• 제목/요약/키워드: Li Diffusion

검색결과 261건 처리시간 0.028초

ON THE RATIO OF BIOMASS TO TOTAL CARRYING CAPACITY IN HIGH DIMENSIONS

  • Heo, Junyoung;Kim, Yeonho
    • 대한수학회지
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    • 제58권5호
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    • pp.1227-1237
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    • 2021
  • This paper is concerned with a reaction-diffusion logistic model. In [17], Lou observed that a heterogeneous environment with diffusion makes the total biomass greater than the total carrying capacity. Regarding the ratio of biomass to carrying capacity, Ni [10] raised a conjecture that the ratio has a upper bound depending only on the spatial dimension. For the one-dimensional case, Bai, He, and Li [1] proved that the optimal upper bound is 3. Recently, Inoue and Kuto [13] showed that the supremum of the ratio is infinity when the domain is a multi-dimensional ball. In this paper, we generalized the result of [13] to an arbitrary smooth bounded domain in ℝn, n ≥ 2. We use the sub-solution and super-solution method. The idea of the proof is essentially the same as the proof of [13] but we have improved the construction of sub-solutions. This is the complete answer to the conjecture of Ni.

액체 카드뮴 음극을 사용한 용융염 전해제련로 전산해석 (Computational Analysis for a Molten-salt Electrowinner with Liquid Cadmium Cathode)

  • 김광락;정용주;백승우;김지용;권상운;윤달성;김시형;심준보;김정국;안도희;이한수
    • 방사성폐기물학회지
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    • 제8권1호
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    • pp.1-7
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    • 2010
  • 본 연구에서는 LiCl-KCl/Cd계의 전해제련 공정을 대상으로 악티늄 및 희토류족 원소들의 전해이동을 모델링하고 해석하였다. 이 공정에서 용융염 전해질과 액체 카드뮴 음극간의 확산 경계층 계면에서 확산제한 전기화학반응 및 물질수지를 고려한 단순화된 동적모델을 수립하였다. 제안된 모델링 접근방법은 음극에서 일어나는 금속염의 반쪽 전지 환원반응에 기초를 둔 모델이다. 이 모델을 사용하여 정전류 전해공정에서 주어진 인가전류 조건을 만족하는 시간까지의 전해이동과 연계된 농도거동, 각 원소의 패러데이 전류 그리고 시간 함수의 전기화학 전위를 예측하는 가능성을 보여주었다. 선택된 5성분 원소(U, Pu, Am, La, Nd)계의 결과를 예비 모사하여 전산모델이 전기화학적 특성을 이해하고 개선된 전해제련로를 개발하기 위한 정보를 제공할 수 있는가를 평가하였다.

리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성 (Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries)

  • 박종완
    • 한국재료학회지
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    • 제16권5호
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    • pp.297-301
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    • 2006
  • Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.

인가주파수에 따른 결합형 광변조기 특성변화 (Characterization of coupling optical modulator to the applied frequency)

  • 강기성
    • E2M - 전기 전자와 첨단 소재
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    • 제9권6호
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    • pp.584-592
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    • 1996
  • Coupling optical modulator which on the $LiTaO_3$ substrate is fabricated by using proton exchange method and self-aligned method. Proton exchange of proton diffusion method was applied to pattern a waveguide on $LiTaO_3$ substrate. The annealing at >$400^{\circ}C$ was carded out to control waveguide width and depth. The depths of the two annealed optical waveguides, which were measured by using .alpha.-step, were 1.435 K.angs. and 1.380 K.angs. Using .alpha.-step facility, we examined that the width of waveguides is increased from 5.mu.m to 6.45 .mu.m and 6.3.mu.m due to the annealing effects. The process of proton exchange was done at 150.deg. C for 120 min, >$200^{\circ}C$ for 60 min and annealing process was done at >$400^{\circ}C$ for 90 min, >$400^{\circ}C$ for 60 min. The high speed coupling optical modulator has very good figures of merits; the measured high frequency power were achieved.

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고주파에서 방향성결합형 광 스위치의 출력 특성변화 (Characterization of directional coupling optical switch at High frequency)

  • 강기성;소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.264-268
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    • 1996
  • Directional coupling optical switch which on the LiNbO$_3$ substrate is fabricated by using proton exchange method and self-aligned method. Proton exchange of proton diffusion method was applied to pattern a waveguide on LiNbO$_3$ substrate. The annealing at 400[$^{\circ}C$] was caroled out to control waveguide width and depth. The process of proton exchange was done at 150[$^{\circ}C$] for 120[min], 200[$^{\circ}C$] for 60[min] and annealing process was done at 400[$^{\circ}C$] for 90[min], 400[$^{\circ}C$] for 60[min]. The high speed directional coupling optical switch has very good figures of merits:the measured high frequency power were achieved.

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Lifetime Evaluation of AI-Fe Coating in Wet-seal Environment of MCFC

  • Jun, JaeHo;Jun, JoongHwan;Kim, KyooYoung
    • Corrosion Science and Technology
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    • 제3권4호
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    • pp.161-165
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    • 2004
  • Aluminum source in an Al-Fe coating reacts with molten carbonate and develops a protective $LiAlO_2$ layer on the coating surface during operation of molten carbonate fuel cells (MCFC). However, if aluminum content in an Al-Fe coating decreases to a critical level for some reasons during MCFC operation, a stable and continuous $LiAlO_2$ protective layer can no longer be maintained. The aluminum content in an Al-Fe coating can be depleted by two different processes; one is by corrosion reaction at the surface between the aluminum source in the coating and molten carbonate, and the other is inward-diffusion of aluminum atoms within the coating into a substrate. In these two respects, therefore, the decreasing rate of aluminum concentration in an Al-Fe coating was measured, and then the influences of these two aspects on the lifetime of Al-Fe coating were investigated, respectively.

GROWTH AND CHARACTERIZATIONS OF $La_3Ga_5SiO_{14}$ SINGLE CRYSTALS AND SINTERED BODY FOR THE APPLICATIONS OF FILER AND RESONATOR

  • Jung, Il-Hyoung;Kyung Joo;Shim, Kwang-Bo;Auh, Keun-Ho
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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    • pp.73-77
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    • 1998
  • Langasite(La3Ga5SiO14) is a new piezoelectric material which is similar to quartz, LN(LiNbO3) and LT(LiTaO3) in its acoustic behavior. In this study, pure Langasite and Langasite family groups were synthesized by the solid state reactions in air. For the synthesis process, diffusion species were investigated and sintered body of synthesized powders were studied on dielectric property according to surface microstructures.

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전극구조설계 기반 고에너지밀도·고속충전 리튬이온배터리 제작 (Design of Structured Electrode for High Energy Densified and Fast Chargeable Lithium Ion Batteries)

  • 박수진;배창준
    • 세라미스트
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    • 제21권4호
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    • pp.406-415
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    • 2018
  • Lithium ion batteries have been widely adopted as energy storage and the LIB global market has grown fastest. However, LIB players have struggled against maximizing energy density since commercial monolithic electrodes are limited by electrolyte depletion caused by long and tortuous Li-ion diffusion pathways. Recently, new strategies designing the structure of battery electrodes strive for creating fast Li-ion path and alleviating electrolyte depletion problem in monolithic electrodes. In this paper, given the fundamental and experimental approaches, we compare the monolithic to structured electrodes and demonstrate the ways to fabricate high energy, fast chargeable Lithium ion battery.

Electrochemical Behavior of Tm ion and Bi ion in LiCl-KCl Molten Salt

  • Kim, Beom-Kyu;Han, Hwa Jeong;Park, Ji Hye;Kim, Won Ki;Park, Byung Gi
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2017년도 추계학술논문요약집
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    • pp.83-84
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    • 2017
  • This study, electrolytic behavior of Thulium and Tm-Bi ion system was studied. The electrochemical behavior of Tm was studied in $LiCl-KCl-TmCl_3$ molten salts using electrochemical techniques Cyclic Voltammetry on tungsten electrodes at 773K. During the process of CV and SWV, intermetallic compound were observed Bi-Tm. Further study, in order to determine clarity of diffusion coefficient in this experiment, we will compare result of electrochemistry method and we also need to quantitative research.

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Electrochemical behavior of dissolved hydrogen at Pt electrode surface in a high temperature LiOH-H3BO3 solution: Effect of chloride ion on the transient current of the dissolved hydrogen

  • Myung-Hee Yun;Jei-Won Yeon
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3659-3664
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    • 2023
  • The electrochemical behavior of dissolved hydrogen (H2) was investigated at a Pt electrode in a high temperature LiOH-H3BO3 solution. The diffusion current of the H2 oxidation was proportional to the concentration of the dissolved H2 as well as the reciprocal of the temperature. In the polarization curve, a potential region in which the oxidation current decreases despite an increase in the applied potential between the H2 oxidation and the water oxidation regions was observed. This potential region was interpreted as being caused by the formation of a Pt oxide layer. Using the properties of the Cl- ion that reduces the growth rate of the Pt oxide layer, it was confirmed that there is a correlation between the Cl- ion concentration and the transient current of the H2 oxidation.