• Journal of the Korean Chemical Society
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• v.59 no.6
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• pp.499-507
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• 2015

The purpose of this study is to investigate middle school students’ understanding of ionic equation. Two hundreds and nineteen middle school students were participated in the study. After six class hours of learning ‘electrolyte and ion’ unit, instrument was implemented to evaluate students’ understanding of ionic process and ability to write ionic equation. We analyzed the influence of characteristics of ionic compounds on correct answer rate. In addition, knowledge state of students required for writing ionic equation was analyzed. The results were as follows: First, ionic compounds tested were categorized into six groups. The correct answer rate was different depending on the characteristics of each group. Second, knowledge state required for writing ionic equation was structured. Based on results some suggestion were made to develope effective learning strategy for understanding ionic equation.

• Korean Journal of Soil Science and Fertilizer
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• v.36 no.6
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• pp.391-398
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• 2003

Research was conducted to establish the leaf and petiole sap test to diagnose the nutritional status of tomato. The concentrations of $NO_3$, $PO_4$, K, Ca, Mg and $SO_4$ ions extracted from the leaves and petioles in the different positions in a plant were measured and compared with their corresponding inorganic contents in the leaves analyzed by the chemical method. The ionic concentrations in the leaf and petiole sap showed the different values depending on their positions in a plant. The leaves and petioles in the lower positions of a plant had higher concentrations of $NO_3$, Ca, Mg and $SO_4$ ions. In particular, there were greater changes of ionic concentrations and less increases in the leaf length and width from the 9th compound leaf down from the uppermost cluster. On the other hand, the leaflets in a compound leaf had the same ionic concentrations. Therefore, it appeared that the optimal sampling position of leaf and petiole for the sap test is the leaflets of the 9th compound leaf down from the uppermost cluster. A good correlation between the sap test and the chemical analysis of plant showed that the ionic concentrations in the leaf and petiole sap reflect the nutritional status of tomatoes.

• Macromolecular Research
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• v.16 no.5
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• pp.424-428
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• 2008

We prepared an ionic gel polymer electrolyte for dye-sensitized solar cells (DSSCs) without leakage problem. Triiodide compound (BTDI) was synthesized by the reaction of benzene tricarbonyl trichloride with diethylene glycol monotosylate and subsequent substitution of tosylate by iodide using NaI. Bisimidazole was prepared by the reaction of imidazole with the triethylene glycol ditosylate under strongly basic condition provided by NaH. BTDI and bisimidazole dissolved in an ionic liquid were injected into the cells and permeated into the $TiO_2$ nanopores. In situ crosslinking was then carried out by heating to form a network structure of poly(imidazolium iodide), thereby converting the ionic liquid electrolytes to a gel or a quasi-solid state. A monomer (BTDI and bisimidazole) concentration in the electrolytes of as low as 30 wt% was sufficient to form a stable gel type electrolyte. The DSSCs based on the gel polymer electrolytes showed a power conversion efficiency of as high as 1.15% with a short circuit current density of $5.69\;mAcm^{-2}$, an open circuit voltage of 0.525 V, and a fill factor of 0.43.

• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.1-10
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• 2009

This article reviewed transport behaviours of electroactive species in ionic compounds, focusing on chemical diffusion of Li through the transition metal oxide in a current flowing condition. For this purpose, a distinction has been first briefly made between migration and diffusion with respect to current, driving force and charge of electroactive species considered. Then, the equations for chemical diffusion are derived theoretically in open-circuit and current flowing conditions. Finally, the experimental methods such as ac impedance spectroscopy and current (potential) transient techniques are described in details for characterising chemical diffusion. In addition, the role of the thermodynamic enhancement factor in chemical diffusion is discussed.

• Elastomers and Composites
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• v.50 no.3
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• pp.167-174
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• 2015

Anionic epoxy compound was synthesized and added to asphalt aiming to prepare self-healing asphalt. Epoxy-modified asphalt showed excellent modification effect and healing effect as well. The results revealed that with 5% addition of polymer the tensile strength, impact strength and complex shear modulus of the polymer-modified asphalt increased by 65%. 64% and 35%, respectively. It seems that high interaction occurs between polymer and asphalt matrix. Self-healing efficiency of the polymer-modified asphalt based on tensile strength showed 100%, comparing to 79% of straight asphalt. In impact experiment the polymer-modified asphalt showed 99% of healing efficiency, comparing to 77% of straight asphalt. In rheological experiment the polymer-modified asphalt showed 103% of healing efficiency, comparing to 72% of straight asphalt. It appears that the ionic bonding existing in epoxy polymers contributed to high values of self-healing efficiency. The polymer which has high intermolecular force fills the crack of the asphalt, pulling the opponent side each other, and so the original properties were restored.

• Journal of the Korean institute of surface engineering
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• v.34 no.6
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• pp.553-567
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• 2001

Electrodeposition technology is widely used in industry for various kinds of coatings. Modifications in this technology led to several processes to meet various requirements. Electrolysis in ionic liquids has many advantages such as low energy consumption of energy, low pollutant emission and low operating costs. Although ionic liquids have already been used in liquid/liquid extraction processes, only recently their use in electrodeposition was exploited. Electrochemical deposition of composites is an expanding area. Coupled with the progress in the synthesis of nanometric powder, this research will open a large number of innovative materials. Pulse current plating is another electrodeposition technique which yields improved coatings. Although electrodeposition is now regarded as an environmental non-friendly process, it is economically viable and has many inherent advantages. For certain applications, alternatives to electrodeposition have not yet been fully implemented. Hence, continued research in this technology is warranted. This article reviews some recent advances in electrodeposition technology. Aspects of electrodeposition such as electrolysis in ionic liquids, electrodeposition of composites, pulse current plating techniques, metal and alloy deposition, compound deposition and effects of additives are discussed in this review.

• Journal of Radiopharmaceuticals and Molecular Probes
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• v.3 no.2
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• pp.116-121
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• 2017

To overcome the low reactivity and solubility of alkali metal fluorides (MFs), various types of phase transfer catalysts (PTCs) have been developed over the last decades. However, since the fluoride activated by such PTC sometimes has a strong basicity, it may cause various side reactions such as elimination reaction or hydroxylation reaction in the nucleophilic fluorination reaction. Also, they may cause separation problems in the compound purification process. In recent advanced study, various PTCs have been developed to solve these problem of conventional catalyst. In this review, we would like to introduce three kinds of novel multifunctional organic catalysts such as bis-tert-alcohol-functionalized crown-6-calix[4]arene (BACCA), easy separable pyrene-tagged ionic liquid (PIL) by reduced graphene oxide (rGO), and tri-tert-butanolamine organic catalyst.

• Journal of the Korean Ceramic Society
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• v.49 no.1
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• pp.48-55
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• 2012

Degradation of performance and life time of a functional material or device thereof is induced, to a great extent, by mass transfer in the material that is driven by various thermodynamic forces imposed intentionally or accidentally during its operation or service. The forces are any gradient of intensive thermodynamic variables, component chemical potentials, electrical potential, temperature, stresses, and the like. This paper reviews electric-field induced degradation phenomena in ionic solid compounds including insulation resistance degradation, crystal shift, microstructural alterations, compositional unmixing, and compound decomposition. Their inner workings are also discussed qualitatively.

• Journal of the Korean Physical Society
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• v.73 no.12
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• pp.1873-1878
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• 2018

We have investigated the ionic conductivity and dielectric relaxation in $Li_2B_4O_7$ (LBO) and $Li_2O-B_2O_3-Ta_2O_5$ (LBTO) glasses. The sample was synthesized by using the melt quenching method. The frequency dependence of the electrical data from the LBO and LBTO glasses has been analyzed in the frameworks of the impedance Cole-Cole formalism and the universal power-law representation driven by the modified fractional Rayleigh equation. The potential barriers in the LBO and the LBTO glasses turn out to be the same. Comparing with the dc and ac activation energies of the LBO glass, these energies of the LBTO glass decrease due to the increasing Coulomb interaction of inter-cationic interaction.

• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.205-210
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• 1999

The thermodynamic properties and phase diagram of the$ PbO-ZrO_2$ system have been critically assessed using the Thermo-Calc program. Excess Gibbs energies were expressed by Redlich-Kister polynomials for the solid phases, by the two-sublattice ionic liquid model for the liquid phase and by the compound energy model for the solid solution phase. All solid phases were treated as stoichimetric compounds.