• Title/Summary/Keyword: KCL-2

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Effect of Mechanical Polishing Pretreatment on Tribological Properties of Manganese Phosphate Coating of Carbon Steel (기계적 연마 전처리가 인산망간 피막의 윤활 특성에 미치는 영향)

  • Kim, Ho-Young;Noh, Young-Tai;Jeon, Jun-Hyuck;Kang, Ho-Sang
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.350-356
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    • 2019
  • In this study, the effect of mechanical polishing of carbon steel on the tribological properties of manganese phosphate coating on carbon steel has investigated. The microstructure, surface morphology and chemical composition were analyzed by SEM, EDS, and XRD. The surface roughness test was carried out in order to calculate Rvk value by 3D laser microscopy. Also, the tribology property of manganese phosphate coating was tested by ball-on disk. In the results of EDS analysis, coating layer consists of elements such in Mn, P, Fe, and O. XRD showed that (Mn,Fe)5H2(PO4)4·4H2O in manganese phosphate coating layer was formed by the chemical reaction between manganese phosphate and elements in carbon steel. As the mechanical polishing degree increased, the friction coefficient was reduced. The rougher the mechanical polishing degree, the better corrosion resistance was obtained.

Initial Particle Size Effects on Sintering and Dielectric Properties of $Pb>(Fe_1/2Nb_1/2)O_3$ (초기입자크기가 $Pb>(Fe_1/2Nb_1/2)O_3$의 소결 및 유전성에 미치는 영향)

  • 박경봉;김태희;윤기현
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.711-718
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    • 1992
  • Pb(Fe1/2Nb1/2)O3 was prepared by the molten salt synthesis method using an equimolar mixture of NaCl-KCl. Initial particle size could be controlled by varying the weight ratio of the NaCl-KCl to raw materials from 0.1 to 1.0, and the initial particle size effects on the sintering and dielectric properties of Pb(Fe1/2Nb1/2)O3 were investigated at the sintering temperature range from 90$0^{\circ}C$ to 105$0^{\circ}C$. As the weight ratio of salt increased, the average particle size decreased and the particle size distributions tended to narrow. As the initial particle size decreased, the linear shrinkage and density increased due to the promotion of densification. Dielectric constant increased with decreasing the initial particle size resulting from the increase of density and grain size.

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Optimization of the Sucrose and Ion Concentrations for Saikosaponin Production in Hairy Root Culture of Bupleurum falcatum

  • Ahn, Jun-Cheul;Chong, Won-Seog;Kim, Young-Soon;Hwang, Baik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.2
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    • pp.121-126
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    • 2006
  • Saikosaponin productivity was examined in a Bupleurum falcatum L. BFHR2 hairy root culture in response to changes in the sucrose content $(2{\sim}8%)$, nitrogen content $(0{\sim}250mM\;NH_4NO_3)$, phosphate content $(0{\sim}12mM\;NaH_2PO_4)$, and the potassium content $(0{\sim}87.2 mM\; KCl)$ of the culture media. We found that the conditions for maximal saikosaponin production differed from those for optimal root growth. Highest saikosaponin yield was achieved for 8% sucrose, 62mM $NH_4NO_3$ 1.2 mM $NaH_2PO_4$, and 0.5mM KCl.

Surface Charge Density and Acidic Characteristics of $SO_4^{2-}/Al_2O_3$ ($SO_4^{2-}/Al_2O_3$의 표면전하밀도와 산적특성)

  • 함영민;홍영호;장윤호
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.933-940
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    • 1993
  • SO42-/Al2O3 powder was prepared by the coprecipitation method from the Al(NO3)3.9H2O and NH4OH and followed by being treated with various concentrations of sulfuric acid. The characterization of these powders was performed with XRD, BET and FT-IR. The surface charge density at alumina/KCl(aq) interface was measured by potentiometric titration method. From the experimental data it was shown that acid strength, specfic surface area, and structure of surface treated alumina were independent on the amount of exchanged SO42-. However, the acid amounts of alumina were increased with the amounts of SO42- formed on alumina surface. The relation between the acid amount of SO42- ion exchanged alumina surface and the surface charge density for SO42-/Al2O3/KCl(aq) interface was investigated.

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Calculations of Solubility Preduct Constants for Metal Oxides in the KCI-LiCl Eutectic Composition by Exact Thermodynamic Cycle (KCl-LiCl 공정 용융염욕에서 열역학적 싸이클법에 의한 금속산화물의 용해도적 계산)

  • 백영현
    • Journal of the Korean institute of surface engineering
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    • v.23 no.4
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    • pp.225-229
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    • 1990
  • Solubility Products of metal oxides, such as Al2O3 and UO2 in KCl-LiCl eutectic composition was calculated by using an exact an exact thermodynamic. The values for Al2O3 ThO2 and UO2 were found to be 2.51$\times$10-27, 4.97$\times$10-15and 2.17$\times$10-12in mole per liter basis at 743 K, respectively. The correlation of theoretical values with those of experiment were in good agreement. It is worth to note that the exact cycle method was proved to be satisfactory in making predictions of solubillities and also solubility products of sparingly soluble metal oxides in an ionic salt system.

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Effects of Li2O Addition and Heat-Treatment on Formability of FeS2 Powder for Cathode of Thermal Battery (열전지 양극용 FeS2 분말의 성형성에 미치는 Li2O 첨가 및 열처리의 효과)

  • Ryu, Sung-Soo;Lee, Won-Jin;Kim, Seongwon;Cheong, Hae-Won;Cho, Sung-Baek;Kang, Seung-Ho;Lee, Sung-Min
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.185-190
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    • 2014
  • $FeS_2$ has been widely used for cathode materials in thermal battery because of its high stability and current capability at high operation temperature. Salts such as a LiCl-KCl were added as a binder for improving electrical performance and formability of $FeS_2$ cathode powder. In this study, the effects of the addition of $Li_2O$ in LiCl-KCl binder on the formability of $FeS_2$ powder compact were investigated. With the increasing amount of $Li_2O$ addition to LiCl-KCl binder salts, the strength of the pressed compacts increased considerably when the powder mixture were pre-heat-treated above $350^{\circ}C$. The heat-treatment resulted in promoting the coating coverage of $FeS_2$ particles by the salts as $Li_2O$ was added. The observed coating as $Li_2O$ addition might be attributed to the enhanced wettability of the salt rather than its reduced melting temperature. The high strength of compacts by the $Li_2O$ addition and pre-heat-treatment could improve the formability of $FeS_2$ raw materials.

Effect of Electrolytic Material Feeding on Blood and Carcass Traits of Broiler under Intense Heat Condition in Summer (폭염 시 육계 출하 전 전해질 급여가 닭고기 도체 및 혈액에 미치는 영향)

  • Chae, Hyun-Seok;Choi, Hee-Chul;Na, Jae-Cheon;Kim, Min-Ji;Kang, Hwan-Ku;Kim, Dong-Wook;Kim, Ji-Hyeok;Jo, Soo-Hyun;Lee, Chong-Eon;Kim, Nam-Young;Choi, Yang-Ho;Park, Byong-Sung
    • Korean Journal of Poultry Science
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    • v.39 no.3
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    • pp.183-193
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    • 2012
  • This study was conducted to investigate the effect of feeding the electrolytic materials on blood and carcass traits of broiler during transportation exposed under intense heat condition in summer. The broilers were selected on the day when the outside temperature was about $32^{\circ}C$ to provide heat stressed environment. Broilers reared for 33 d were selected and fed with the electrolytic materials ($NaHCO_3$, NaCl, KCl) for 2 days. Treatments were as follows; feeding the underground water for control, $NaHCO_3$ (1.0%) + NaCl (0.5%) for treament 1, KCl (0.5%) + NaCl (0.5%) for treatment 2, KCl (1.0%) + NaCl (0.5%) treatment 3, KCl (0.5%) + $NaHCO_3$ (1.0%) + NaCl (0.5%) for treatment 4 and KCl (1.0%) + $NaHCO_3$ (1.0%) + NaCl (0.5%) for treament 5. pH of chicken meat increased for treatments group of electrolytic material, especially, that of treatment 3 was highest when compared to the other treatments. The frequency rate (%) of $1^+$ quality grade were 33.3, 60.0 and 83.3% at control, treatment 3, 4 and treatment 5, respectively. Occurrence rates of PSE were 50% for control and 13.3% for treatment 5. Corticosterone increased at the post-harvest period compared to the pre-harvest period of broiler and have small disparity between pre-and post-harvest only except treatment 3 when compared to control. $pCO_2$ partial pressure of blood at the pre-harvest period was low in all treatments by heat stress, the disparity value of control was high for control, and those of treatment 4 and 5 were low compared to other treatments.

PTCR Effects In Nb2O5 Doped BaTiO3 Ceramics Prepared By Molten Salt Synthesis Method (용융염합성법에 의한 Nb2O5 첨가 BaTiO3의 PTCR 효과)

  • 윤기현;정해원;윤상옥
    • Journal of the Korean Ceramic Society
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    • v.24 no.6
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    • pp.579-585
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    • 1987
  • The effects of flux KCl and dopant Nb2O5 on the PTCR characteristics of BaTiO3 prepared by molten salt synthesis method have been investigated. As the amount of dopant Nb2O5 is over the solubility limit in BaTiO3, the room-temperature resistivity increases, and the PTCR effect and the grain size decrease. The variation of the amount of flux KCl slightly influences on the room-temperature resistivity, PTCR effect and grain size in Nb2O5 doped BaTiO3, but BaTiO3 ceramics prepared by the method of molten salt synthesis show larger PTCR effect than those of conventional calcining of mixed oxides.

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Transport and Degradation of Benzene affected by Hydrogen Peroxide and Microorganism in a Sandy Soil (사질토양에서의 과산화수소 및 미생물에 의한 Benzene의 이동 및 분해특성)

  • 백두성;박춘화;김동주;김희성;이한웅;박용근
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.49-56
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    • 2001
  • Benzene, one of the aromatic hydrocarbons, can be degraded by physical, chemical and biological processes in aquifers. This study aimed at analyzing separately the three different forms of degradation by performing column tests. Column tests using KCl and benzene as tracers were conducted for four different cases: 1) no hydrogen peroxide and no microorganism, 2) hydrogen peroxide only; 3) microorganism only; 4) hydrogen peroxide and microorganism to investigate the sorption and degradation of benzene. The observed BTCs of KCl and benzene in all cases showed that the arrival times of the peaks of both tracers coincided well but the peak concentration of benzene was much lower than that of KCl. This reveals that a predominant process affecting the transport of benzene in a sandy soil is an irreversible sorption and/or degradation rather than retardation. Decay of benzene through sorption and degradation increased with the addition of hydrogen peroxide and/or microorganism. Dissolved oxygen decreased with the increase of benzene in all cases indicating that degradation of benzene was also influenced by dissolved oxygen. For BTCs with the addition of microorganisms (case 3 and case 4), microorganism showed much lower concentrations compared to the initial levels and an increasing tendency with time although concentrations of benzene returned to zero, indicating a possible retardation of microorganism due to reversible and irreversible sorption to the particle surfaces.

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Optimal Production and Characterization of Laccase from Fomitella fraxinea Mycelia (Fomitella fraxinea 균사체로부터 Laccase의 최적생산 및 효소적 특성)

  • Park Kyung-Mi;Park Sang-Shin
    • Microbiology and Biotechnology Letters
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    • v.34 no.3
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    • pp.228-234
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    • 2006
  • The culture conditions were investigated to maximize the production of laccase from Fomitella fraxinea mycelia. Among the tested media, mushroom complete medium (MCM) showed the highest production of the enzyme. The optimum culture medium was 2% dextrose, 0.4% $(NH_4)_{2}HPO_4$, 0.05% $Na_{2}HPO_{4}{\cdot}7H_{2}O$, and 0.05% KCl as carbon, nitrogen, phosphorus, and inorganic salt sources respectively. SDS-PAGE followed by laccase activity staining using 2,6-djmethoxyphenol as the substrate was performed to identify the laccase activity under culture conditions studied. Zymogram analysis of the culture supernatant showed a laccase band with a molecular mass of 50 kDa. The enzyme production from F. fraxinea was reached to the highest level after the cultivation for 10 days at $25^{\circ}C$ and initial pH 8. The enzyme activity of the culture supernatant was most active at $50^{\circ}C$ and pH 5.