• Journal of Korean Society of Environmental Engineers
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• v.39 no.3
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• pp.149-154
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• 2017

We investigate the availability of $CO_2$ ocean storage by means of chemical conversion of $CO_2$ to the dissolved inorganic carbon (mainly the bicarbonate ion) in seawater. The accelerated weathering of limestone (AWL) technique, which is accelerating the natural $CO_2$ uptake process through the chemical conversion using limestone and seawater, was proposed as an alternative method for reducing energy-related $CO_2$ emission. The method presented in this paper is slightly different from the AWL method. It involves reacting $CO_2$ with seawater and quicklime obtained from alkaline wastes to produce the bicarbonate-rich solution over 100 times more than seawater, which could be released and diluted into the ocean. The released dense bicarbonate-enriched water mass could subside into the deeper layer because of the density flow, and could be sequestrated stably in the ocean.

• Journal of Hydrogen and New Energy
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• v.10 no.4
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• pp.197-210
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• 1999

The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.165-175
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• 2005

Measurement of spent resin activity was initiated in 2004 in order to develop the C-14 removal technology for safe disposal. As part of this program, spent resins were sampled and measured in the in-station resin storage tank 2 at Wolsong Nuclear Power Plant Unit 1. At the time of sampling, the resins had been in storage tank from 3 to 23 years. Total 72 resin samples were sampled, which were collected from both man-hole (68 samples) and test-hole (4 samples) in the in-station resin storage tank 2. They were separated into liquid, activated carbon, zeolite, and spent resin. The spent resins were oxidized with sample oxidizer and analyzed for C-14. Ten of collected mixed resin samples were separated by density into cation and anion resins using a sugar solution. The C-14 concentration in anion exchange resin was approximately 2 times higher than in the mixed resin. The average concentration of C-14 in the cation/anion mixed exchange resin was $460\;GBq/m^3$ from test-hole and $53.1\;GBq/m^3$ from man-hole. We have found that concentration of C-14 in the spent resin is about from 0.4 to $1,321\;GBq/m^3$. So it could be a problem, when dispose of at a repository, since there is a disposal limit of $222\;GBq/m^3$. This means we should develop the C-14 removal technology.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.247-252
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• 2012

Of late, the development of advanced batteries with high power density and capacity has been indispensible for pushing ahead with much wider applications to electric vehicles and smart IT devices. However, a conventional Li-ion battery contains a limited energy density due to various technological challenges such that other types of Li batteries including Li-S and Li-air have been extensively studied due to their interestingly high energy capacities. Sulfur and oxygen, of which both are cathode materials, showing similar physicochemical characteristics have widely been available which may also contribute to the commercialization of these batteries. In this review, we introduce some perspectives in improving these advanced Li batteries through several approaches such as the provision of porous cathode structures, the optimization of cathode-electrolyte interfaces and the modification of Li anodes.

• Korean Journal of Food Science and Technology
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• v.4 no.4
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• pp.317-321
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• 1972

Octopus Octopus vulgaris was dried with open air at $17{\sim}20^{\circ}C$ for 90 hours. Nucleotides and related substances were collected by extraction with cold perchloric acid, and their amounts were determined by ion exchange column chromatography. The contents of inosine, hypoxanthine and ADP in raw sample were 9.4, 5.1 and 4.1 ${\mu}mole/g{\cdot}dry\;wt.$ respectively. ATP and AMP were very low in content. But IMP was not detected in Octopus muscle. ATP, ADP and inosine tended to degrade rapidly during sun drying while AMP and hypoxanthine were increased. Especially, hypoxanthine were increased about three times during sun drying and also it was increased about two times during three months storage after sun drying.

• Journal of the Korean Electrochemical Society
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• v.10 no.1
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• pp.36-42
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• 2007

In general, the battery and the(electric) condenser are pictured as electrical energy storage devices. Although there were lots of inventions and utilizations of morden conveniences according to enormous growth of the science and technologies after the Industrial Revolution, a speed of technology development on these devices being closely used in civilized human lives and many electric or electronic systems as a core component are relatively slower to the other fields of technologies. Nevertheless, based on a remarkable progress of the material science and technologies for the last ten years, a new type of electrical energy storage device so called as 'electrochemical capacitors' are being developed and used practically. The electrochemical capacitors exhibit their own characteristics of much enhanced capacitance over the conventional condensers and also distinctively exhibit a longer lift time and higher power capability that the nickel hydrogen batteries and secondary batteries such as lithium ion and polymer batteries does not show up so for. Hence, in this paper, it is intended to introduce a fundamental understanding and updated technology trends on the electrochemical capacitors.

• The Transactions of the Korean Institute of Power Electronics
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• v.25 no.5
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• pp.376-384
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• 2020

An energy storage system is composed of lithium-ion batteries in modern applications. Batteries are regarded as storage devices for renewable and residual energy. The failure of batteries can cause the performance reduction and explosion of battery systems. High maintenance cost is essential when dealing with the problem of battery safety. Therefore an accurate health diagnosis is required to ensure the high reliability of battery systems. A battery pack is a combination of single cells in series and parallel connections. A battery pack has to consider various factors to assess battery health. Battery health involves conventional factors and additional factors, such as cell-to-cell imbalance. For large applications, state-of-health (SOH) can be inaccurate because of the lack of factors that indicate the state of the battery pack. In this study, six characterization factors are proposed for improving the SOH estimation of battery packs. The six proposed characterization factors can be regarded as health indicators (HIs). The six HIs are applied to the principal component analysis (PCA) algorithm. To reflect information regarding capacity, voltage, and temperature, the PCA algorithm extracts new degradation factors by using the six HIs. The new degradation factors are applied to a multiple regression model. Results show the advancement and improvement of SOH estimation.

• Korean Journal of Metals and Materials
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• v.49 no.2
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• pp.174-179
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• 2011

We investigated the surface morphology changes of a lithium/sulfur battery using multi-walled canbon nanotube added sulfur electrode during charge-discharge cycling. The Li/S cell showed the first discharge capacity of 1286 mAh/g-S, which utilized is 71% of the theoretical value. It decreased to 328 mAh/g-S at the 100th cycle, which corresponds to about 19% utilization of the total sulfur in the cathode. The spherical lumps of the reaction product were observed on the surface of the sulfur electrode. This material was verified as lithium sulfide by X-ray diffraction measurement. The pores in the separator were filled with reaction product. Thus the diffusion of the $Li^+$ ion decreased, which resulted in the decreased capacity of the Li/S cell.

• Korean Journal of Materials Research
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• v.31 no.12
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• pp.710-718
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• 2021

Recently, due to high theoretical capacitance and excellent ion diffusion rate caused by the 2D layered crystal structure, transition metal hydroxides (TMHs) have generated considerable attention as active materials in supercapacitors (or electrochemical capacitors). However, TMHs should be designed using morphological or structural modification if they are to be used as active materials in supercapacitors, because they have insulation properties that induce low charge transfer rate. This study aims to modify the morphological structure for high cycling stability and fast charge storage kinetics of TMHs through the use of nickel cobalt hydroxide [NiCo(OH)₂] decorated on nickel foam. Among the samples used, needle-like NiCo(OH)₂ decorated on nickel foam offers a high specific capacitance (1110.9 F/g at current density of 0.5 A/g) with good rate capability (1110.9 - 746.7 F/g at current densities of 0.5 - 10.0 A/g). Moreover, at a high current density (10.0 A/g), a remarkable capacitance (713.8 F/g) and capacitance retention of 95.6% after 5000 cycles are noted. These results are attributed to high charge storage sites of needle-like NiCo(OH)₂ and uniformly grown NiCo(OH)₂ on nickel foam surface.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.20 no.2
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• pp.1-10
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• 2024

The introduction of the sector coupling concept has expanded the scope of ESS utilization, resulting in the importance of thermal management of ESS. To ensure the safe use of the lithium-ion batteries that are used in ESS, it is important to use the batteries at the optimal temperature. To examine the utilization of liquid cooling in ESS, numerical study was conducted on the thermal characteristics of 21700 battery modules (16S2P array) during liquid cooling using Novec-649 as insulating fluid. The NTGK model, an MSMD model in ANSYS fluent, was used to investigate thermal characteristics on the battery modules with liquid immersion cooling. The results show that the final temperature of the battery module discharged at 5 C-rate is 68.9℃ using natural convection and 48.3℃ using liquid cooling. However, the temperature difference among cells in the battery module was up to 0.5℃ when using natural convection cooling and 5.8℃ when using liquid cooling, respectively, indicating that the temperature difference among cells was significantly increased when liquid cooling was used. As the mass flow rate increased from 0.01 kg/s to 0.05 kg/s, the average temperature of the battery module decreased from 48.3℃ to 38.4℃, confirming that increasing the mass flow rate of the insulating fluid improves the performance of liquid immersion cooling. Although partial liquid immersion cooling has a high cooling performance compared to natural convection cooling, the temperature difference between modules was up to 8.9℃, indicating that the thermal stress of the battery cells increased.