Bulletin of the Korean Chemical Society

  • 제31권8호
  • /
  • Pages.2195-2200
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Palladium Nanoparticles Suspended in an Ionic Liquid as Reusable Catalyst for Alkyne Semihydrogenation

  • Lee, Jin-Kyu (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University) ;
  • Kim, Dae-Won (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University) ;
  • Cheong, Min-Serk (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University) ;
  • Lee, Hyun-Joo (Energy division, Korea Institute of Science and Technology) ;
  • Cho, Byung-Won (Energy division, Korea Institute of Science and Technology) ;
  • Kim, Hoon-Sik (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University) ;
  • Mukherjee, DebKumar (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
  • 투고 : 2010.05.19
  • 심사 : 2010.06.08
  • 발행 : 2010.08.20
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초록

The reaction of $PdCl_2$ dispersed in tetra-n-butylammonium bromide with tributyl amine at $120^{\circ}C$ under argon leads to stable isolable nanometric particles. X-ray diffraction analysis of the material indicated that it is constituted of Pd(0). Transmission electron microscopy analysis of the particles dispersed in acetone shows the mean particle size distribution ($4{\pm}1\;nm$). The isolated palladium nanoparticles can be dispersed in an ionic liquid or in methanol or used in solventless condition for selective hydrogenation of 2-hexyne under mild reaction conditions(0.2 MPa and $20^{\circ}C$). The commercial variety of the Lindlar catalyst was also studied for comparative investigations.

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  3. Microcapsules: Particulated Ionic Liquid as A New Material for the Heterogenization of Catalysts vol.26, pp.16, 2014, https://doi.org/10.1021/cm501840d
  4. Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer vol.50, pp.72, 2014, https://doi.org/10.1039/C4CC04183F
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