• Title/Summary/Keyword: Layer charge density

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Electrochemical Properties of $V_2O_5$ Electrodes as a Function of Additon of Carbon for Film Supercapacitor (Film형 Supercapacitor용 $V_2O_5$전극의 Carbon 첨가에 따른 전기화학적 특성)

  • Kim, Myung-San;Kim, Jong-Uk;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.39-41
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    • 2000
  • Carbon is an attractive candidate for use in eletrochemical supercapacitors that depend on charge storage in the electrode/eletorlyte international double layer. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that $V_2O_5$-carbon (SP270) composite electrode for supercapacitor. The discharge capacitance of $V_2O_5$-SP270 (20wt%) in 1st and 35cyc1e was 14F/g and 8.5F/g at current density of $0.1mA/cm^2$. The discharge process of $V_2O_5$-SP270 (20wt%) composite electrode is larger than that others.

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Method of Minimizing ESS Capacity for Mitigating the Fluctuation of Wind Power Generation System (풍력발전의 출력 변동 저감을 위한 ESS 최소용량 산정기법)

  • Kim, Jae-Hong;Kang, Myeong-Seok;Kim, Eel-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.31 no.5
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    • pp.119-125
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    • 2011
  • In this paper, we have studied about minimizing the Energy Storage System (ESS) capacity for mitigating the fluctuation of Wind Turbine Generation System (WTGS) by using Electric Double Layer Capacitor (EDLC) and Battery Energy Storage System (BESS). In this case, they have some different characteristics: The EDLC has the ability of generating the output power at high frequency. Thus, it is able to reduce the fluctuation of WTGS in spite of high cost. The BESS, by using Li-Ion battery, takes the advantage of high energy density, however it is limited to use at low frequency response. To verify the effectiveness of the proposed method, simulations are carried out with the actual data of 2MW WTGS in case of worst fluctuation of WTGS is happened. By comparing simulation results, this method shows the excellent performance. Therefore, it is very useful for understanding and minimizing the ESS capacity for mitigating the fluctuation of WTGS.

A Study on ALD $Al_2O_3$ Films for Rear Surface Passivation of Crystalline Silicon Solar Cells (결정질 태양전지의 후면 패시베이션을 위한 ALD $Al_2O_3$ 막 연구)

  • Roh, Si-Cheol;Seo, Hwa-Il
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.1
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    • pp.57-61
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    • 2011
  • To develop high efficiency crystalline solar cells, the rear surface passivation is very important. In this paper, $Al_2O_3$ films deposited by thermal ALD(atomic layer deposition) method were studied for rear surface passivation of crystalline solar cells and their passivation properties were evaluated. After the deposition of $Al_2O_3$ films on p-type Si wafers, the lifetime was increased very much due to the reduction of interface state density and the field effects of the negative fixed charge in the films. Also, optimum annealing condition and effects of SiNx capping layer were investigated. The best lifetime was obtained when the films were annealed at $400^{\circ}C$ for 15min. And the lifetime degradation of the $Al_2O_3$ films with SiNx capping layers was improved compared to those without the capping layers.

Electrical Properties and Temperature Effects of PET Films with Interface Layers

  • Dong-Shick kim;Lee, Kwan-Woo;Park, Dae-Hee;Lee, Jong-Bok;Seun Hwangbo
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.4
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    • pp.25-29
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    • 2000
  • In this paper, PET(Ployethylene Terephthalate) films with semiconducting and interface layers were investigated, The electrical properties, such as volume resistivity, tan$\delta$(dissipation factor) and breakdown strength at various temperatures were measured. Thermal analysis of PET and semiconducting films were measured and compared by differential scanning calorimeter(DSC) of each film. It is found that the volume resistivity of films(dependence on semiconducting interface layers)and electrical properties of PET films are changed ,Breakdown strength and dissipation factor of PET films with semiconducting layer (PET/S/PET) are decreased more greatly than PET and PET/PET films, due to the increase of charge density of charges at two contacted interfaces between PET and semiconductor, The dissipation factor of each films in increased with temperature,. For PET/S/PET film, is depended on temperature more than PET of PET/PET. However, the breakdown strength is increased up to 85$\^{C}$ and then decreased over 100$\^{C}$The electrical properties of PET films with semiconducting/interface layer are worse than without it It is due to a result of temperature dependency, which deeply affects thermal resistance property of PET film more than semiconducting/interface layers.

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A Polycrystalline CdZnTe Film and Its X-ray Response Characteristics for Digital Radiography

  • Kim, Jae-Hyung;Park, Chang-Hee;Kang, Sang-Sik;Nam, Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.5
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    • pp.15-18
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    • 2003
  • The Cd$\_$1-x/Zn$\_$x/Te film was produced by thermal evaporation for the flat-panel X-ray detector. The crystal structure and the surface morphology of poly crystalline Cd$\_$1-x/Zn$\_$x/Te film were examined using XRD and SEM, respectively. The leakage current and X-ray sensitivity of the fabricated films were measured to analyze the X-ray response characteristic of Zn in a polycrystalline CdZnTe thin film. The leakage current and the output charge density of Cd$\_$0.7/Zn$\_$0.3/Te thin film were measured to 0.3 1nA/$\textrm{cm}^2$ and 260 pC/$\textrm{cm}^2$ at an applied voltage of 2.5 V/$\mu\textrm{m}$, respectively. Experimental results showed that the increase of Zn doping rates in Cd$\_$1-x/Zn$\_$x/Te detectors reduced the leakage current and improved the X-ray sensitivity significantly. The leakage current was drastically diminished by the formation of thin parylene layer in the Cd$\_$0.7/Zn$\_$0.3/Te detector.

Study of Self-assembled Organic Layer Formation at the HATCN/Au Interface

  • Kim, Ji-Hoon;Won, Sangyeon;Kwon, Young-Kyun;Kahng, Se-Jong;Park, Yongsup
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.150.2-150.2
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    • 2013
  • We elucidate the mechanism of the self-assembled organic layer formation at the organic/metal interface of hexaaza-triphenylene-hexacarbonitrile (HATCN)/Au(111) by first-principles calculations and Lowtemperature scanning tunneling microscope (STM). In this work, we used HATCN to deposit organic material which is well known as an efficient OLED charge generation material. Low-temperature STM measurements revealed that self-assembled hexagonal porous structure is formed at terraces of Au(111). We also found that the hexagonal porous structure has chirality and forms only small (<1000 $nm^2$) phaseseparated chiral domains that can easily change their chiral phase in subsequence STM images at 80 K. To explain the mechanism of these observation, we calculated the molecular-molecular and molecule-surface interaction energies by using density functional theory method. We found that the change of their chiral phase resulted from the competition between the two energies. These results have not only verified our experimental observations, but also revealed the delicate balance between different interactions that caused the self-assembed structures at the surface.

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Study for Improved Photocurrent via High Concentrated Tin-lead Perovskite Precursor Solution (주석-납 기반 페로브스카이트 고농도 전구체 용액을 이용한 광전류 향상 연구)

  • Hyojin Hong;Seungmin Lee;Jeong Min Im;Jun Hong Noh
    • Current Photovoltaic Research
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    • v.11 no.3
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    • pp.96-102
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    • 2023
  • Sn-Pb narrow-bandgap perovskite solar cells, which is a light-harvesting layer thicker than 1.3 micrometers, is needed to enhance the low photocurrent. The fabrication of such a thick film through solution processing is a key challenge. Here, we studied and characterized the film by using a precursor solution of increased concentration, comparing it with the universally used 1-micrometer Sn-Pb perovskite film. The increase in molar concentration clearly induced thickness enhancement, but we observed that it also created numerous voids at the interface with bottom charge transporting layer. We hypothesized that these voids might hinder the increase in photocurrent associated with thickness enhancement. By introducing methylammonium chloride (MACl), we successfully fabricated Sn-Pb perovskite film with a thickness of 1.3 micrometer and no voids. Void-controlled Sn-Pb perovskite solar cells not only demonstrated superior short-circuit current density compared to those with voids but also operated smoothly under light exposure.

Characteristics of Si Nano-Crystal Memory

  • Kwangseok Han;Kim, Ilgweon;Hyungcheol Shin
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.1 no.1
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    • pp.40-49
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    • 2001
  • We have developed a repeatable process of forming uniform, small-size and high-density self-assembled Si nano-crystals. The Si nano-crystals were fabricated in a conventional LPCVD (low pressure chemical vapor deposition) reactor at $620^{\circ}c$ for 15 sec. The nano-crystals were spherical shaped with about 4.5 nm in diameter and density of $5{\times}l0^{11}/$\textrm{cm}^2$. More uniform dots were fabricated on nitride film than on oxide film. To take advantage of the above-mentioned characteristics of nitride film while keeping the high interface quality between the tunneling dielectrics and the Si substrate, nitride-oxide tunneling dielectrics is proposed in n-channel device. For the first time, the single electron effect at room temperature, which shows a saturation of threshold voltage in a range of gate voltages with a periodicity of ${\Delta}V_{GS}\;{\approx}\;1.7{\;}V$, corresponding to single and multiple electron storage is reported. The feasibility of p-channel nano-crystal memory with thin oxide in direct tunneling regime is demonstrated. The programming mechanisms of p-channel nano-crystal memory were investigated by charge separation technique. For small gate programming voltage, hole tunneling component from inversion layer is dominant. However, valence band electron tunneling component from the valence band in the nano-crystal becomes dominant for large gate voltage. Finally, the comparison of retention between programmed holes and electrons shows that holes have longer retention time.

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The Effect of Neutron Radiation on the Electrical Characteristics of SiC Schottky Diodes (중성자 조사에 따른 SiC Schottky Diode의 전기적 특성 변화)

  • Kim, Sung-Su;Kang, Min-Seok;Cho, Man-Soon;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.4
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    • pp.199-202
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    • 2014
  • The effect of neutron irradiation on the properties of SiC Schottky Diode has been investigated. SiC Schottky diodes were irradiated under neutron fluences and compared to the reference samples to study the radiation-induced changes in device properties. The condition of neutron irradiation was $3.1{\times}10^{10}$ $n/cm^2$. The current density after irradiation decreased from 12.7 to 0.75 $A/cm^2$. Also, a slight positive shift (${\Delta}V_{th}$= 0.15 V) in threshold voltage from 0.53 to 0.68 V and a positive change (${\Delta}{\Phi}_B$= 0.16 eV) of barrier height from 0.89 to 1.05 eV have been observed by the neutron irradiation, which is attributed to charge damage in the interface between the metal and the SiC layer.

Preparation and Electrochemical Characteristics of DAAQ/CNFs Composite electrode for Supercapacitor (DAAQ가 코팅된 슈퍼커패시터용 CNFs전극 활물질의 제조 및 전기 화학적 특성)

  • Kim, Hong-Il;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1226-1229
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    • 2004
  • Supercapacitors, also known as electrochemical capacitors, are being extensively studied due to an increasing demand for energy-storage systems. These devices offer many advantages over conventional secondary batteries, which include the ability of fast charge propagation, long cycle-life and better storage efficiency. That is to say supercapacitor bridges the gap between conventional capacitors and batteries. A new type electric double layer capacitor (EDLC) also called supercapacitors. Recently, supercapacitors concerns about their high power density and energy density. So we experiment with EDLC by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. The electrode for supercapacitor was prepared by synthesis of DAAQ covered CNFs. CNFs could be covered with very thin DAAQ oligomer from the results of CV, XRD, DSC, SEM images, and TEM images. Dissolved electrode active material in NMP solution has been drop-coated on carbon plate. Its electrochemical characteristics were investigated by cyclic voltammograms. And compared with different electrolyte of aqueous type. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors with respect to specific capacity and scan rate dependency.

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