was evaluated with quantification approach by using two-dimensional spatial distribution method as local number 2-dimension (LN2D) analysis. Note that the CFs distribution in composites sensitively changed by sizes of Cu bridging particles between the CFs added in the UD-CF preform fabrication stage, and influenced on only $LN2D_{var}$ values.