• The Transactions of The Korean Institute of Electrical Engineers
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• v.63 no.6
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• pp.820-827
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• 2014

Since a microgrid has renewable energy sources, imbalance between power supply and power demand occurs in the islanded mode. In order to solve the imbalance, several energy storage systems (ESSs) such as bettary energy storage system (BESS), EDLC (electric double layer capacitor), flywheel, and SMES (superconducting magnetic energy storage) are generally used. Especially, their electrical characteristics are different. For efficient use of them, a coordinated control scheme is required. In this paper, a coordinated control scheme for using a Lead-acid BESS, a Lithium BESS, and a EDLC is designed to efficient frequency control for a microgrid in the islanded mode. The coordinated frequency control strategy is designed based on their electrical characteristics. The feasibility of the proposed coordinated frequency control strategy is verified through the simulation.

• Transactions of the Society of Information Storage Systems
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• v.3 no.2
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• pp.94-112
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• 2007

Nano-sized inverted domain dots in ferroelectric materials have potential application in ultrahigh-density rewritable data storage systems. Herein, a data storage system is presented based on scanning non-linear dielectric microscopy and a thin film of ferroelectric single-crystal lithium tantalite. Through domain engineering, we succeeded to form an smallest artificial nano-domain single dot of 5.1 nm in diameter and artificial nano-domain dot-array with a memory density of 10.1 Tbit/$inch^2$ and a bit spacing of 8.0 nm, representing the highest memory density for rewritable data storage reported to date. Sub-nanosecond (500psec) domain switching speed also has been achieved. Next, long term retention characteristic of data with inverted domain dots is investigated by conducting heat treatment test. Obtained life time of inverted dot with the radius of 50nm was 16.9 years at $80^{\circ}C$. Finally, actual information storage with low bit error and high memory density was performed. A bit error ratio of less than $1\times10^{-4}$ was achieved at an areal density of 258 Gbit/inch2. Moreover, actual information storage is demonstrated at a density of 1 Tbit/$inch^2$.

• Transactions on Electrical and Electronic Materials
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• v.15 no.5
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• pp.265-269
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• 2014

Carbon nanofiber electrode has been fabricated for energy storage systems by the electrospinning of SU-8 precursor and subsequent pyrolysis. Various parameters including the applied voltage, the distance between syringe tip and target collector and the flow rate of the polymer affect the diameter of SU-8 electrospun nanofibers. Shrinkage during pyrolysis decreases the fiber diameter. As the pyrolysis temperature increases, the resistivity decreases dramatically. Low resistivity is one of the important characteristics of the electrodes of an energy storage device. Given the advantages of carbon nanofibers having high external surface area, electrical conductivity, and lithium intercalation ability, SU-8 derived carbon nanofibers were applied to the anode of a full lithium ion cell. In this paper, we studied the physical properties of carbon fiber electrode by scanning transmission microscopy, thermal gravimetric analysis, and four-point probe. The electrochemical characteristics of the electrode were investigated by cyclic voltammogram and electrochemical impedance spectroscopy plots.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2304-2308
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• 2010

A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

• Journal of Electrochemical Science and Technology
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• v.6 no.2
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• pp.50-58
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• 2015

There is a great deal of current interest in the development of rechargeable batteries with high energy storage capability due to an increasing demand for electric vehicles (EVs) with driving ranges comparable to those of gasoline-powered vehicles. Among various types of batteries under development, a Li-O₂ battery delivers the highest theoretical energy density; thus, it is considered a promising energy storage technology for EV applications. Despite the fact that extensive research efforts have been made in the field of Li-O₂ batteries in recent years, there are still many technical challenges to be addressed, such as low round-trip efficiency, poor reversibility, and poor power capability. In this article, we provide a short review on the fundamental electrochemistry of Li-O₂ batteries with non-aqueous electrolytes and on electrode materials that have been employed in cathodes (oxygen electrodes). The major aim of this mini-review is to highlight the physical and electrochemical origins of scientific challenges facing Li-O₂ battery technology and to overview the strategies proposed to overcome them.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.108-109
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• 2012

This talk will begin with the demonstration of facile synthesis of silicon nanostructures using the magnesiothermic reduction on silica nanostructures prepared via self-assembly, which will be followed by the characterization results of their performance for energy storage. This talk will also report the fabrication and characterization of highly porous, stretchable, and conductive polymer nanocomposites embedded with carbon nanotubes (CNTs) for application in flexible lithium-ion batteries. It will be presented that the porous CNT-embedded PDMS nanocomposites are capable of good electrochemical performance with mechanical flexibility, suggesting these nanocomposites could be outstanding anode candidates for use in flexible lithium-ion batteries. Directed self-assembly (DSA) of block copolymers (BCPs) can generate uniform and periodic patterns within guiding templates, and has been one of the promising nanofabrication methodologies for resolving the resolution limit of optical lithography. BCP self-assembly processing is scalable and of low cost, and is well-suited for integration with existing semiconductor manufacturing techniques. This talk will introduce recent research results (of my research group) on the self-assembly of Si-containing block copolymers for the achievement of sub-10 nm resolution, fast pattern generation, transfer-printing capability onto nonplanar substrates, and device applications for nonvolatile memories. An extraordinarily facile nanofabrication approach that enables sub-10 nm resolutions through the synergic combination of nanotransfer printing (nTP) and DSA of block copolymers is also introduced. This simple printing method can be applied on oxides, metals, polymers, and non-planar substrates without pretreatments. This talk will also report the direct formation of ordered memristor nanostructures on metal and graphene electrodes by the self-assembly of Si-containing BCPs. This approach offers a practical pathway to fabricate high-density resistive memory devices without using high-cost lithography and pattern-transfer processes. Finally, this talk will present a novel approach that can relieve the power consumption issue of phase-change memories by incorporating a thin $SiO_x$ layer formed by BCP self-assembly, which locally blocks the contact between a heater electrode and a phase-change material and reduces the phase-change volume. The writing current decreases by 5 times (corresponding to a power reduction of 1/20) as the occupying area fraction of $SiO_x$ nanostructures varies.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.17 no.5
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• pp.199-208
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• 2017

Lithium polymer batteries are used in energy storage systems (ESS), electric vehicles (EVs), etc. due to their high safety, fast charging and long lifecycle, and now they are used in agricultural drones. However, when overcharging and overdischarging, the lithium-polymer battery is destroyed in the gap structure in the lithium-ion battery and the battery life is reduced. In order to prevent overcharge and overdischarge, uneven cell voltage Cell balancing system is needed. In this paper, a fuzzy controller suitable for nonlinear systems is proposed by detecting the unbalanced cells by detecting the voltage difference between charging and discharging of each cell, and suggesting the applied cell balancing algorithm. In this paper, we have designed the cell balancing of the battery pack of agricultural drones by fuzzy control and it is designed for equal control between cells. As a final result, we checked whether cell balancing is good, and when there are two cells, Cell balancing was confirmed. We tested whether it could be used for other products. As a result, we confirmed that cell balancing is good regardless of the number of cells used.

• Journal of IKEEE
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• v.25 no.3
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• pp.556-564
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• 2021

This paper presents trends of safety improvement technologies for an electric propulsion system of eco-friendly ships. As an effort to reduce a green house effect, demands for eco-friendly ships have been increased. An energy storage system (ESS) is one of key systems in an eco-friendly ship and a lithium-ion battery generally used in an ESS system due to its high power density and efficiency. However, a lithium-ion battery is considered as one of reasons for ESS fire hazard. Since a fire extinguishing facility is especially limited in the ocean, safety issue in an eco-friendly ship is important. In this paper, recent safety improvement technologies for traction motors, ESS batteries and structures for eco-friendly ships are presented.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.243-252
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• 2021

With increasingly strict requirements for advanced energy storage devices in electric vehicles (EVs) and stationary energy storage systems (EES), the development of lithium-ion batteries (LIBs) with high power density and safety has become an urgent task. Because the performance of LIBs is determined primarily by the physicochemical characteristics of its electrode material, TiO₂, owing to its excellent stability, high safety levels, and environmentally friendly properties, has received significant attention as an alternative material for the replacement of commercial carbon-based anode materials. In particular, self-organized TiO₂ micro and nanostructures prepared by anodization have been intensively investigated as promising anode materials. In this review, the mechanism for the formation of anodic TiO₂ nanotubes and microcones and the parameters that influence their morphology are described. Furthermore, recent developments in anodic TiO₂-based composites as anode electrodes for LIBs to overcome the limitations of low conductivity and specific capacity are summarized.

• Journal of the Korean Electrochemical Society
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• v.24 no.4
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• pp.93-99
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• 2021

In order to decrease the weight of stretchable energy storage devices, interest in developing lightweight materials to replace metal current collectors is increasing. In this study, nanofibers prepared by electrospinning a conductive polymer, PEDOT:PSS, were used as current collectors for lithium ion batteries. The nanofiber showed improved electrical conductivity by using DMSO, a dopant, and indicated a stretch rate of 30% or more from the elasticity evaluation result. In addition, the use of the nanofiber current collector facilitates penetration of the liquid electrolyte and exhibits the effect of increasing the electronic conductivity through the nanofiber network. The lithium-ion battery using the DMSO-doped PEDOT:PSS@PAM nanofiber current collector indicated a high discharge capacity of 135mAh g^-1, and indicated a high capacity retention rate of 73.5% after 1000 cycles. Thus, the excellent electrochemical stability and mechanical properties of conductive nanofibers showed that they can be used as lightweight current collectors for stretchable energy storage devices.