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The Study on the High Nocturnal Concentration of Ground Level Ozone (야간 지표 고농도 오존에 관한 연구)

  • 김유근;홍정혜
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.545-554
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    • 1998
  • The diurnal variation of O3 concentration shows two peaks, the first peak at noontime and the secondary peak at night. In order to show why the secondary peak, high nocturnal O3 concentration, occurs without sunlight which is a essential factor of a photochemical response, the O3 concentration, several weather elements and synoptic weather map were used for June∼September at 1995, 1996. The mean concentration of high nocturnal O3 concentration days is higher by 5.4 ppb than that of low nocturnal O3 concentration days. The nocturnal O3 concentration is higher than that of diurnal O3 concentration during high nocturnal O3 concentration days, at July, 1995 and June, 1996. The high nocturnal O3 concentration is related to low air pressure, high cloud cover and high wind speed. The correlation coefficient, r. between nocturnal O3 concentration and wind speed, pressure and cloud cover is 0.387, -0.218, and 0.194, respeftiviely. It is interesting that the O3 concentration increases at Pusan when the typhoon passes by. The same result showed at Taegu when the typhoon FAYE passed by. According to the analysis of nocturnal O3 concentration for June∼September at 1995 and 1996, it seems that the high nocturnal O3 concentration relates to the trough and cyclones passing by Pusan.

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A Study on the Generation and Movement of Low-concentration $CO_2$ in Summer at Gosan, Korea (제주도 고산지역 여름철 저농도 이산화탄소의 발생원인과 이동경로에 관한 연구)

  • Kang, Kyeoung-Sik;Moon, Il-Ju;Hwang, Seung-Man;Shin, Dong-Suk;Yoon, Soon-Chang
    • Atmosphere
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    • v.20 no.3
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    • pp.307-318
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    • 2010
  • This study investigates the generation and movement of low-concentration $CO_2$ observed in Gosan during summer from 2002 to 2006. For analysis, additional $CO_2$ data in Anmyeondo, Ryori, Barrow, and Minamitorishima as well as NOAA/ESRL daily global $CO_2$ fields, background trajectories data, and 850 hPa wind fields are also used. Based on analyses using various observed data, we classified three types of low-concentration $CO_2$ in Gosan according to its origin: i) the origin of the Siberian continental, in which the consumption of $CO_2$ is active due to photosynthesis from broad forests, ii) the origin of Okhotsh and Artic seas, in which the low-concentration $CO_2$ is dominant due to high primary productivity by a plankton bloom, and iii) the origin of the Northwestern Pacific which is related to the entry of air mass from high latitudes. These results show that the low-concentration $CO_2$ observed in Gosan during summer is not originated from the Pacific oceans as known in previous studies, but originated from high latitude regions such as the Siberian continental and the Okhotsh and Artic seas.

Effects of Sulfuric Acid Concentration and Alloying Elements on the Corrosion Resistance of Cu-bearing low Alloy Steels

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.154-165
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    • 2018
  • During the process of sulfur dioxide removal, flue gas desulfurization equipment provides a serious internal corrosion environment in creating sulfuric acid dew point corrosion. Therefore, the utilities must use the excellent corrosion resistance of steel desulfurization facilities in the atmosphere. Until now, the trend in developing anti-sulfuric acid steels was essentially the addition of Cu, in order to improve the corrosion resistance. The experimental alloy used in this study is Fe-0.03C-1.0Mn-0.3Si-0.15Ni-0.31Cu alloys to which Ru, Zn and Ta were added. In order to investigate the effect of $H_2SO_4$ concentration and the alloying elements, chemical and electrochemical corrosion tests were performed. In a low concentration of $H_2SO_4$ solution, the major factor affecting the corrosion rate of low alloy steels was the exchange current density for $H^+/H_2$ reaction, while in a high concentration of $H_2SO_4$ solution, the major factors were the thin and dense passive film and resulting passivation behavior. The alloying elements reducing the exchange current density in low concentration of $H_2SO_4$, and the alloying elements decreasing the passive current density in high concentration of $H_2SO_4$, together play an important role in determining the corrosion rate of Cu-bearing low alloy steels in a wide range of $H_2SO_4$ solution.

Synoptic Weather Patterns and Variation of Ozone Concentrations Association with High Ozone Days at Five Major Cities in Korea (고농도 오존이 발생하는 날의 종관 기상 패턴과 주요 5대 도시별 오존 농도 변화)

  • 김유라;윤일희;김희종
    • Journal of Environmental Science International
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    • v.10 no.6
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    • pp.437-444
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    • 2001
  • The characteristic features of surface ozone concentration and the forecasting procedure of high ozone days have been studied. The ozone concentration was continuously measured during 3 years (1997~1999) at air quality monitoring stations in five major cities in Korea. The diurnal variation of surface ozone concentration on high ozone days is characterized by low ozone concentration at night. The ozone concentration Increases continuously after sunrise, In reach a peak at 1500~1600 LST. Thereafter it decreases steadily to a low concentration at sunset. The diurnal and annual maximum of the surface ozone concentration at Seoul were observed in May and June, respectively. The favorable synoptic condition for the high ozone day is divided into 4 different synoptic weather patterns: a high-pressure system from the Sea of Okhotsk, the Pacific subtropical high extending westward, a moving high-pressure system covering the Korean peninsula. and a synoptic system In front of a typhoon. Most of high ozone days occur under the high pressure system in Korea.

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Biofilter를 이용한 diesel VOCs의 생물학적 제거

  • 이은영;최우진;최진규;김무훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.347-350
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    • 2002
  • The petrochemical products can cause soil and groundwater contamination during their transportation and the use of the products, and while being contained in underground storage tanks(USTs) throughout the leakage. To treat the contaminated soil, the bioventing method is suitable for the remediation of semi-volatile compounds, such as diesel and kerosene. Biofiltration is one of possible method to treat the off-gas produced in the process of the bioventing. This study is related to the usage, effectiveness of treatment, and feasibility of two types of biofilter system made of ceramic-compost and polymer respectively to treat diesel VOCs at constant retention time of 20 sec. Compost biofilter showed the average removal efficiency of 73 % when the inlet concentration increased to 20 ppmv. Increased the inlet concentration decreased the microbial activities as well as the removal efficiency. On the contrary, the removal efficiency of the polyurethane biofilter was maintained at 88 % at the inlet concentration of 13 ppmv during ten days and was obtained to 80 % at the inlet concentration of 30 ppmv in spite of the drop of the efficiency in the sudden increase of the inlet concentration. At the beginning of the experiment it showed low removal efficiency at low inlet concentration due to the low microbial activity, however, as experiments proceed the removal efficiency could be obtained more than 80% at high inlet concentration.

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On-line Measurement of $H_2$O/LiBr Concentration using Electric Conductivity (전기 전도도를 이용한 $H_2$O/LiBr 용액의 실시간 농도의 측정)

  • 박찬우;김정환;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.1078-1083
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    • 2002
  • The objectives of this paper are to measure the concentration of $H_2$O/LiBr solution by measuring the electrical conductivity and to study the effect of the solution temperature and the concentration on the electrical conductivity of the solution. The solution temperature ranges $20^{\circ},\;40^{\circ},\;and\; 60^{\circ}$ for a fixed concentration during the experiment. The valid ranges of the concentration are two regions, low concentration region (1~20% of LiBr) and high concentration region (55~66% of LiBr). The results show that the conductivity of the solution increases linearly with increasing the solution temperature while it increases without creasing the concentration lower than about 35% of LiBr and decreases with increasing the concentration higher than 35%. This paper proposes experimental correlations for the concentration as functions of the solution temperature and the concentration with error band of $\pm7$% for the low concentration region and $\pm1$% for the high concentration region, respectively. The experimental correlation can be practically used in the on-line measurement without any sampling of solution from the closed system.

The Effect of HRT and SRT on Treatment Efficiency of Activated Sludge Process for Low Concentration Municipal Sewage (저농도 도시하수 처리를 위한 활성슬러지공정에서 HRT 및 SRT가 처리효율에 미치는 영향)

  • Whang, Gye Dae;Kim, Min Ho;Ko, Sae Bom
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.1
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    • pp.64-73
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    • 1997
  • Most of the municipal wastewater treatment plants operated in Korea are designed for high concentrations municipal sewage. However, activated sludge process employed by municipal wastewater treatment plant is operated at low organic loading. The objective of this study was to determine optimum operating condition of activated sludge process for treatment of low concentration municipal sewage. Three bench scale activated sludge reactors were operated to investigate the effect of HRT and SRT on the COD and TSS removal efficiency. The average concentration of TSS, SCOD, SBOD and TKN in influent were 118mg/l, 61mg/l, 21mg/l, and 12mg/l, respectively. The activated sludge reactors operated with various HRT and SRT showed about 89-93% TSS removal efficiency. HRT and SRT does not affect the TSS removal efficiency of actvatied sludge process significantly. However, HRT affected the SCOD removal efficiency slightly. As the HRT decreases from 13hours to 3hours, the SCOD removal efficiency decreases from 67% to 56%. The average effluent TCOD concentration of the reactor operated with 3hours of HRT was approximatly 40-45mg/l. Kinetic coefficient yield (Yt) and decay coefficients(Kd) were 0.594-0.954 mgMLVSS/mgCOD and $0.0197-0.0317day^{-1}$, respectively. Low concentration municipal sewage can be treated with 3 hours of HRT without effluent quality deterioration and SRT does not affect the substrate removal efficiency at this operation condition.

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Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process (초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거)

  • Lee, Hongju;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.391-396
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    • 2014
  • Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

Evaluation of Carryover Contamination on Autopipetting System (자동분주기의 이월오염 평가)

  • Lee, Hyun-Ju;Min, Gyung-Sun;Shin, Sun-Young;Woo, Jae-Ryong;Lee, Ho-Young
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.3
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    • pp.189-192
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    • 2009
  • Purpose: Autopipetting system is an efficient automated equipment pipetting patient samples and reagents for rapid and accurate test. However, it can cause carryover between high concentration sample and low concentration sample. We evaluated carryover contamination of TECAN freedom Evo 100 autopipetting system. Materials and Method: We studied carryover contamination of $\alpha$-fetoprotein (AFP) and carcinoembryonic antigen (CEA) test on TECAN freedom Evo 100 autopipetting system. Very low concentration control samples were pipetted for comparison to the contaminated very low concentration samples. Then, The contaminated very low concentration samples were pipetted following the high concentration samples were pipetted alternately. The difference of low concentration samples represents carryover. The target value to decide carryover was 1ppm (parts per million). Results: For AFP, the mean values of the uncontaminated control samples and the contaminated samples were less than 0.6 IU/mL (the l imit of detection (LoD)). Carryover did not occur even though the high concentration sample which value was 650000 IU/mL. For CEA, the values of the low concentration control samples and the contaminated samples were less than 0.2 ng/mL (LoD). Carryover did not occur even though the high concentration sample which value was 65,000 ng/mL. Conclusions: Sample carryover was not found on TECAN freedom Evo 100 autopipetting system for AFP, CEA. However, carryover is a potential problem with automated instruments and robotic pipetting systems. Therefore, Clinical laboratories must periodically verify carryover contamination for the accurate and confidential test results.

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Response of Barley Genotypes to Fusarium Head Blight under Natural Infection and Artificial Inoculation Conditions

  • Khanal, Raja;Choo, Thin Meiw;Xue, Allen G.;Vigier, Bernard;Savard, Marc E.;Blackwell, Barbara;Wang, Junmei;Yang, Jianming;Martin, Richard A.
    • The Plant Pathology Journal
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    • v.37 no.5
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    • pp.455-464
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    • 2021
  • Forty-eight spring barley genotypes were evaluated for deoxynivalenol (DON) concentration under natural infection across 5 years at Harrington, Prince Edward Island. These genotypes were also evaluated for Fusarium head blight (FHB) severity and DON concentration under field nurseries with artificial inoculation of Fusarium graminearum by the grain spawn method across 2 years at Ottawa, Ontario, and one year at Hangzhou, China. Additionally, these genotypes were also evaluated for FHB severity under greenhouse conditions with artificial inoculation of F. graminearum by conidial suspension spray method across 3 years at Ottawa, Ontario. The objective of the study was to investigate if reactions of barley genotypes to artificial FHB inoculation correlate with reactions to natural FHB infection. DON concentration under natural infection was positively correlated with DON concentration (r = 0.47, P < 0.01) and FHB incidence (r = 0.56, P < 0.01) in the artificially inoculated nursery with grain spawn method. Therefore, the grain spawn method can be used to effectively screen for low DON. FHB severity, generated from greenhouse spray, however, was not correlated with DON concentration (r = 0.12, P > 0.05) under natural infection and it was not correlated with DON concentration (r = -0.23, P > 0.05) and FHB incidence (r = 0.19, P > 0.05) in the artificially inoculated nursery with grain spawn method. FHB severity, DON concentration, and yield were affected by year, genotype, and the genotype × year interaction. The effectiveness of greenhouse spray inoculation for indirect selection for low DON concentration requires further studies. Nine of the 48 genotypes were found to contain low DON under natural infection. Island barley had low DON and also had high yield.