• 전기의세계
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• 제29권8호
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• pp.532-537
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• 1980

Effect of Argon and Sulfur hexafloride in the transformer oil are experimented under non-uniform A.C. electric field. The result has shown that the corona frequency and corona charge quantity in liquid dielectrics were varied with gas condition in the oil and affected by the additives. SF$_{6}$ that has the effects of pressure and electrical negative characteristic is the most effective. The corona is considered to be the breakdown of bubble produced by gas contained in the oil or by dissociated ion of the oil molecules.s.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2233-2236
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• 2011

We evaluate quantum-mechanical velocity autocorrelation functions from classical molecular dynamics simulations using quantum correction approaches. We apply recently developed approaches to supercritical argon and liquid neon. The results show that the methods provide a solution more efficient than previous methods to investigate quantum-mechanical dynamic behavior in condensed phases. Our numerical results are found to be in excellent agreement with the previous quantum-mechanical results.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1992년도 춘계학술발표회
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• pp.126-126
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• 1992

Solid and liquid sintering behaviors of mechanically alloyed 75W-25Cu powders have been studied by using a dilatometry technique. The sintering was performed under hydrogen atmosphere of 1 atm with a heating rate of 3 $^{\circ}C$/min. The mechanically alloyed 75W-25Cu powders were prepared by high energy ball milling process under argon atmosphere of 1 atm with alloying times of 0 to 400 h. To compare with the sintering behaviors of mechanically alloyed powders, pure Cu and W powders were also sintered under the above conditions, As the mechanical alloying time increased from 0 to 400 h, the shrinkage behavior of the alloyed powders was enhanced during the sintering, and staring temperature of liquid sintering decreased from 1083 to 1068 $^{\circ}C$. The saturation temperature, above which the shrinkage was completed, of liquid phase sintering decreased from 1248 to 1148 $^{\circ}C$ with increasing mechanical alloying time from 200 to 400 h. The residual stress of the mechanically alloyed powder was measured by X-raydiffractometer. The microstructure of sintered spcimen was observed by optical and scanning electron microscope. From these results, variations of solid and liquid sintering behaviors with mechanical alloying time were discussed in terms of the amount of residual stress and the distribution of W and Cu powders in the mechanically alloyed powder.

• 한국재료학회지
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• 제13권5호
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• pp.285-291
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• 2003

The nanosized silver and gold particles are prepared by ERC method in which metal vapors with high temperature is rapidly quenched by coolants such as liquid nitrogen or liquid argon. In order to monitor the crystal structural changes on the internal and the surface of the nanosized noble metal particles, lattice parameter, internal strain and Debye-Waller factor are investigated, and the calculation of X-ray diffraction scattering intensity is performed. The lattice parameters of silver and gold particles agree with those of bulk materials, and crystal internal strain of the metal particles is not changed by rapid cooling. The Debye-Waller factor of gold particles is increased with decreasing particle size because of the surface softening phenomenon of nanosized particles, but the crystal structural change on the surface of the particles is not detected from the comparison the calculated X-ray diffraction profile with the experimental profile on gold particles with the particle size of 4 nm.

• 대한화학회지
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• 제8권4호
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• pp.183-187
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• 1964

액체에 관한 hole theory 를 사용하여 여러가지 액체들의 표면장력과 표면 각층의 excess molar sulface entropy 들을 계산하였다. 표면 첫째층의 것은 이상적인 분자가 표면을 형성할 때의 값 Rln2보다 다소 큰 값을 보여주며 액체 내부에 들어감에 따라 점점 줄어들어 저온에서는 셋째층부터 거의 없어진다. 그리고 알곤, 질소, 메탄, 벤젠 및 할로겐들의 표면장력을 계산하여 측정치와 비교하였다.

• 설비공학논문집
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• 제19권12호
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• pp.883-888
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• 2007

As a starting point of investigating what molecular dynamic simulations can reveal about the nature of atomic level of heating and cooling process, argon described by the LJ potential is considered. Stepwise heating and cooling of constant rates are simulated in the NPT (constant number, pressure and temperature) ensemble. Hysteresis is found due to the superheating and supercooling. Drastic change of volume and energy is involved with phase change, but the melting point can not be obtained by simply observing the changes of these quantities. Since liquid and solid phases can co-exist at the same temperature, Gibbs free energy should be calculated to find the temperature where the Gibbs free energy of liquid is equal to that of the solid since the equilibrium state is the state of minimum Gibbs free energy. The obtained melting temperature, $T^*=0.685$, is close to that of the experiment with only 2% error.

• 한국시뮬레이션학회논문지
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• 제6권1호
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• pp.53-60
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• 1997

Results from a nonequilibrium molecular dynamics (NEMD) simulation are presented for an argon liquid subject to a shear flow. The segmented molecular dynamics method and the subtraction technique used in NEMD program to reduce the thermal fluctuation noise in data are studied with different shear rates. The standard deviation in the shear stress reduced from 0.030 to 0.004 by the segmented molecular dynamics method for 50 repeated segments. On the other hand, the standard deviation of the data remained the same when the subtraction technique was applied, where as the results of shear stress by constant value in a random way.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2195-2200
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• 2010

The reaction of $PdCl_2$ dispersed in tetra-n-butylammonium bromide with tributyl amine at $120^{\circ}C$ under argon leads to stable isolable nanometric particles. X-ray diffraction analysis of the material indicated that it is constituted of Pd(0). Transmission electron microscopy analysis of the particles dispersed in acetone shows the mean particle size distribution ($4{\pm}1\;nm$). The isolated palladium nanoparticles can be dispersed in an ionic liquid or in methanol or used in solventless condition for selective hydrogenation of 2-hexyne under mild reaction conditions(0.2 MPa and $20^{\circ}C$). The commercial variety of the Lindlar catalyst was also studied for comparative investigations.

• 대한화학회지
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• 제10권1호
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• pp.18-24
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• 1966

액체 내에는 분자들 주위에 분자크기의 빈자리가 들어 있게 되어 빈자리로 뛰어들면서 기체와 같은 자유도를 갖는 분자와, 빈자리에서 좀 떨어져서 고체와 같은 자유도를 갖는 분자와, 빈자리 때문에 변형에너지를 받고서 천이상태에 있는 분자들이 있다고 가정하여 액체에 대한 상태함을 유도하여 알곤, 질소, 벤젠, 클로로포름 및 이황화탄소의 액체상태에서의 열역학적 성질들을 계산한 결과 실측치와의 좋은 일치를 얻었다.

• 한국수소및신에너지학회논문집
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• 제27권6호
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• pp.642-650
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• 2016

One of the most feasible solution for reducing the excessive energy consumption and carbon dioxide emission is usage of more efficient fuel such as hydrogen. As is well known, there are three viable technologies for storing hydrogen fuel: compressed gas, metal hydride absorption, and cryogenic liquid. In these technologies, the storage for liquid hydrogen has better energy density by weight than other storage methods. However, the cryogenic liquid storage has a significant disadvantage of boiling losses. That is, high performance of thermal insulation systems must be studied for reducing the boiling losses. This paper presents an experimental study on the effective thermal conductivities of the composite layered insulation with aerogel blankets($Cryogel^{(R)}$ Z and $Pyrogel^{(R)}$ XT-E) and Multi-layer insulation(MLI). The aerogel blankets are known as high porous materials and the good insulators within a soft vacuum range($10^{-3}{\sim}1$ Torr). Also, MLI is known as the best insulator within a high vacuum range(<$10^{-6}{\sim}10^{-3}$ Torr). A vertical axial cryogenic experimental apparatus was designed to investigate the thermal performance of the composite layered insulators under cryogenic conditions as well as consist of a cold mass tank, a heat absorber, annular vacuum space, and an insulators space. The composite insulators were laminated in the insulator space that height was 50 mm. In this study, the effective thermal conductivities of the materials were evaluated by measuring boil-off rate of liquid nitrogen and liquid argon in the cold mass tank.