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http://dx.doi.org/10.5012/bkcs.2010.31.8.2195

Palladium Nanoparticles Suspended in an Ionic Liquid as Reusable Catalyst for Alkyne Semihydrogenation  

Lee, Jin-Kyu (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
Kim, Dae-Won (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
Cheong, Min-Serk (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
Lee, Hyun-Joo (Energy division, Korea Institute of Science and Technology)
Cho, Byung-Won (Energy division, Korea Institute of Science and Technology)
Kim, Hoon-Sik (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
Mukherjee, DebKumar (Department of Chemistry and Research institute for Basic Sciences, Kyung Hee University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.8, 2010 , pp. 2195-2200 More about this Journal
Abstract
The reaction of $PdCl_2$ dispersed in tetra-n-butylammonium bromide with tributyl amine at $120^{\circ}C$ under argon leads to stable isolable nanometric particles. X-ray diffraction analysis of the material indicated that it is constituted of Pd(0). Transmission electron microscopy analysis of the particles dispersed in acetone shows the mean particle size distribution ($4{\pm}1\;nm$). The isolated palladium nanoparticles can be dispersed in an ionic liquid or in methanol or used in solventless condition for selective hydrogenation of 2-hexyne under mild reaction conditions(0.2 MPa and $20^{\circ}C$). The commercial variety of the Lindlar catalyst was also studied for comparative investigations.
Keywords
Palladium; Nanoparticles; Semihydrogenation; Ionic liquid; Lindlar catalyst;
Citations & Related Records
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Times Cited By Web Of Science : 1  (Related Records In Web of Science)
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