DOI QR코드

DOI QR Code

Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process

초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거

  • Received : 2014.06.23
  • Accepted : 2014.07.31
  • Published : 2014.08.15

Abstract

Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

Keywords

References

  1. Bennett, A. (2009) Water processes and production:High and ultra-high purity water, Filtration+Separation March/April, 24-27.
  2. Choi, H.S., Ham, Y.K., Lee, S.K. (2000) The sampling and analysis methods of ultra water, Membrane Journal, 10, No. 3, 112-120.
  3. Dow Filmtec webpage, http://www.dow.com
  4. Grabowski, A., Zhang, G., Strathmann, H., Eigenberger, G. (2006) The production of high purity water by continuous electrodeionization with bipolar membranes: Influence of the anion-exchange membrane permselectivity, Journal of Membrane Science, 281, 297-306. https://doi.org/10.1016/j.memsci.2006.03.044
  5. Hydranautics webpage, http://www.membranes.com
  6. K, Yabe. (2011) Introduction to water treatment technologies for pure and ultra-pure water production, Maruzen Publishing, Tokyo.
  7. Lee, C. S. (1996) The current of ultra water system, Membrane Journal, 6, No. 3, 127-140.
  8. Lee, J. H., Choi, J.H. (2012) The production of ultrapure water by membrane capacitive deionization (MCDI) technology, Journal of Membrane Science, 409-410, 251-256. https://doi.org/10.1016/j.memsci.2012.03.064
  9. Paul, D.R. (2004) Reformulation of the solutiondiffusion theory of reverse osmosis, Journal of Membrane Science, 241, 371-386. https://doi.org/10.1016/j.memsci.2004.05.026
  10. Qin, J. J., Oo, M.H., Wai, M.N., Kekre, K. (2005) TOC removal in reclamation of municipal wastewater by RO, Separation and Purification Technology, 46, 125-128. https://doi.org/10.1016/j.seppur.2005.04.004
  11. Toray webpage, http://www.toray.com
  12. Woongjin chemical webpage, http://www.wjchemical.co.kr
  13. Wu, M., Sun, D., Tay, J. (2003) Development of a practical model for capacity evaluation of ultrapure water systems, Desalination, 161, 223-233.
  14. Zhang, G., Shong, J. (1998) Production of ultrapure water for the STN-LCD process line, Desalination, 119, 355-356. https://doi.org/10.1016/S0011-9164(98)00182-9