• Title/Summary/Keyword: Intermediate temperature

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Methodology of Ni-base Superalloy Development for VHTR using Design of Experiments and Thermodynamic Calculation (실험 계획법 및 열역학 계산법을 이용한 초고온가스로용 니켈계 초합금 설계 방법론)

  • Kim, Sung-Woo;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.132-141
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    • 2013
  • This work is concerning a methodology of Ni-base superalloy development for a very high temperature gas-cooled reactor(VHTR) using design of experiments(DOE) and thermodynamic calculations. Total 32 sets of the Ni-base superalloys with various chemical compositions were formulated based on a fractional factorial design of DOE, and the thermodynamic stability of topologically close-packed(TCP) phases of those alloys was calculated by using the THERMO-CALC software. From the statistical evaluation of the effect of the chemical composition on the formation of TCP phase up to a temperature of 950 oC, which should be suppressed for prolonged service life when it used as the structural components of VHTR, 16 sets were selected for further calculation of the mechanical properties. Considering the yield and ultimate tensile strengths of the selected alloys estimated by using the JMATPRO software, the optimized chemical composition of the alloys for VHTR application, especially intermediate heat exchanger, was proposed for a succeeding experimental study.

Spectroscopic Studies on Crystallization of Na, TPA-ZSM-5 synthesized at Low Temperature and Atomospheric pressure (저온 상압에서 합성된 Na, TPA-ZSM-5의 결정화에 관한 분광학적 고찰)

  • Yun, Young Ja;Ha, Jae Mok
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.18-30
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    • 1997
  • Na, TPA-ZSM-5 with Si / Al mole ratio of about 130 was synthesized at low temperature and atmospheric pressure. These intermediate products were characterized by using XRD, XRF, FT-IR, NMR, and SEM. As a result, intermediate product were different from those that synthesized by autoclave method but spectroscopic characteristics of the final products showed to be in the typical ZSM-5 region. The defect sites were observed in the final product and removed by calcination at $540^{\circ}C$. Na, TPA-ZSM-5, aboveall, was synthesized at this condition within 48hr.

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Electrical Characteristics of and Temperature Distribution in Chalcogenide Phase Change Memory Devices Having a Self-Aligned Structure (자기정렬구조를 갖는 칼코겐화물 상변화 메모리 소자의 전기적 특성 및 온도 분포)

  • Yoon, Hye Ryeon;Park, Young Sam;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.448-453
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    • 2019
  • This work reports the electrical characteristics of and temperature distribution in chalcogenide phase change memory (PCM) devices that have a self-aligned structure. GST (Ge-Sb-Te) chalcogenide alloy films were formed in a self-aligned manner by interdiffusion between sputter-deposited Ge and $Sb_2Te_3$ films during thermal annealing. A transmission electron microscopy-energy dispersive X-ray spectroscopy (TEM-EDS) analysis demonstrated that the local composition of the GST alloy differed significantly and that a $Ge_2Sb_2Te_5$ intermediate layer was formed near the $Ge/Sb_2Te_3$ interface. The programming current and threshold switching voltage of the PCM device were much smaller than those of a control device; this implies that a phase transition occurred only in the $Ge_2Sb_2Te_5$ intermediate layer and not in the entire thickness of the GST alloy. It was confirmed by computer simulation, that the localized phase transition and heat loss suppression of the GST alloy promoted a temperature rise in the PCM device.

Analysis of the Strength Property for TiC-Mo Composites at High Temperature

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.24 no.4
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    • pp.201-206
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    • 2014
  • TiC-21 mol% Mo solid solution (${\delta}$-phase) and TiC-99 mol% Mo solid solution (${\beta}$-phase), and TiC-(80~90) mol% Mo hypo-eutectic composite were deformed by compression in a temperature range from room to 2300 K and in a strain rate range from $4.9{\times}10^{-5}$ to $6.9{\times}10^{-3}/s$. The deformation behaviors of the composites were analyzed from the strengths of the ${\delta}$- and ${\beta}$-phases. It was found that the high strength of the eutectic composite is due primarily to solution hardening of TiC by Mo, and that the ${\delta}$-phase undergoes an appreciable plastic deformation at and above 1420 K even at 0.2% plastic strain of the composite. The yield strength of the three kinds of phase up to 1420 K is quantitatively explained by the rule of mixture, where internal stresses introduced by plastic deformation are taken into account. Above 1420 K, however, the calculated yield strength was considerably larger than the measured strength. The yield stress of ${\beta}$-phase was much larger than that of pure TiC. A good linear relationship was held between the yield stress and the plastic strain rate in a double-logarithmic plot. The deformation behavior in ${\delta}$-phase was different among the three temperature ranges tested, i.e., low, intermediate and high. At an intermediate temperature, no yield drop occurred, and from the beginning the work hardening level was high. At the tested temperature, a good linear relationship was held in the double logarithmic plot of the yield stress against the plastic strain rate. The strain rate dependence of the yield stress was very weak up to 1273 K in the hypo-eutectic composite, but it became stronger as the temperature rose.

A Study on Autoignition of Fish Meal with Change of Ambient Temperature (주위온도 변화에 따른 어분의 자연발화에 관한연구)

  • 목연수;최재욱
    • Journal of the Korean Society of Safety
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    • v.7 no.1
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    • pp.47-56
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    • 1992
  • Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

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Differences on Growth, Photosynthesis and Pigment Contents of Open-pollinated Pinus densiflora Families Under Elevated Temperature and Drought (온도 증가와 건조 스트레스에 따른 소나무 풍매차대묘의 가계간 생장, 광합성 및 광색소 함량 차이)

  • Kim, Gil Nam;Han, Sim-Hee;Park, Gwan Soo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.4
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    • pp.285-296
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    • 2014
  • The impacts of high temperature and drought were studied on the seedlings of three families (superiorgangwon74, intermediate-gangwon77 and inferior-gangwon132) of P. densiflora which had been selected by the based on the growth indexes of 32-year-old. The seedlings were grown in controlled-environment growth chambers with combinations of four temperatures ($-3^{\circ}C$, $0^{\circ}C$, $+3^{\circ}C$ $+6^{\circ}C$; based on the monthly average for 30 years in Korea) and two water conditions (control, drought). The growth performance, photosynthetic parameters and photosynthetic pigment contents were measured at every 30 days under four temperatures and drought condition, and the end of each treatment. The superior family showed higher relative diameter at root collar growth rate and the dry weight than intermediate and inferior family in all treatments. Under elevated temperature and drought condition, growth rate was decreased, and seedlings showed lower growth rate than that of control in three families under low temperature. Photosynthetic rate, stomatal conductance and transpiration rate of three families decreased with the increase of temperature and drought condition, and that of seedlings under low temperature was lower than control. But under elevated temperature and drought condition, water use efficiency increased in three families. Photosynthetic pigment contents of leaves decreased under the increase of temperature and drought condition, but chlorophyll a/b ratio increased with the increase of temperature and drought condition in three families. The superior family showed higher total chlorophyll content than intermediate and inferior family in all treatments. In conclusion, P. densiflora is under changed temperature and drought condition, growth was decreased, seedlings more affected in elevated temperature than that of decreased temperature. The increase in monthly average temperature in Korea of more than $6^{\circ}C$, P. densiflora seedling growth in depending on region may decrease. In this study, the superior family(gangwon74) showed more excellent growth and physiological responses than intermediate (gangwon77) and inferior(gangwon132) family under changes temperature and drought.

Evaluation of High-Temperature Structural Integrity Using Lab-Scale PCHE Prototype (SUS316L 로 제작된 실험실 수준 인쇄기판형 열교환기 시제품의 고온구조건전성 평가)

  • Song, Kee Nam;Hong, Sung Deok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.9
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    • pp.1189-1194
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    • 2013
  • The Intermediate Heat Exchanger (IHX) of a Very High Temperature Reactor (VHTR) is a core component that transfers the high heat of $950^{\circ}C$ generated in the VHTR to a hydrogen production plant. The Korea Atomic Energy Research Institute manufactured a lab-scale prototype of a Printed Circuit Heat Exchanger (PCHE) as a candidate for an IHX. In this study, as a part of a high-temperature structural integrity evaluation of the lab-scale PCHE prototype made of SUS316L, we carried out high temperature structural analysis modeling and macroscopic thermal and elastic structural analysis for the lab-scale PCHE prototype under helium experimental loop (HELP) test conditions as a precedent study prior to the performance test in HELP.

Effects of Metal Mg on Replacement Reaction of Molten Al for Fabrication of $Al_2$O$_3$//Al Composites (Al$_2$O$_3$/Al 복합체 제조시 용융 알루미늄의 치환반응에 미치는 금속 마그네슘의 영향)

  • 정두화;배원태
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.23-32
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    • 1998
  • Al2O3/Al composites were produced by immersing the sintered silica preform in molten aluminum which contained magnesium as impurity. Three distinct regions existed in the penetration behavior of molten me-tal with changing the reaction temperature. These regions are denoted as low temperature regime(75$0^{\circ}C$-85$0^{\circ}C$) intermediate regime(90$0^{\circ}C$-95$0^{\circ}C$) and high temperature regime(100$0^{\circ}C$$\leq$) In the low temperature regime the penetration speed of molten aluminum increased with increasing reaction temperature whereas it decreased in the intermediate regime due to the phase transition of alumina formed by displacement reac-tion. In the high temperature regime the penetration speed of molten aluminum was the highest at 100$0^{\circ}C$ which was 3.6 mm/hr But above 105$0^{\circ}C$ molten aluminum did not penetrate into the silica preform because of the formation of a dense spinel layer at the preform surface by magnesium in molten Al.

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Macroscopic High-Temperature Structural Analysis Model of Small-Scale PCHE Prototype (II) (소형 PCHE 시제품에 대한 거시적 고온 구조 해석 모델링 (II))

  • Song, Kee-Nam;Lee, Heong-Yeon;Hong, Sung-Deok;Park, Hong-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.9
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    • pp.1137-1143
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    • 2011
  • The IHX (intermediate heat exchanger) of a VHTR (very high-temperature reactor) is a core component that transfers the high heat generated by the VHTR at $950^{\circ}C$ to a hydrogen production plant. Korea Atomic Energy Research Institute manufactured a small-scale prototype of a PCHE (printed circuit heat exchanger) that was being considered as a candidate for the IHX. In this study, as a part of high-temperature structural integrity evaluation of the small-scale PCHE prototype, we carried out high-temperature structural analysis modeling and macroscopic thermal and elastic structural analysis for the small-scale PCHE prototype under small-scale gas-loop test conditions. The modeling and analysis were performed as a precedent study prior to the performance test in the small-scale gas loop. The results obtained in this study will be compared with the test results for the small-scale PCHE. Moreover, these results will be used in the design of a medium-scale PCHE prototype.

Effect of Fermentation Temperature and Salt Concentration on the Fermentation Rate of Dongchimi (발효온도와 소금농도가 동치미 발효속도에 미치는 영향)

  • Chang, Sang-Keun;Ko, Soon-Nam;Choi, Hee-Sook;Kim, Jong-Goon;Kim, Woo-Jung
    • Applied Biological Chemistry
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    • v.39 no.5
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    • pp.398-402
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    • 1996
  • This study was carried out to compare the fermentation rates of Dongchimi as affected by fermentation temperature and salt concentration of brining solution. The Dongchimi was prepared by fermentation of the radish in salt solutions of 2.0, 3.2 and 5.1% NaCl respectively with addition of garlic, green onion, ginger at $4^{\circ}C,\;10^{\circ}C,\;20^{\circ}C$. The fermentation was classified into 3 steps of initial, intermediate and final stages according to pH changes and the rates of fermentation and color change were calculated from intermediate stage. The time reached equilibrium in hardness of radish and salt concentration and their equilibrated values were also compared. Fermentation rate became more rapid as fermentation temperature and salt concentration increased. The rates of Hunter color change of Dongchimi liquid were increased as the temperature increased. The 'L' values decreased slowly, and 'a' and 'b' values increased rapidly to maximum at the intermediate stage. The time required to reach equilibrium was reduced for both salt concentration and hardness of radish as the fermentation temperature increased. The equilibrated values of salt concentration were increased while those of hardness of radish were decreased as the temperature and salt concentration increased. The data obtained can be used for prediction of some of the major characteristics of Dongchimi during fermentation.

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