• Title/Summary/Keyword: Life Cycle $CO_{2}$

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A Facile Process for Surface Modification with Lithium Ion Conducting Material of Li2TiF6 for LiMn2O4 in Lithium Ion Batteries

  • Kim, Min-Kun;Kim, Jin;Yu, Seung-Ho;Mun, Junyoung;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.223-230
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    • 2019
  • A facile method for surface coating with $Li_2TiF_6$ which has a high lithium-ion conductivity, on $LiMn_2O_4$ spinel cathode material for high performance lithium ion batteries. The surface coating is performed by using a co-precipitation method with $Li_2CO_3$ powder and $H_2TiF_6$ solution under room temperature and atmospheric pressure without special equipment. Total coating amount of $Li_2TiF_6$ is carefully controlled from 0 to 10 wt.% based on the active material of $LiMn_2O_4$. They are evaluated by a systematic combination of analyses comprising with XRD, SEM, TEM and ICP. It is found that the surface modification of $Li_2TiF_6$ is very beneficial to high cycle life and excellent rate capability by reducing surface failure and supporting lithium ions transportation on the surface. The best coating condition is found to have a high cycle life of $103mAh\;g^{-1}$ at the 100th cycle and a rate capability of $102.9mAh\;g^{-1}$ under 20 C. The detail electrochemical behaviors are investigated by AC impedance and galvanostatic charge and discharge test.

A Study on Life-Cycle Environmental Impact of Synthetic Resin Formwork (합성수지 거푸집의 전과정 환경영향평가에 관한 연구)

  • Nam, Kyung-Yong;Yang, Keun-Hyeok;Lee, Young-Do
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.3
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    • pp.245-252
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    • 2020
  • Synthetic resin formwork is made of lightweight high-density polyethylene(HDPE). This study used a process flow chart that satisfies the system boundary (such as Cradle-to- Product shipmen ) required by ISO FDIS 13352 to evaluate the entire process of synthetic resin foam using. The entire life cycle inventory (LCI) database calculated from input energy sources, materials used, transportation methods, and manufacturing processes at the system boundary was analyzed. Based on the environmental impact assessment index methodology of the Ministry of Environment from the LCI data analysis of synthetic resin formwork, the environmental impact assessment was carried out through classification, normalization, characterization, and weighting process. The experimental results are as follows the amount of CO2 (carbon) emission considering the number of conversions was about 32% lower than that of the Euroform. This shows that the use of synthetic resin formwork reduces material production by half compared to Euroform and reduces CO2 (carbon) emissions.

Stable C and N Isotopes: A Tool to Interpret Interacting Environmental Stresses on Soil and Plant

  • Yun, Seok-In;Ro, Hee-Myong
    • Journal of Applied Biological Chemistry
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    • v.51 no.6
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    • pp.262-271
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    • 2008
  • Natural abundances of stable isotopes of nitrogen and carbon (${\delta}^{15}N$ and ${\delta}^{13}C$) are being widely used to study N and C cycle processes in plant and soil systems. Variations in ${\delta}^{15}N$ of the soil and the plant reflect the potentially variable isotope signature of the external N sources and the isotope fractionation during the N cycle process. $N_2$ fixation and N fertilizer supply the nitrogen, whose ${\delta}^{15}N$ is close to 0%o, whereas the compost as. an organic input generally provides the nitrogen enriched in $^{15}N$ compared to the atmospheric $N_2$. The isotope fractionation during the N cycle process decreases the ${\delta}^{15}N$ of the substrate and increases the ${\delta}^{15}N$ of the product. N transformations such as N mineralization, nitrification, denitrification, assimilation, and the $NH_3$ volatilization have a specific isotope fractionation factor (${\alpha}$) for each N process. Variation in the ${\delta}^{13}C$ of plants reflects the photosynthetic type of plant, which affects the isotope fractionation during photosynthesis. The ${\delta}^{13}C$ of C3 plant is significantly lower than, whereas the ${\delta}^{13}C$ of C4 plant is similar to that of the atmospheric $CO_2$. Variation in the isotope fractionation of carbon and nitrogen can be observed under different environmental conditions. The effect of environmental factors on the stomatal conductance and the carboxylation rate affects the carbon isotope fractionation during photosynthesis. Changes in the environmental factors such as temperature and salt concentration affect the nitrogen isotope fractionation during the N cycle processes; however, the mechanism of variation in the nitrogen isotope fractionation has not been studied as much as that in the carbon isotope fractionation. Isotope fractionation factors of carbon and nitrogen could be the integrated factors for interpreting the effects of the environmental factors on plants and soils.

A Study on the Environment Assessment of Waste Polyethylene Terephthalate (PET) by LCA (LCA기법을 이용한 PET의 환경성평가에 관한 연구)

  • Park, Chan-Hyuk;Chung, Jae-Chun;Choi, Suk-Soon;Kim, Sung-Hwan
    • Journal of the Korea Organic Resources Recycling Association
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    • v.13 no.1
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    • pp.115-123
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    • 2005
  • In this study, life cycle assessment(LCA) technique was employed to evaluate the environmental impact of material recycling of polyethylene terephthalate(PET) bottle. Life cycle inventory was established based on the data collected from recycling companies in Korea. Simapro 5.0 LCA software and Eco-indicator 95 index were used for the analysis. The biggest impact by the material recycling of PET bottle on the environmental category was the global warming. It is because melting and production of the recycled PET product consume a significant amount of electricity and energy. In the environmental pollution discharge, $CO_2$ emission was the highest, followed by NOx. This is probably due to the use of diesel and gasoline in the consumption of electricity and transportation. All the environmental impact showed (-) value except the ozone layer depletion, which means that the material recycling of PET bottle is environmentally fair. The use of recycled PET product greatly reduced the environmental impact.

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Comparison of Environmental Impacts of Green and Traditional Buildings using Life Cycle Assessment (전과정평가(LCA)를 이용한 친환경 인증 건축물과 일반 건축물의 환경영향 비교 사례 연구)

  • Hong, Taehoon;Jeong, Kwangbok;Ji, Changyoon
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.3
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    • pp.58-65
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    • 2014
  • This study aims to understand the environmental impact reduction of green buildings that are certified by Green standard for energy and environmental design(G-SEED). To ensure this end, this study assessed and compared the environmental impacts(global warning, ozone layer depletion, acidification, and eutrophication) of a G-SEED-certified elementary school building(green building) and an uncertified elementary school building(traditional building) using the life cycle assessment methodology. This study considered the environmental impacts from the material manufacturing, material transportation, on-site construction, and operation during 40 years. The comparison of the environmental impact intensity of two buildings showed that the green building generated much more environmental impacts than the traditional building. For example, the global warming potential of the green building was approximately 12.5% higher than of the traditional building since the global warming potential of the green building was 3.751 $t-CO_2eq./m^2$ while that of the traditional building was 3.282 $t-CO_2eq./m^2$. It signifies that the G-SEED doesn't guarantee the reduction of the environmental impacts in terms of four impact categories. Therefore, the G-SEED should be complemented and improved to achieve the environmental impact reduction.

Study of Garlic's Carbon Footprint though LCA (전과정평가를 통한 마늘의 탄소배출량 산정연구)

  • Yoon, Sung-Yee;Kim, Young-Ran;Kim, Tae-Ho;Park, Jin-Hyun;Ahn, Sung-Woo
    • Korean Journal of Organic Agriculture
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    • v.20 no.2
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    • pp.161-172
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    • 2012
  • This study was carried out to estimate carbon footprint and to establish of LCA of garlic production system. We have case study in cultivate garlic 1 kg calculate in carbon footprint. LCA carried out to estimate carbon footprint and to establish of LCI (life cycle inventory) database of garlic production system. The data is from Research of Farmer's income in 2010 (RDA, 2011), and used Pass (5.0.0) program. The value of fertilizer, amount of pesticide input were shown the environmental effect and direct emission. Carbon footprint in agriculture guarantees the choice right the consumer to choose the lower carbon goods. Its can make to strengthen of agriculture and food industry's reduction effort of $CO_2$. Nowadays consumer requests food's safety and environment friendly process. Carbon footprint also needs consumer's relief and incentives.

Environmental assessment of a BIPV system

  • Demetrios N. Papadopoulos;Constantinos N. Antonopoulos;Vagelis G. Papadakis
    • Advances in Energy Research
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    • v.8 no.1
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    • pp.1-19
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    • 2022
  • The application of Photovoltaic (PV) power in the building sector, is expanding as part of the ongoing energy transition into renewables. The article addresses the question of sustainability of energy generated from PVs through an environmental assessment of a building-integrated PV system (BIPV) connected to the grid through net metering. Employing retrospective life cycle analysis (LCA), with the CCaLC2 software and ecoinvent data, the article shows that the carrying structure and other balance of system (BOS) components are responsible for a three times higher energy payback time than the literature average. However, total environmental impact can be lowered through reuse or reinstallation of PVs on the same building structure after the 30-year interval. Further ways to improve environmental efficiency include identifying the most polluting materials for each LCA parameter. The results of this study are of interest to researchers and producers of PVs and organizations investing and promoting decentralized power production through PVs.

LCA (Life Cycle Assessment) for Evaluating Carbon Emission from Conventional Rice Cultivation System: Comparison of Top-down and Bottom-up Methodology (관행농 쌀 생산체계의 탄소배출량 평가를 위한 전과정평가: top-down 방식의 국가평균값과 bottom-up 방식의 사례분석값 비교)

  • Ryu, Jong-Hee;Jung, Soon Chul;Kim, Gun-Yeob;Lee, Jong-Sik;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.1143-1152
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    • 2012
  • We established a top-down methodology to estimate carbon footprint as national mean value (reference) with the statistical data on agri-livestock incomes in 2007. We also established LCI (life cycle inventory) DB by a bottom-up methodology with the data obtained from interview with farmers from 4 large-scale farms at Gunsan, Jeollabuk-do province to estimate carbon footprint in 2011. This study was carried out to compare top-down methodology and bottom-up methodology in performing LCA (life cycle assessment) to analyze the difference in GHGs (greenhouse gases) emission and carbon footprint under conventional rice cultivation system. Results of LCI analysis showed that most of $CO_2$ was emitted during fertilizer production and rice cultivation, whereas $CH_4$ and $N_2O$ were mostly emitted during rice cultivation. The carbon footprints on conventional rice production system were 2.39E+00 kg $CO_2$-eq. $kg^{-1}$ by top-down methodology, whereas 1.04E+00 kg $CO_2$-eq. $kg^{-1}$ by bottom-up methodology. The amount of agro-materials input during the entire rice cultivation for the two methodologies was similar. The amount of agro-materials input for the bottom-up methodology was sometimes greater than that for top-down methodology. While carbon footprint by the bottom-up methodology was smaller than that by the top-down methodology due to higher yield per cropping season by the bottom-up methodology. Under the conventional rice production system, fertilizer production showed the highest contribution to the environmental impacts on most categories except GWP (global warming potential) category. Rice cultivation was the highest contribution to the environmental impacts on GWP category under the conventional rice production system. The main factors of carbon footprints under the conventional rice production system were $CH_4$ emission from rice paddy field, the amount of fertilizer input and rice yield. Results of this study will be used for establishing baseline data for estimating carbon footprint from 'low carbon certification pilot project' as well as for developing farming methods of reducing $CO_2$ emission from rice paddy fields.

Analysis of environmental impact of activated carbon production from wood waste

  • Kim, Mi Hyung;Jeong, In Tae;Park, Sang Bum;Kim, Jung Wk
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.117-126
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    • 2019
  • Activated carbon is carbon produced from carbonaceous source materials, such as coconut shells, coals, and woods. In this study, an activated carbon production system was analyzed by carbonization and activation in terms of environmental impact and human health. The feedstock of wood wastes for the system reduced fossil fuel consumption and disposal costs. Life cycle assessment methodology was used to analyze the environmental impacts of the system, and the functional unit was one tonne of wood wastes. The boundary expansion method was applied to analyze the wood waste recycling process for activated carbon production. An environmental credit was quantified by avoided impact analysis. Specifically, greenhouse gases discharged from 1 kg of activated carbon production system by feeding wood wastes were evaluated. We found that this system reduced global warming potential of approximately $9.69E+00kg\;CO_2-eq$. compared to the process using coals. The environmental benefits for activated carbon production from wood wastes were analyzed in contrast to other disposal methods. The results showed that the activated carbon system using one tonne of wood wastes has an environmental benefit of $163kg\;CO_2-eq$. for reducing global warming potential in comparison with the same amount of wood wastes disposal by landfilling.