• Carbon letters
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• 제1권1호
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• pp.22-26
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• 2000

Raman spectroscopy has been used to investigate the structure of coal tar pitch heat-treated up to $3000^{\circ}C$ by using 514.5 run Ar ion laser line. Four critical temperature ranges were found on pyrolyzing coal tar pitch, which correspond to four distinct processes from disordered carbons to the well-ordered graphite structure. The range of heat treat temperature (HTT) below $1000^{\circ}C$ corresponds to gas evolution during the pyrolysis of coal tar pitch. Above the HTT are correlated to rearrangements of enlarged molecules, growth of the molecules along the direction of plane, finally stacking in the normal direction of the plane, in the respective HTT ranges of 1000-2000, above 2000 and $2500-3000^{\circ}C$.

• Applied Science and Convergence Technology
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• 제27권2호
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• pp.42-45
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• 2018

Photovoltaic and optoelectronic devices based on hybrid metal halide perovskites ($MAPbX_3$; $MA=CH_3NH_3{^+}$, $X=Cl^-$, $Br^-$, or $I^-$) are rapidly improving in power conversion efficiency. Also, during recent years, perovskite single crystals have emerged as promising materials for high-efficiency photovoltaic and optoelectronic devices because of their low defect density. Here we show that the light soaking effect of mixed halide perovskite ($MAPbBr_{3-x}I_x$) single crystals can be explained using photoluminescence, time-resolved photoluminescence, and Raman scattering measurements. Unlike Br-based single crystal, Br/I mixed single crystal show a strong light soaking effect under laser irradiation condition that was related to the existence of multiple phases.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.249-249
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• 2013

Surface-enhanced Raman spectroscopy (SERS) is a sensitive approach to detect and to identify a variety of molecules. To enhance the Raman signal, optimization of the gap between nanostructures is quite important. One-dimensional materials such as nanowires, nanotubes, and nanograsses have great potential to be used in SERS due to their unique sizes and shape dependent characteristics. In this study we investigate a simple way to fabricate SERS substrates based on randomly grown copper oxide (CuO) nanowires. CuO nanograss is fabricated on pre-cleaned Cu foils. Cu oxidized in an ammonium ambient solution of 2.5 M NaOH and 0.1 M $(NH_4)_2S_2O_8$ at $4^{\circ}C$ for 10, 30, and 60 minutes. Then, Cu(OH)2 nanostructures are formed and dried at $180^{\circ}C$ for 2 h. With the drying process, the Cu(OH)2 nanostructure is transformed to CuO nanograss by dehydration reaction. CuO nanograss are grown randomly on Cu foil with the average length of 10 ${\mu}m$ and the average diameter of a 100 nm. CuO nanograsses are covered by Ag with various thicknesses from 10 to 30 nm using a thermal evaporator. Then, we immerse uncoated and Ag coated CuO nanowire samples of various oxidation times in a 0.001M methanol-based 4-mercaptopyridine (4-Mpy) in order to evaluate SERS enhancement. Raman shift and SERS enhancement are measured using a Raman spectrometer (Horiba, LabRAM ARAMIS Spectrometer) with the laser wavelength of 532 nm. Raman scattering is believed to be enhanced by the interaction between CuO nanograss and Ag island film. The gaps between Ag covered CuO nanograsses are diverse from <10 nm at the bottom to ~200 nm at the top of nanograsses. SERS signal are improved where the gaps are minimized to near 10s of nanometers. There are many spots that provide sufficiently narrow gap between the structures on randomly grown CuO nanograss surface. Then we may find optimal enhancement of Raman signal using the mapping data of average results. Fabrication of CuO nanograss based on a solution method is relatively simple and fast so this result can potentially provide a path toward cost effective fabrication of SERS substrate for sensing applications.

• 한국광학회지
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• 제7권2호
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• pp.142-149
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• 1996

대향류버너의 화염에서 연소반응의 중간단계 생성물로 존재하는 OH라디칼의 축퇴 4광자 혼합스팩트럼을 비포화영역에서 Forward Box 형태의 위상정합조건으로 측정하였다. X$^{2}$.PI..rarw.A$^{2}$.SIGMA.$^{+}$ 천이선들 중 R$_{1}$-가지 분광선들의 세기로부터 회전에너지 준위의 밀도분포를 구하고 볼쯔만분포와 비교하여 온도를 구하였다. 흡수분광스펙트럼을 측정하여 화염내에서 레이저의 흡수효과를 보정하여 주었다. 측정된 온도의 오차는 2000K 근방에서 .+-.60K로서 CARS로 얻은 온도와 오차범위내에서 일치하였다. 화염의 여러부분에서 스펙트럼을 측정하여 온도분포와 OH농도분포를 얻었다.

• ETRI Journal
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• 제26권1호
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• pp.38-44
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• 2004

Searching for systems of self-assembled monolayers (SAMs) that can be used as templates for chemical lithography, we found that nitro groups on aromatic SAMs are selectively converted on Ag to amino groups by irradiation with a visible laser. 4-nitrobenzenethiol on Ag was thus converted to 4-aminobenzenethiol by irradiating it with an $Ar^+$ laser. This was evident from surface-enhanced Raman scattering (SERS) as well as from a coupling reaction forming amide bonds. The surface-induced photoreaction allowed us to prepare patterned binary monolayers on Ag that showed different chemical reactivities. Using the binary monolayers as a lithographic template, we induced site-specific chemical reactions, such as the selective growth of biominerals on either the nitro- or amine-terminated regions by adjusting the crystal-growth conditions. We also demonstrated that patterned, amine-terminated monolayers can be fabricated even on gold by using silver nanoparticles as photoreducing catalysts.

• 한국광학회지
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• 제32권4호
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• pp.147-152
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• 2021

본 논문에서는 최고 출력 3.0 kW 발진 단일 모드 이터븀(ytterbium, Yb) 첨가 광섬유 레이저에 대해 보고한다. 고출력 광섬유 레이저의 출력을 제한하는 주된 요소인 유도 라만 산란 문턱 값과 광섬유 내 온도 분포를 계산하고 이를 바탕으로 양방향 펌핑 구조의 단일 공진기 Yb 광섬유 레이저 시스템을 제작하였다. 그 결과 4.1 kW의 펌프 출력에서 최고 출력 3.0 kW의 레이저 빔을 얻을 수 있었고, 그때의 기울기 효율은 81.5%로 계산되었다. 최고 출력에서 측정된 출력 빔의 빔질(M²)은 1.26으로 단일 공간 모드 빔 출력 특성을 가지고 있음을 확인하였고, 유도 라만 산란 및 횡모드 불안정 현상은 관측되지 않았다. 본 연구에서 얻은 광섬유 레이저 출력 결과는 지금까지 국내에서 보고된 다이오드 레이저로 펌핑한 광섬유 레이저 출력 중 가장 높은 출력이며, 향후 더 높은 출력을 얻기 위한 방법에 대해 논의하고자 한다.

• 반도체디스플레이기술학회지
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• 제18권4호
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• pp.51-56
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• 2019

LuAG:Ce(Lu₃Al₅O₁₂:Ce³⁺) nano phosphor were synthesized by applying the coprecipitation method. It is used to increase the color rendering of phosphor ceramic plate for high power LEDs and laser lighting. Internal quantum efficiency and absorption of LuAG:Ce nano phosphor are 51.5 % and 64.4 %, respectively, which is higher than the previously studied nano phosphors. The maximum absorption wavelength of this phosphor is 450 nm blue light, and the emission wavelength is 510 nm. The emission wavelength shifted to longer wavelength when the concentration of Ce increased in the heat treatment of the reducing atmosphere. Thermal quenching of LuAG nano phosphor was 70 % at 200 ℃, it was explained by their significant quenching of all raman scattering modes, implying the restriction of electron-phonon couplings caused by their defects.

• Journal of the Optical Society of Korea
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• 제18권5호
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• pp.551-557
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• 2014

In this study, we demonstrated multimodal nonlinear optical (NLO) microscopy integrated simultaneously with two-photon excitation fluorescence (TPEF), second-harmonic generation (SHG), and coherent anti-Stokes Raman scattering (CARS) in order to obtain targeted cellular and label-free images in an immunofluorescence assay of the atherosclerotic aorta from apolipoprotein E-deficient mice. The multimodal NLO microscope used two laser systems: picosecond (ps) and femtosecond (fs) pulsed lasers. A pair of ps-pulsed lights served for CARS (817 nm and 1064 nm) and SHG (817 nm) images; light from the fs-pulsed laser with the center wavelength of 720 nm was incident into the sample to obtain autofluorescence and targeted molecular TPEF images for high efficiency of fluorescence intensity without cross-talk. For multicolor-targeted TPEF imaging, we stained smooth-muscle cells and macrophages with fluorescent dyes (Alexa Fluor 350 and Alexa Fluor 594) for an immunofluorescence assay. Each depth-sectioned image consisted of $512{\times}512$ pixels with a field of view of $250{\times}250{\mu}m^2$, a lateral resolution of $0.4{\mu}m$, and an axial resolution of $1.3{\mu}m$. We obtained composite multicolor images with conventional label-free NLO images and targeted TPEF images in atherosclerotic-plaque samples. Multicolor 3-D imaging of atherosclerotic-plaque structural and functional composition will be helpful for understanding the pathogenesis of cardiovascular disease.

• 한국지반공학회논문집
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• 제23권4호
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• pp.15-24
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• 2007

본 연구에서는 여러 지점의 온도를 동시에 측정할 수 있는 두 가지 온도 모니터링 기법을 소개하고 있다. 그 하나는 고유주소를 가지고 있는 온도센서로 구성된 온도센서 배열 케이블을 이용하는 기법이며, 다른 하나는 광섬유 센서를 이용하여 분포 온도를 측정하는 기법이다. 이 두 기법의 차이점은 다음과 같이 요약될 수 있다. 온도센서 배열 케이블은 온도센서가 위치하는 정확한 지점의 온도를 측정하게 된다. 그에 대한 온도 측정의 정밀도 및 분해능은 그 온도 센서의 성능에 따라 결정된다. 한편, 광섬유 센서는 레이저 펄스가 광섬유를 따라 보내질 때 생성되는 Raman 역산란파를 분석함으로써 온도를 측정하기 때문에 분포 개념의 온도를 측정하게 된다. 그에 대한 온도 분해능은 측정거리, 측정시간 및 온도측정 거리분해능에 따라 결정된다. 본 논문은 두 가지 온도 모니터링 시스템의 장단점을 비교함으로써 기술적이고 경제적인 측면에서 그의 응용분야를 면밀히 검토하는 데 그 목적이 있다. 이를 위해 두 기법을 이용한 다양한 실험을 실시하였다. 그 결과를 검토해 보면 온도센서 배열 케이블은 300m 범위 내의 지하수 흐름, 지열 분포 및 그라우팅 효과 검증에 적합할 것으로 판단되며 광섬유 센서는 상대적으로 긴 거리에 걸친 분포 온도에 대한 정보가 필요한 파이프 파인 감시, 터널 화재 감시 및 전력선 모니터링과 같은 분야에서 효율적으로 활용될 것이 기대된다.