• 제목/요약/키워드: Low Temperature Shift

검색결과 201건 처리시간 0.028초

비정질 Sb-Bi-Te 박막의 전기적 특성에 관한 연구 (A Study on the Electrical Properties of Amorphous Sb-Bi-Te Thin Films)

  • 이준신;이재형
    • 한국전기전자재료학회논문지
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    • 제15권3호
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    • pp.220-226
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    • 2002
  • Amorphous $Sb_{2-x}Bi_xTe_3$ (x = 0.0, 0.5 and 1.0) thin films were prepared by vacuum evaporation. The resistivity of 7he films decreases from 1.4{\times}10^{-2}$ to $8.84{\times}10^{-5}\Omega cm$ and the type of conductivity changes from p to n with the increase of the x value of the films. D.C. conduction studies on these films ate performed at various electric fields in the temperature range of 303-403 K. At low electric fields, two types of conduction mechanisms, i.e. the variable range hopping and the phonon assisted hopping are found to be responsible for the conduction, depending upon the temperature. The activation energy decreases from 0.082 to 0.076 eV in the temperature range of 303-363 K and from 0.47-0.456 eV in the second range of 363-403 K, indicating the shift of the Fermi level towards the conduction band edge and hence the change of the conduction from P to n type with the increase of the Bi concentration. Poole-Frankel emission dominates at high fields. The shape of the potential well of the localized centre is deduced and the mean free path of the charge carriers is also calculated.

Comparison of Hygrothermal Performance between Wood and Concrete Wall Structures using Simulation Program

  • Yu, Seulgi;Chang, Seong Jin;Kang, Yujin;Kim, Sumin
    • Journal of the Korean Wood Science and Technology
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    • 제44권2호
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    • pp.283-293
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    • 2016
  • Owing to an increase in the air tightness of recent buildings, the natural ventilation rate was significantly lowered and the removal of accumulated moisture became difficult in these buildings. The hygrothermal performance of these buildings should be carefully considered to provide comfortable indoor environment by removing the moisture condensation risk and the mold growth potential. In this study, hygrothermal performance of two selected wall structures was investigated based on WUFI simulation program. The results displayed that the indoor temperature had impact on the moisture accumulation in the insulation layer for both modeled walls, showing that lower indoor temperature resulted in higher moisture accumulation, especially in the wood frame structure. Also, the yearly moisture accumulation profile exhibited a downward shift throughout the year by adding a vapour retarder with a lower sd-value. In addition, both of the two walls have condensation risk in winter, due to low temperature level. The wood frame structure has a bigger fluctuation and higher condensation risk than the concrete structure.

고기동 추진기관의 노즐개방형 측추력기 개발 (Development of Side Jet Thruster with Nozzle Closure Separation Device)

  • 한혁섭;박의용;김동진;손영일
    • 한국추진공학회지
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    • 제18권2호
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    • pp.80-85
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    • 2014
  • 노즐개방형 측추력기는 고체 추진기관을 사용하는 비행체의 궤도 수정 기능을 제공하는 장치이다. 노즐개방형 측추력기는 비교적 낮은 연소온도를 가지는 추진제, 안정된 추력을 공급하기 위한 중립형 추진제 그레인, 선택적 노즐 사용이 가능한 노즐개방장치로 구성되었다. 궤도 수정이 요구되면 추력 반대방향으로 필요한 추력만큼 노즐을 개방하여 비행체에 측추력을 발생시킨다. 궤도 수정 후 추력방향으로 노즐을 개방하여 측추력을 제거함으로써 추력 발생을 정지한다. 지상연소시험을 통해 측추력기의 작동과정을 확인하였으며, 본 연구를 통하여 개발된 노즐개방형 측추력기는 노즐개방을 통한 측추력 제어를 통해 비행체의 궤도 수정에 활용할 수 있다.

고압 WGS 반응을 위한 Cu-ZnO/Al2O3 촉매상에서 기-액 계면 촉매 반응 특성 연구 (Catalytic Activity Tests in Gas-Liquid Interface over Cu-ZnO/Al2O3 Catalyst for High Pressure Water-Gas-Shift Reaction)

  • 김세훈;박노국;이태진
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.905-912
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    • 2011
  • In this study, the novel concept catalytic reactor was designed for water-gas shift reaction (WGS) under high pressure. The novel concept catalytic reactor was composed of an autoclave, the catalyst, and liquid water. Cu-ZnO/$Al_2O_3$ as the low temperature shift catalyst was used for WGS reaction. WGS in the novel concept catalytic reactor was carried out at the ranges of 150~$250^{\circ}C$ and 30~50 atm. The liquid water was filled at the bottom of the autoclave catalytic reactor and the catalyst of pellet type was located at the gas-liquid water interface. It was concluded that WGS reaction occurred over the surface of catalysts partially wetted with liquid water. The conversion of CO for WGS was also controlled with changing content of Cu and ZnO used as the catalytic active components. Meanwhile, the catalyst of honey comb type coated with Cu-ZnO/$Al_2O_3$ was used in order to increase the contact area between wet-surface of catalyst and the reactants of gas phase. It was confirmed from these experiments that $H_2$/CO ratio of the simulated coal gas increased from 0.5 to 0.8 by WGS at gas-liquid water interface over the wet surface of honey comb type catalyst at $250^{\circ}C$ and 50 atm.

The Effects of a Thermal Annealing Process in IGZO Thin Film Transistors

  • Kim, Hyeong-Jun;Park, Hyung-Youl;Park, Jin-Hong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.289.2-289.2
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    • 2016
  • In-Ga-Zn-O(IGZO) receive great attention as a channel material for thin film transistors(TFTs) as next-generation display panel backplanes due to its superior electrical and physical properties such as a high mobility, low off-current, high sub-threshold slope, flexibility, and optical transparency. For the purpose of fabricating high performance IGZO TFTs, a thermal recovery process above a temperature of $300^{\circ}C$ is required for recovery or rearrangement of the ionic bonding structure. However diffused metal atoms from source/drain(S/D) electrodes increase the channel conductivity through the oxidation of diffused atoms and reduction of $In_2O_3$ during the thermal recovery process. Threshold voltage ($V_{TH}$) shift, one of the electrical instability, restricts actual applications of IGZO TFTs. Therefore, additional investigation of the electrical stability of IGZO TFTs is required. In this paper, we demonstrate the effect of Ti diffusion and modulation of interface traps by carrying out an annealing process on IGZO. In order to investigate the effect of diffused Ti atoms from the S/D electrode, we use secondary ion mass spectroscopy (SIMS), X-ray photoelectron spectroscopy, HSC chemistry simulation, and electrical measurements. By thermal annealing process, we demonstrate VTH shift as a function of the channel length and the gate stress. Furthermore, we enhance the electrical stability of the IGZO TFTs through a second thermal annealing process performed at temperature $50^{\circ}C$ lower than the first annealing step to diffuse Ti atoms in the lateral direction with minimal effects on the channel conductivity.

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Asymmetric Sythesis of Unnatural L-Amino Acids Using Thermophilic Aromatic L-Amino Acid Transaminase

  • Cho, Byung-Kwan;Seo, Joo-Hyun;Kim, Ju-Han;Lee, Chang-Soo;Kim, Byung-Gee
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제11권4호
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    • pp.299-305
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    • 2006
  • Aromatic L-amino acid transaminase is an enzyme that is able to transfer the amino group from L-glutamate to unnatural aromatic ${\alpha}-keto$ acids to generate ${\alpha}-ketoglutarate$ and unnatural aromatic L-amino acids, respectively. Enrichment culture was used to isolate thermophilic Bacillus sp. T30 expressing this enzyme for use in the synthesis of unnatural L-amino acids. The asymmetric syntheses of L-homophenylalanine and L-phenylglycine resulted in conversion yields of >95% and >93% from 150 mM 2-oxo-4-phenylbutyrate and phenylglyoxylate, respectively, using L-glutamate as an amino donor at $60^{\circ}C$. Synthesized L-homophenylalanine and L-phenylglycine were optically pure (>99% enantiomeric excess) and continuously pre-cipitated in the reaction solution due to their low solubility at the given reaction pH. While the solubility of the ${\alpha}-keto$ acid substrates is dependent on temperature, the solubility of the unnatural L-amino acid products is dependent on the reaction pH. As the solubility difference between substrate and product at the given reaction pH is therefore larger at higher temperature, the thermophilic transaminase was successfully used to shift the reaction equilibrium toward rapid product formation.

스퍼터링에 의한 Low-k 박막의 특성 (CharacteristicProperties of Low-k Thin Film Deposited by Sputtering)

  • 오데레사
    • 한국산학기술학회논문지
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    • 제13권7호
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    • pp.3160-3164
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    • 2012
  • 저온공정을 위해 스퍼터 방법에 의해 SiOC 박막을 증착하였으며, SiOC 박막 위에 투명전극을 제작하기 위해서 AZO박막과 ZnO 박막을 증착하였다. 박막의 광학적 특성은 PL 분석기와 스펙트라포토미터를 이용하였다. SiOC 박막은 n-type Si 위에 증착하였을 때 증착조건에 따라서 방사 효과가 다양하게 나타났으며, 두꺼운 박막에서 blue shit 현상이 나타났다. SiOC/Si 박막 위에 AZO 박막을 증착할 경우 빛의 흡수영역이 넓어졌다. 이러한 특성은 태양전지의 투명전극을 만들 경우 효율을 높일 수 있게 된다.

신재생에너지용 연계형 인버터의 고효율 승압에 관한 연구 (Study on High Efficiency Boosting-up Circuit for Renewable Energy Application)

  • 정태욱;김주용;최세권;조준석;고희석
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2009년도 춘계학술대회 논문집
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    • pp.336-339
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    • 2009
  • In this paper, such as battery power or solar energy and fuel cells generated from Renewable energy sources, high voltage to low voltage DC-DC Converter for converting the design of the study. System consists of low voltage ($24{\sim}28$ [VDC]) and Boosts the voltage (270 [VDC]) for a 3 [kW] DC-DC converter and control circuit is configured as, Power switch the ST Tomson's Automotive low voltage high current MOSFET switches STE250NS10S (temperature 250A) was applied to the two parallel. Also, Controller's processor used ATMEGA128, and Gate Drive applies and composed Photo Coupler TLP250. development. Input voltage (24V) and output voltage (270V) for Conversion in the H-bridge converter topology of the circuit output side power and voltage to control the implementation of the Phase shift angle control applied. And, 3kW of power to pass appropriate specification of the secondary side as interpreted by the high frequency transformer, and the experimental production and analysis of the experiment

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저 압력 측정을 위한 실리콘 용량형 압력센서 (Silicon Capacitive Pressure Sensor for Low Pressure Measurements)

  • 서희돈;이윤희;박종대;최세곤
    • 센서학회지
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    • 제2권1호
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    • pp.19-27
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    • 1993
  • 본 논문은 $n^{+}$ 에피택셜층을 이용한 전기화학 에칭스톱과 글라스-실리콘의 양극 접합기술을 이용하여 저 압력측정을 위한 용량형 압력센서를 제작한 것이다. 제작된 센서는 하이브리드형으로 센서 커패시터와 기준 커패시터를 갖는 센서 칩과 두가지 출력검출회로 칩으로 구성되어 있다. 이 제작된 센서는 다이아프램 크기가 $1.0{\times}1.0 mm^{2}$이고, 두께가 $10{\mu}m$로 제작된 센서는 압력이 인가되지 않을 때 용량의 크기가 7.1 pF이고, 10 KPa 압력에서 감도가 5.2 %F.S.이다. 또 용량을 전압으로 검출하는 컨버터회로를 이용할 경우, $5{\sim}45^{\circ}C$ 온도범위에서 영점 온도특성과 감도 온도특성은 각각 0.051 %F.S./$^{\circ}C$와 0.12 %F.S./$^{\circ}C$ 이다.

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Syntrophic Propionate Degradation Response to Temperature Decrease and Microbial Community Shift in an UASB Reactor

  • Ban, Qiaoying;Li, Jianzheng;Zhang, Liguo;Jha, Ajay Kumar;Zhang, Yupeng;Ai, Binling
    • Journal of Microbiology and Biotechnology
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    • 제23권3호
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    • pp.382-389
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    • 2013
  • Propionate is an important intermediate product during the methane fermentation of organic matter, and its degradation is crucial for maintaining the performance of an anaerobic digester. In order to understand the effect of temperature on propionate degradation, an upflow anaerobic sludge blanket (UASB) reactor with synthetic wastewater containing propionate as a sole carbon source was introduced. Under the hydraulic retention time (HRT) of 10 h and influent propionate of 2,000 mg/l condition, propionate removal was above 94% at 30-$35^{\circ}C$, whereas propionate conversion was inhibited when temperature was suddenly decreased stepwise from $30^{\circ}C$ to $25^{\circ}C$, to $20^{\circ}C$, and then to $18^{\circ}C$. After a long-term operation, the propionate removal at $25^{\circ}C$ resumed to the value at 30- $35^{\circ}C$, whereas that at $20^{\circ}C$ and $18^{\circ}C$ was still lower than the value at $35^{\circ}C$ by 8.1% and 20.7%, respectively. Microbial community composition analysis showed that Syntrophobacter and Pelotomaculum were the major propionate-oxidizing bacteria (POB), and most POB had not changed with temperature decrease in the UASB. However, two POB were enriched at $18^{\circ}C$, indicating they were low temperature tolerant. Methanosaeta and Methanospirillum were the dominant methanogens in this UASB and remained constant during temperature decrease. Although the POB and methanogenic composition hardly changed with temperature decrease, the specific $COD_{Pro}$ removal rate of anaerobic sludge (SCRR) was reduced by 21.4%-46.4% compared with the control ($35^{\circ}C$) in this system.