• Title/Summary/Keyword: Interfacial properties

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Fabrication and Impact Properties of $Nb/MoSi_2-ZrO_2$ Laminate Composites ($Nb/MoSi_2-ZrO_2$ 적층복합재료의 제조 및 충격특성)

  • Lee, Sang-Pill;Yoon, Han-Ki;Kong, Yoo-Sik
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.29-34
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    • 2002
  • [ $Nb/MoSi_2-ZrO_2$ ] laminate composites have been successfully fabricated by alternately stacking $MoSi_2-ZrO_2$ powder layer and Nb sheet, followed by hot pressing in a graphite mould. The fabricating parameters were selected as hot press temperatures. The instrumented Charpy impact test was carried out at the room temperature in order to investigate the relationship between impact properties and fabricating temperatures. The interfacial shear strength between $MoSi_2-ZrO_2$ and Nb, which is associated with the fabricating temperature and the growth of interfacial reaction layer, is also discussed. The plastic deformation of Nb sheet and the interfacial delamination were macroscopically observed. The $Nb/MoSi_2-ZrO_2$ laminate composites had the maximum impact value when fabricated at 1623K, accompanying the increase of fracture displacement and crack propagation energy. The interfacial shear strength of $Nb/MoSi_2-ZrO_2$ laminate composites increased with the growth of interfacial reaction layer, which resulted from the increase of fabricating temperature. there is an appropriate interfacial shear strength for the enhancement of impact value of $Nb/MoSi_2-ZrO_2$ laminate composites. A large increase of interfacial shear strength restrains the plastic deformation of Nb sheet.

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Control of morphology and interfacial tension of PC/SAN blends with compatibilizer

  • Kim, J.H.;Kim, M.J.;Kim, C.K.;Lee, J.W.
    • Korea-Australia Rheology Journal
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    • v.13 no.3
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    • pp.125-130
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    • 2001
  • Block copolymers of PC-b-PMMA (polycarbonate-b-polymethylmethacrylate) and PC -b-SAN (polycarbonate-b-(styrene-c-acrylonitrile)), were examined as compatibilizers for blonds of PC with SAN copolymer. The average diameter of the dispersed particles was measured with an image analyser, and the interfacial properties of the blonds were analysed with an imbedded fiber retraction (IFR) technique. The average diameter of dispersed particles and interfacial tension of the PC/SAN blends reached a minimum value when the SAN copolymer contained about 24 wt% AN. Interfacial tension and particle size were further reduced by adding compatibilizer to the PC/SAN blends. PC-b-PMMA was more effective than PC-b-SAN as a compatibilizer in reducing the average diameter of the dispersed particles and interfacial tension of PC/SAN blend. A direct proportionality between the particle diameter and interfacial tension was also observed. The interfacial properties of the PC/SAN blends were optimized by adding a block copolymer and using an SAN copolymer that had minimum interaction energy with PC.

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Modeling of Single Fiber Pull-Out Experiment Considering the Effects of Transverse Isotropy (횡방향 등방성을 고려한 단섬유 인장 실험 모델링)

  • Seol, Il-Chan;Lee, Choon-Yeol;Chai, Young-Suck
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1384-1392
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    • 2002
  • Single fiber pull-out technique has been commonly used to characterize the mechanical behavior of interface in fiber reinforced composite materials. An improved analysis considering the effects of transversely isotropic properties of fiber and the effects of thermal residual stresses in both radial and axial directions along the fiber/matrix interface is developed for the single fiber pull-out test. Although the stress transfer properties across the interface is not much affected by considering the transversely isotropic properties of fiber, interfacial debonding is notably encouraged by the effect. The interfacial shear stress that plays an important role in interfacial debonding is very much affected by the component of axial thermal residual stress in the bonded region, which can induce a two-way debonding mechanism.

Anormal Dielectric and Insulation Properties of Semiconductor/XLPE (반도전층/XLPE 의 불규칙한 유전 및 절연 특성)

  • Lee, Jong-Chan;Kim, Kwang-Soo;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.53-57
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    • 2002
  • Reduction of insulation thickness would be beneficial not only for increasing the cable length but would also improve its thermal performance. An interfacial diffusion method was devised to reduce insulation thickness by improving the interfacial properties of XLPE cable insulation. In this paper, to evaluate superficially the interface properties between XLPE insulation and semiconducting layer, the dielectric and insulation properties of tan${\delta}$ and volume resistance were measured with temperature dependence. Above the results, dielectirc and insulation properties with semiconductor/XLPE were more anormal than its bulk caused by the interfacial properties.

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Effect of Silane Coupling Agent on the Interfacial Adhesion and Mechanical Properties of Polyketone Fiber Reinforced Epoxy Composites (실란커플링제 처리가 폴리케톤섬유/에폭시 복합재료의 계면접착성 및 물성에 미치는 영향)

  • Jo, Hani;Yang, Jee-Woo;Lim, Hyeon Soo;Oh, Woo Jin;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.29 no.2
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    • pp.77-85
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    • 2017
  • The interfacial adhesion between fiber and matrix affects the physical properties of fiber reinforced composites. In this study, 3-(Methacryloyloxy)propyltrimethoxy silane(MPS) coupling agent was used to increase the interfacial adhesion between polyketone fiber and epoxy resin. The change of surface chemical composition of polyketone fiber treated with MPS was analyzed using a FTIR-ATR. The interfacial bonding between fiber and resin increased with silane coupling agent largely. Consequently, interfacial shear strength(IFSS) was enhanced with increasing concentration of MPS coupling agent and thus, the physical properties of the composites such as flexural properties and dynamic mechanical properties were changed. Flexural strength and modulus increased when the MPS concentration was higher than 0.5wt%. The dynamic storage modulus of Polyketone/Epoxy composites treated with MPS was higher than that of the untreated one. When the MPS concentration of 3wt%, the highest storage modulus was obtained.

A Study on the Mechanical Properties of Interfacial Transition Zone (ITZ) of Lightweight High Strength Concrete Via Nanoindentation (나노 인덴테이션을 통한 경량 고강도 콘크리트 Interfacial Transition Zone (ITZ)의 역학적 특성에 관한 연구)

  • Im, Su-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.537-544
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    • 2020
  • The interfacial transition zone(ITZ) which is the boundary layer between cement composites and aggregates is considered to be the region of gradual transition, heterogeneous, and the weakest part of concrete. For the development of lightweight high strength concrete, it is essential to evaluate the mechanical properties of ITZ between high strength concrete with low water-binder ratio and lightweight aggregates. However, the mechanical properties of ITZ are not well established due to its high porosity and complex structure. Furthermore, the properties of ITZ in concrete using lightweight aggregates are dominated by more various variations (e.g. water-binder ratio, water absorption capacity of aggregate, curing conditions) than normal-weight aggregate concrete. This study aims to elucidate the mechanical properties of ITZ in lightweight high-strength cement composites according to the types of aggregates and the aggregate sizes. Nanoindentation analysis was used to evaluate the elastic modulus of ITZ between high strength cement composites with the water-binder ratio of 0.2 and normal sand, lightweight aggregate with different aggregate siz es of 2mm and 5mm in this study.

Effects of electrochemical oxidation of carbon fibers on interfacial shear strength using a micro-bond method

  • Kim, Dong-Kyu;An, Kay-Hyeok;Bang, Yun Hyuk;Kwac, Lee-Ku;Oh, Sang-Yub;Kim, Byung-Joo
    • Carbon letters
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    • v.19
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    • pp.32-39
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    • 2016
  • In this work, we studied the effects of electrochemical oxidation treatments of carbon fibers (CFs) on interfacial adhesion between CF and epoxy resin with various current densities. The surface morphologies and properties of the CFs before and after electrochemical-oxidation-treatment were characterized using field emission scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and single-fiber contact angle. The mechanical interfacial shear strength of the CFs/epoxy matrix composites was investigated by using a micro-bond method. From the results, electrochemical oxidation treatment introduced oxygen functional groups and increased roughness on the fiber surface. The mechanical interfacial adhesion strength also showed higher values than that of an untreated CF-reinforced composite.

A study on analysis of interfacial breakdown properties with variable temperalure in straight cable Joint modeling EPGXY/EPOM interface (온도에 따른 케이블 직선 접속재 모델링 EPOXY/EPDM 계면의 파괴 특성에 관한 연구)

  • 배덕권;정인재;김상걸;정일형;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.532-535
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    • 1999
  • In power cable joints, the interfaces of two different dielectric materials are inevitable. In addition, the interfacial breakdown between two internal dielectric surfaces represents one of the major causes of failure for power cable joints. We chose epoxy/EPDM interface, one of the interface in cable joints, and investigate dielectric interfacial breakdown phenomenon. First, design specimen with Flux 2D. Second, find interface condition which has high dielectric strength. Third, investigate interfacial breakdown properties with variable temperature.

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Improvement of Mechanical Interfacial Properties of Epoxy/Clay Nanocomposites Using Silane Intercalant (실란유기화제를 이용한 에폭시/클레이 나노복합재료의 기계적 계면 물성 향상)

  • Park, Soo-Jin;Seo, Dong-Il;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.125-128
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    • 2001
  • In this wort, the $Na^+-MMT$ has organically modified with silane intercalant to prepare the polymer/clay nanocomposites. The pH. X-ray diffraction (XRD), and contact angles were used to analyze the surface properties of clay and the exfoliation phenomenon of clay interlayer, The mechanical interfacial properties of epoxy/clay nanocomposites were investigated by three-point bending test. From the experimental results. the surface modification made by silane intercalant on clay surface leads to an increase of distance of silicate layers, surface acid value. and electron acceptor parameter of organoclay. The treatments are also necessary and useful for epoxy to intercalate into the interlayer by interacting of electron donor-accepter between basic epoxy and clay surface. The mechanical interfacial properties of the nanocomposites was improved by the presence of dispersed clay nanolayer containing low content of organoclay in comparison with the conventional, which increase the interfacial adhesion between dispersed clay and epoxy resins.

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Effect of Oxy-Fluorinated Carbon Fiber Surfaces on Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites (산소-불소처리된가 탄소섬유 강화 복합재료의 기계적 계면특성에 미치는 영향)

  • Oh Jin-Seok;Lee Jae Rock;Park Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.100-103
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    • 2004
  • In this work, the effects of oxy-fluorination on surface characteristics of carbon fibers were investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by X-ray photoelectron spectroscopy (XPS), FT-IR. and contact angle measurements. And their mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical stress intensity factor $(K_{IC})$. As experimental results, the $F_{1S}/C_{1S}$ ratio of carbon fiber surfaces was increased by oxy-fluorination, due to the development of the oxygen containing functional groups. The mechanical interfacial properties of the composites, including ILSS and $K_{IC}$, had been improved in the oxy-fluorination on fibers. These results could be explained that the oxy-fluorination was resulted in the increase of the adhesion between fibers and matrix in a composite system.

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