• 제목/요약/키워드: Ionization development

검색결과 187건 처리시간 0.033초

배기가스 조건에 따른 코로나 방전 현상 시뮬레이션 (Simulation Study of Corona Discharge According to Flue Gas Conditions)

  • 정재우;조무현
    • 한국대기환경학회지
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    • 제17권2호
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    • pp.223-231
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    • 2001
  • In order to provide some insights into the influence of electric field, gas composition, and gas temperature on electron energy distribution and electron transport characteristics, the Boltzmann equation was solved by using cross section data for electron collisions, Critical electric fields for the corona development in dry air and flue gas are 150 and 80 Td, respectively. It was seen that the decrease of critical electric field in flue gas is mainly caused by the $H_2O$ addition through the comparison of ionization and attachment coefficients of gas components. Increase of $O_2$, $H_2O$, and $CO_2$ contents in gas affected discharge characteristics according to their reciprocal characteristics between lowering the ionization threshold and increasing the electro-negativity. As electric field increases, electrons with higher energies in the electron energy distribution also increase. The mean and characteristic electron energies also linearly increase with electric field. The variation of flue gas temperature did rarely affect on the electron energy distribution function and electron transport characteristics, because the gas temperature is several hundreds or thousands times lower than the electron temperature.

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Development of Neutron Sensitive PCP ionization Chamber

  • Lee, Hee-Young;Kim, Jin-Kon
    • Nuclear Engineering and Technology
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    • 제6권1호
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    • pp.27-35
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    • 1974
  • 원자로계장을 위해서 중성자에 민감한 전리함을 개량된 기술에 의해서 성공적으로 개발하였다. 이 전리함은 50mm의 직경에 87cm의 길이를 가지고 있으며 대략 $10^{9}$ nv의 중성자속에 대해서 14$\mu$A의 전리전류를 흘릴 수 있다. 요구되는 정상전압은 +350v이다. 이 전리함은 동작중의 원자로에서 집어낼 수 있으며 또한 방사선에 대한 별다른 주의 없이 즉시 분해할 수 있다.

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LC/MS를 이용한 식육중 잔류 벤지미다졸계 구충제 분석법 연구 (Study on analytical method of residual benzimidazole anthelmintics in meat by LC/MS)

  • 최은영;서형석;백귀정;허부홍;서이원;정동석
    • 한국동물위생학회지
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    • 제28권1호
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    • pp.81-89
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    • 2005
  • Recently, mass spectrometry coupled with liquid chromatography (LC/MS) has been a preferred technique for determination of organic compounds in complex matrixes. LC/MS provides a high degree sensitivity and specificity of the compounds of interest. The purpose of this study was to confirm analytical method of residual 6 benzimidazoles (thiabendazole, oxfendazole, mebendazole, albendazole, flubendazole and fenbendazole) in meat by LC/MS. Benzimidazoles were analyzed by LC/MS on XTerra $C_{18}$ column with 0.01% trifluoroacetic acid-acetonitrile (TFA) in a gradient mode as mobile phase, and that were identified by electrospray ionization with selected ion recording mode at 150-350 amu mass range. Residual benzimidazoles were extracted from tissue with ethylacetate, and elute benzimidazoles with $50\%$ acetonitrile. In the LC/MS analysis of benzimidazoles, signal to noise ratio was showed relatively high in the positive mode and special ion in the quality analysis was determined via $[M+H]^+$ and Fragment ions. A spectrum of benzimidazoles was showed from all 6 benzimidazoles

선량 중첩을 이용한 멀티형 연 X-선 정전기 제거장치의 개발 (Development of Multi-Type Soft X-ray Ionizer using Radiation Dose Overlapped Effect)

  • 이수환;이동훈
    • 한국안전학회지
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    • 제33권2호
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    • pp.28-31
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    • 2018
  • In display and semi-conductor manufacturing process, there are numerous unstable factors such as particle concentration, minimal vibration, changes in magnetic field, or electrostatic that becomes an issue to be managed and controlled. In the recent, X-ray ionization is widely used that is neutralized by separating air or gas molecules in the area where the static must be resolved. The mono-type of X-ray ionizer was not capable to be used in $8^{th}$ generation panels manufacturing plant due to its insufficient ionizing coverage since the panel itself is approximately in $2m{\times}3m$. To resolve the current problem, the development of new type called, "Multi-type X-ray ionizer" has resulted in covering enough ionizing space in $8^{th}$ generation panels industry. Comparing mono and multi types with MCNPX code simulation, the multi one indicates more X-ray flux, efficiency, and ionization performance in comparison with either a mono-type or multi-type in array format. In addition, the ionizing efficiency of overlapping area with multi-type showed 30% higher effectiveness rate as to the ordinary mono-type.

Development of a Rapid and Accurate Identification Method for Citrobacter Species Isolated from Pork Products Using a Matrix-Assisted Laser-Desorption Ionization Time-of-Flight Mass Spectrometry (MALDITOF MS)

  • Kwak, Hye-Lim;Han, Sun-Kyung;Park, Sunghoon;Park, Si Hong;Shim, Jae-Yong;Oh, Mihwa;Ricke, Steven C.;Kim, Hae-Yeong
    • Journal of Microbiology and Biotechnology
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    • 제25권9호
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    • pp.1537-1541
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    • 2015
  • Previous detection methods for Citrobacter are considered time consuming and laborious. In this study, we have developed a rapid and accurate detection method for Citrobacter species in pork products, using matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectrometry (MS). A total of 35 Citrobacter strains were isolated from 30 pork products and identified by both MALDI-TOF MS and 16S rRNA gene sequencing approaches. All isolates were identified to the species level by the MALDI-TOF MS, while 16S rRNA gene sequencing results could not discriminate them clearly. These results confirmed that MALDITOF MS is a more accurate and rapid detection method for the identification of Citrobacter species.

Mass Spectrometric Analysis of Eight Common Chemical Explosives Using Ion Trap Mass Spectrometer

  • Park, Sehwan;Lee, Jihyeon;Cho, Soo Gyeong;Goh, Eun Mee;Lee, Sungman;Koh, Sung-Suk;Kim, Jeongkwon
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3659-3664
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    • 2013
  • Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either $[M-H]^-$ for TNT and DNT or $[M]^{{\cdot}-}$ for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i.e., $[M+HCOO]^-$. These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available.

Analysis of Placental Proteins in Somatic Cell Clone Recipient Cows

  • Woo, Jei-Hyun;Chung, Hak-Jae;Kim, Bong-Ki;Ko, Yeoung-Gyu;Kim, Jeom-Soon;Jung, Jin-Kwan;Chang, Won-Kyong
    • 한국동물번식학회:학술대회논문집
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    • 한국동물번식학회 2004년도 춘계학술발표대회
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    • pp.197-197
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    • 2004
  • The purpose of this experiment was to investigate the protein profiles in the placenta of Korean native cows(KNC) transferred cloned embryos and KNC artificially inseminated placental tissues were collected from the cows after cesarean section around parturition, and placental proteins were analyzed. Using two dimensional polyacrylamide gel eletrophoresis and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. (omitted)

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전자오븐을 이용한 간편하고 연속적인 마이크로파 발생 장치 개발 (Development of simple and continuous microwave source using a microwave oven)

  • 권기청;김재현;김정희;이효석;전상진;허승회;최원호
    • 한국진공학회지
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    • 제9권3호
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    • pp.290-295
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    • 2000
  • KAIST-TOKAMAK에서 재현성이 좋은 저항가열 플라즈마를 발생시키는데 필요한 전이온화(pre-ionization)에 응용하기 위해 2.45 GHz 마그네트론을 사용하여 간편한 마이크로파 발생장치를 개발하였다. 장치에 사용한 마그네트론은 출력 500 W, 주파수 2.45 GHz이며, 일반적인 가정용 전자오븐(microwave oven)에 사용된다. 기존의 가정용 마그네트론은 음극(cathode)과 양극(anode)사이에 걸리는 고전압이 60 Hz의 주기를 갖기 때문에 약 16ms마다 약 8 ms 동안만 주기적으로 마이크로파를 발생한다. 이 마그네트론을 사용하여 토카막 전이온화에 충분할 정도로 연속적으로 발생되는 마이크로파를 얻기 위해서 음극과 양극사이에 개량된 회로로 리플전압이 작은 DC 고전압(5 kV 1 A)을 인가하였다. 본 논문에서는 주기적으로 생성.소멸하는 ECH 플라즈마와 연속적인 ECH 플라즈마를 발생시켜 랑뮈어탐침과 광증배관(PMT)을 이용한 이온 포화전류와 $H_\alpha$/ 방출(emission)을 측정하여 마이크로파 발생장치의 특성을 조사하였다.

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GC/FID에 의한 작업환경중 메틸 이소시아네이트의 분석 (The Determination of Methyl Isocyanate in the Workplace by Gas Chromatography with Flame Ionization Detector)

  • 이은정;유철;한영선;조영봉
    • 한국산업보건학회지
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    • 제11권3호
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    • pp.249-253
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    • 2001
  • The purpose of this study is the development of the simple and precise sampling and analysis method of methyl isocyanate(MIC) in the work place as their secondary aliphatic amine derivatives by gas chromatography with flame ionization detector. The urea derivatives are quantitatively and simultaneously derived from MIC with secondary aliphatic amines such as dipropylamine(DPA), dibutylamine(DBA), and dipentylamine (DAA) in methylene chloride. The method is based on sampling glass tube in XAD-2 resin which is coated with secondary aliphatic amines. The samples are desorbed by $2m{\ell}$ methylene chloride and analysed using gas chromatography with flame ionization detector(GC/FID). In the results, the detection limit of the overall procedure and reliable quantity are $0.020-0.027{\mu}g$($1.347-1.740{\mu}g/m^3$(0.529-0.684 ppb) based on a 15 L air volume) MIC per sample. The average desorption efficiencies are 97.96 - 101.23 %. The results of versus storage time are high and stable recovery rates.

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