• Title/Summary/Keyword: Ion storage

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Comparative Analysis of the characteristics of Ni-rich LIB according to temperature change (온도 변화에 따른 Ni-rich LIB의 설계인자별 파라미터 특성 비교 분석)

  • Gwon, Sun-Jong;Im, Ji-Hun;Choe, Jin-Hyeok;Kim, Jong-Hun
    • Proceedings of the KIPE Conference
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    • 2018.11a
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    • pp.131-132
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    • 2018
  • The world market for BESS (Battery Energy Storage System) is growing rapidly, and battery technology is also developing. It is important to understand the battery characteristics and develop a control strategy to develop the optimal BMS (Battery Management System). In this paper, we compare and analyze the parameter characteristics of NCM LIB (Lithium Ion Battery) according to the temperature change.

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Comparison of Analysis Methods for Ammonia from Swine Production Facilities

  • Kim, Ki Y.;Choi, Hong L.;Kim, Chi N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.11
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    • pp.1608-1614
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    • 2004
  • This study was performed to evaluate the accuracy, validation and applicability of UV spectrophotometer (UV), Ion Chromatography (IC), and Detector tube (DT) methods for measuring ammonia (NH3) concentration in a swine confinement house and swine slurry storage tank. The mean values of $NH_{3}$ emitted from the house and slurry were 5.333 ppm and 42.192 ppm for the IC method; 4.13 ppm and 36.29 ppm for the Detector tube; and 5.417 ppm and 34.193 ppm for the UV method. The accuracy and the correlation of an ammonia level analyzed by the IC method compared to the UV method were 98% and 0.998($R^{2}$) in the swine confinement house and 94% and 0.997($R^{2}$) in the swine slurry storage tank. On the other hand, those of ammonia level measured by the Detector tube compared to the UV method were 77% and 0.957($R^{2}$) in the swine confinement house and 82% and 0.941($R^{2}$) in the swine slurry storage tank. This indicated that the accuracy and the correlation of the IC method compared to the UV method were higher than those of the Detector tube method compared to the UV method. Therefore, it was concluded that the IC method was more accurate in measuring ammonia concentration in a swine house and a swine slurry storage tank. The Detector tube method should not be applied to the swine slurry storage tank in which ammonia concentration is generally higher than 30 ppm because low accuracy is caused by a gross space between scales inscribed in the Detector tube.

Quality Characteristics of Dolsan Leaf Mustard according to Various Blanching Conditions and Liquid Chromatography with Photodiode Array and Tandem Mass Spectrometry Analysis (다양한 데침조건에서 돌산갓의 이화학적 특성 및 LC-PDA/MS/MS 분석)

  • Son, Hae-Reon;Oh, Sun-Kyung;Tsukamoto, Chigen;Choi, Myeong-Rak
    • KSBB Journal
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    • v.31 no.1
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    • pp.20-26
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    • 2016
  • This study aims to examine the optimum blanching conditions as a pretreatment condition to improve the storage stability of Dolsan leaf mustard pickle. The effects of the blan- ching temperature and time were investigated at a temperature range of $80-100^{\circ}C$. Sampling was done for 1 month after a 5 days interval. The L value of the Dolsan leaf mustard was found to be the highest at $80^{\circ}C$. The cutting force increased as the blanching temperature increased. The tensile strength decreased at $95^{\circ}C$ and $100^{\circ}C$. In addition, the sensory evaluation scores were the best at $80^{\circ}C$. The storage stability was assessed at various blanching temperatures to increase the sinigrin content during storage. Liquid chromatography with photodiode array and tandem mass spectrometry (LC-PDA/MS/MS) analysis was conducted to identify and quantify the sinigrin content in the Dolsan leaf mustard. Sinigrin as an internal standard was co-injected into each sample solution. The sample was monitored by recording the ultraviolet absorbance at 228 nm and by electrospray ionization (ESI) positive ion mode in the m/z 50-1,500 range. Blanching the sample at $80^{\circ}C$ showed the highest sinigrin concentration during storage among various temperatures and the maximum concentration was 350 ppm at 15 days storage. Study on utilization of vegetable from food processing of leaf mustard and preservation conservation results suggest that blanching at $80^{\circ}C$ is expected to improve the palatability of the pickle.

Electrochemical Characteristics of Synthesized Nb2O5-Li3VO4 Composites as Li Storage Materials

  • Yang, Youngmo;Seo, Hyungeun;Kim, Jae-Hun
    • Corrosion Science and Technology
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    • v.20 no.4
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    • pp.183-188
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    • 2021
  • The increasing demand for energy storage in mobile electronic devices and electric vehicles has emphasized the importance of electrochemical energy storage devices such as Li-ion batteries (LIBs) and supercapacitors. For reversible Li storage, alternative anode materials are actively being developed. In this study, we designed and fabricated an Nb2O5-Li3VO4 composite for use as an anode material in LIBs and hybrid supercapacitors. Nb2O5 powders were dissolved into a solution and the precursors were precipitated onto Li3VO4 through a simple, low-temperature hydrothermal reaction. The annealing process yielded an Nb2O5-Li3VO4 composite that was characterized by X-ray diffraction, electron microscopy, and X-ray photoelectron spectroscopy. Electrochemical tests revealed that the Nb2O5-Li3VO4 composite electrode demonstrated increased capacities of approximately 350 and 140 mAh g-1 at 0.1 and 5 C, respectively, were maintained up to 1000 cycles. The reversible capacity and rate capability of the composite electrode were enhanced compared to those of pure Nb2O5-based electrodes. These results can be attributed to the microstructure design of the synthesized composite material.

Influence of Temperature on Chloride Ion Diffusion of Concrete (콘크리트의 염화물이온 확산성상에 미치는 온도의 영향)

  • So, Hyoung-Seok;Choi, Seung-Hoon;Seo, Chung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
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    • v.26 no.1
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    • pp.71-78
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    • 2014
  • The long term integrity of concrete cask is very important for spent nuclear fuel dry storage system. However, there are serious concerns about early deterioration of concrete cask from creaking and corrosion of reinforcing steel by chloride ion because the cask is usually located in seaside, expecially by combined deterioration such as chloride ion and heat, carbonation. This study is to investigate the relation between temperature and chloride ion diffusion of concrete. Immersion tests using 3.5% NaCl solution that were controlled in four level of temperature, i.e. 20, 40, 65, and $90^{\circ}C$, were conducted for four months. The chloride ion diffusion coefficient of concrete was predicted based on the results of profiles of Cl- ion concentration with the depth direction of concrete specimens using the method of potentiometric titration by $AgNO_3$. Test results indicate that the diffusion coefficient of chloride ion increases remarkably with increasing temperature, and there was a linear relation between the natural logarithm values of the diffusion coefficients and the reciprocal of the temperature from the Arrhenius plots. Activation energy of concrete in this study was about 46.6 (W/C = 40%), 41.7 (W/C = 50%), 30.7 (W/C = 60%) kJ/mol under a temperature of up to $90^{\circ}C$, and concrete with lower water-cement ratio has a tendency towards having higher temperature dependency.

Potential-dependent Complex Capacitance Analysis for Porous Carbon Electrodes (다공성 탄소전극의 전위에 따른 복소캐패시턴스 분석)

  • Jang, Jong H.;Yoon, Song-Hun;Ka, Bok H.;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.255-260
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    • 2003
  • The complex capacitance analysis was performed in order to examine the potential-dependent EDLC characteristics of porous carbon electrodes. The imaginary capacitance profiles $(C_{im}\;vs.\;log\lf)$ were theoretically derived for a cylindrical pore and further extended to multiple pore systems. Two important electrochemical parameters in EDLC can be estimated from the peak-shaped imaginary capacitance plots: total capacitance from the peak area and $\alpha_0$ from the peak position. Using this method, the variation of capacitance and ion conductivity in pores can be traced as a function of electric potential. The electrochemical impedance spectroscopy was recorded on the mesoporous carbon electrode as a function of electric potential and analyzed by complex capacitance method. The capacitance values obtained from the peak area showed a maximum at 0.3V (vs. SCE), which was in accordance with cyclic voltammetry result. The ionic conductivity in pores calculated from the peak position showed a maximum at 0.2 V (vs. SCE), then decreased with an increase in potential. This behavior seems due to the enhanced electrostatic interaction between ion and surface charge that becomes enriched at more positive potentials.

Voltage Balancing Circuit for Li-ion Battery System (리튬-이온 배터리 시스템을 위한 전압안정화 회로)

  • Park, Kyung Hwa;Yi, Kang Hyun
    • Journal of Korea Society of Industrial Information Systems
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    • v.18 no.5
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    • pp.73-80
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    • 2013
  • Recently, Li-ion battery is regarded as a potential energy storage device in the lime light and it can supply power to the satellite very effectively during eclipse. Because it has better features as high voltage range, large capacity and small volume than any other battery. Generally, multi cells are connected in series to use Li-ion batteries in satellite application. Since the internal resistance of cells is different each other, voltage in some cells can be overcharged or undercharged, so capacity of the cell is reduced and the life of whole battery pack is decreased. Therefore, a voltage balancing circuit with Fly-back converter is proposed and the voltage equalization of each cell is verified the prototype in this paper.

Accuracy and Precision of Ion Chromatography/Visible Absorbance Detection for Analyzing Hexavalent Chromium Collected on PVC Filter (Ion Chromatography/Visible Absorbance Detection을 이용한 Cr(VI) 분석의 정확도 및 정밀도 평가)

  • Shin, Yong Chul;Oh, Se Min;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.223-232
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    • 1997
  • The accuracy and precision of a modified method of NIOSH Method 7600 and EPA method 218.6 was determined for analyzing hexavalent chromium, Cr(VI), collected on PVC filter from workplace air. The method was designed to extract from Cr(VI) on PVC filter with a alkali solution, 2% NaOH/3% $Na_2CO_3$, and to analyze it using ion chromatography/visible absorbance detection(IC/VAD). The results and conclusion are as the following. 1. The peak of Cr(VI) was separated sharply on chromatogram and was linearly related with Cr(VI) concentration in sloution. The correlation coefficient was 0.9999 in a calibration curve. The limit of detection was 0.25 $0.25{\mu}g/sample$. 2. The accuracy(% recovery) was 93.3% in a set of sample($9-50{\mu}g$) stored for a day, and 100.1%($10-60{\mu}g$) in another set of samples stored for 2 hours. It is assumed that the difference in recovery by storage time was due to reduction of Cr(VI) to Cr(III). 3. The precision(coefficient of variation, CV) of the method was 0.015 in spiked samples with Cr(VI) standard solution, and 0.010 in spiked samples with plating solution from a chrome electroplating factory. The overall CV in all types of samples was 0.0013. 4. The Cr(VI) was stable in 2% NaOH/3% $Na_2CO_3$ at least for 10 hours. In conclusion, the IC/VAD method is appropriate for determining low-level Cr(VI) in workplace air containing various interferences.

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A Study on the Characteristics of Cell Reaction for the MCMB Carbon as Anode in Li-ion Batteries (리튬이온 전지용 카본(MCMB) 부극재료의 전지반응 특성)

  • 박영태;류호진;김정식
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.172-177
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    • 1999
  • Graphite and carbonaceous materials showed an excellent capability as a negative electrode in Li-ion batteries because Li-ion can be intercalated and de-intercalated reversibly within most carbonaceous materials of layered structure. Also, the electrochemical potential of Li-intercalated carbon anode is almost identical with that of Li metal. In the present study, mesocarbon microbeads(MCMB) were used as anode electrode and its properties of charge/discharge and interfacial reaction with electrolyte were studied by Potentiostat/Galvanostat test, FT-IR analysis, XRD and SEM. The passivation film of solid-state was formed as the interface between electrode and electrolyte as the cell reaction began and, once formed, became thicker with repeated charge/discharge process. Also, the relationship between the passivation film formed at the electrode interface and storage capacity was discussed.

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