• 제목/요약/키워드: Interfacial Tension

검색결과 186건 처리시간 0.028초

동적 접촉각 측정을 이용한 실리콘고무 블렌드의 발수성회복 검토 (Hydrophobisity Recovery of PDMS Blended with Fluorinated Silicone Rubber Using Dynamic Contact Angle Measurement)

  • 이창용;류성식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.6-8
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    • 2001
  • This report describes the effect of the blending of poly(trifluoropropylmethylvinylsiloxane) (PTFPMVS) with poly(dimethylsiloxane) (PDMS) on the surface properties such as water repellency using dynamic contact angle (DCA) measurement. We have investigated the surface molecular mobility of the PDMS/PTFPMVS blends via a DCA measurement and an adhesion tension relaxation. It could be shown that a flexible side-chain segment in PTFPMVS having higher surface energy, could be reoriented easily in water to decrease the interfacial tension of the polymer/water interface, which seems to play a major role at the decrease of the receding contact angle and the surface resistivity of PDMS/PTFPMVS blends.

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2-유체 모델의 고유치에 근거한 기포류에서의 계면압력도약항 (Mechanistic Pressure Jump Terms based on the System Eigenvalues of Two-Fluid Model for Bubbly Flow)

  • 정문선;이원재;이성재;송철화;하귀석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.81-86
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    • 2001
  • Interfacial pressure jump terms based on the physics of phasic interface and bubble dynamics are introduced into the momentum equations of the two-fluid model for bubbly flow. The pressure discontinuity across the phasic interface due to the surface tension force is expressed as the function of fluid bulk moduli and bubble radius. The consequence is that we obtain from the system of equations the real eigenvalues representing the void-fraction propagation speed and the pressure wave speed in terms of the bubble diameter. Inversely, we obtain an analytic closure relation for the radius of bubbles in the bubbly flow by using the kinematic wave speed given empirically in the literature. It is remarkable to see that the present mechanistic model using this practical bubble radius can indeed represent both the mathematical well-posedness and the physical wave speeds in the bubbly flow.

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초소형 밀폐형 이상 써모싸이폰 기포의 거동에 관한 해석적인 연구 (Analytical Study on the Behavior of the Bubble in the Micro Two-Phase Closed Thermosyphon)

  • 이윤표;이영수;이영
    • 설비공학논문집
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    • 제5권2호
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    • pp.85-93
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    • 1993
  • The rise of a large gas bubble or slug in a Micro Two-Phase Closed Thermosyphon with a thin wire insert has been analiged by the potential flow theory. The effect of the interfacial surface tension is explicitly accounted by application of the Kelvin-Laplace equation and solved for the bubble shape. The solution is expressed in terms of the Stokes stream function which consists of an infinite series of Bessel functions. The conditions of the bubble movement in a Micro Two-Phase Closed Thermosyphon were theoretically ascertained.

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Vapor-liquid Interface of Argon by Using a Test-area Simulation Method

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.167-170
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    • 2012
  • A test-area molecular dynamics simulation method for the vapor-liquid interface of argon through a Lennard-Jones intermolecular potential is presented in this paper as a primary study of interfacial systems. We found that the calculated density profile along the z-direction normal to the interface is not changed with time after equilibration and that the values of surface tension computed from this test-area method are fully consistent with the experimental data. We compared the thermodynamic properties of vapor argon, liquid argon, and argon in the vapor-liquid interface. Comparisons are made with kinetic and potential energies, diffusion coefficient, and viscosity.

Bond between FRP formworks and concrete-effect of surface treatments and adhesives

  • Goyal, Reema;Mukherjee, Abhijit;Goyal, Shweta
    • Steel and Composite Structures
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    • 제20권3호
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    • pp.671-692
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    • 2016
  • FRP stay-in-place (SIP) formworks are designed as a support for casting concrete and as a tension reinforcement when concrete is cured. Bond development between SIP formwork and concrete is critical for FRP tension element to be effective. This paper reports the bond strength between FRP formwork and concrete for different interfacial treatments. A novel experimental setup is prepared for observing the bond behaviour. Three different adhesives with varying workability have been investigated. Along with the load-deformation characteristics, bond slip and strains in the formwork have been measured. A finite element numerical simulation was conducted for the experiments to understand the underlying mechanism. The results show that the adhesive bonding has the best bond strength.

유화액 시스템에서 옥테닐 호박산 베타글루칸의 계면 특성 (Interfacial Properties of Octenyl Succinyl Barley ${\beta}$-Glucan in Emulsion System)

  • 길나영;김산성;이의석;신정아;이기택;홍순택
    • 한국응용과학기술학회지
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    • 제31권4호
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    • pp.642-652
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    • 2014
  • The synthesis of octenyl succinyl ${\beta}$-gucan (OSA-${\beta}$-glucan) was carried out and its interfacial properties at the oil-water interface and in emulsion systems were investigated. An aqueous ethanol system as a reaction media was used to facilitate the synthesis process; 10% (w/w) ethanol found to be the best as it showed a maximum degree of substitution (DS: 0.0132). FT-IR showed a characteristic absorption spectrum at $1736cm^{-1}$, indicating the esterification of octenyl succinyl groups to ${\beta}$-glucan backbone. As for interfacial tension measurements, it was decreased with increasing concentration of OSA-${\beta}$-glucan in the aqueous phase and when NaCl was added to aqueous OSA-${\beta}$-glucan solution in the range of 0.01 M to 0.1 M and also when pH was raised (pH 3 ~ pH 9). In systems of emulsion stabilized with OSA-${\beta}$-glucan, fat globule size found to decrease with increasing concentration of OSA-${\beta}$-glucan, showing a critical value of about $0.32{\mu}m$ at 0.5 wt%. When the OSA-${\beta}$-glucan emulsions were stored, it was found that fat globule size was increased with storage time and particularly pronounced increase was observed in emulsion with 1% OSA-${\beta}$-glucan, possibly due to depletion flocculation. Results of creaming stability evaluated by light scattering technique showed that it was more stable in emulsions containing smaller fat globule size. Surface load of OSA-${\beta}$-glucan in emulsions increased with increasing concentration of OSA-${\beta}$-glucan, suggesting a multilayer adsorption.

Micromechanical 시험법과 음향방출을 이용한 플라즈마 처리된 PBO와 Kevlar 섬유강화 Epoxy 복합재료의 비파괴적 파단특성 및 계면물성 평가 (Nondestructive Microfailure and Interfacial Evaluation of Plasma-Treated PBO and Kevlar Fibers/Epoxy Composites using Micromechanical Test and Acoustic Emission)

  • 박종만;김대식;김성룡
    • Composites Research
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    • 제16권4호
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    • pp.74-79
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    • 2003
  • Micromechanical 시험법과 음향방출을 이용하여 산소 플라즈마 처리된 PBO와 Kevlar 섬유강화 에폭시 복합재료의 계면물성과 미세파괴메카니즘을 고찰하여 상호 비교하였다. 산소 플라즈마 처리된 PBO와 Kevlar 섬유강화 에폭시 복합재료의 계면전단강도와 접착일은 극성 작용기의 도입으로 향상 시킬 수 있었다. 임계표면장력과 총 표면자유에너지 중 극성 표면자유에너지는 플라즈마 처리된 Kevlar 섬유에서 가장 컸으며. 미처리된 PBO의 섬유의 경우에서 가장 작았다. Microfibril 파단 형상은 산소 플라즈마 처리된 Keviar 섬유의 경우에서는 명확하게 관찰 되었으며. 미처리와 비교차여 microfibril 파단이 대각선 방향으로 연속적해서 일어나 가장 많은 섬유 파단 신호가 감지되었다 비파괴 음향방출법을 이용하여 얻은 섬유파단 감지 결과는 microdroplet과 두 섬유강화 복합재료 시험법에서 광학현미경을 이용하여 관찰한 미세파단 형상과 상호 일치하였다.

Micromechanical 시험법을 이용한 Kenaf 및 Ramie 섬유 강화 에폭시 복합재료의 계면물성 평가 (Interfacial Evaluation of Single Ramie and Kenaf Fibers/Epoxy Composites Using Micromechanical Technique)

  • 박종만;트란콩손;정진규;김성주;황병선
    • 접착 및 계면
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    • 제6권2호
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    • pp.13-20
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    • 2005
  • 환경 친화적인 자연섬유 강화 고분자 복합재료의 계면 전단강도는 총체적인 기계적 물성을 조절하는데 매우 중요한 역할을 수행한다. Ramie와 Kenaf 섬유 강화 에폭시 복합재료의 계면 전단강도는 최종 물성을 위한 최적 조건을 찾아내기 위해 미세역학시험법과 비파괴 음향방출시험을 이용하여 평가했다. Ramie와 Kenaf 섬유의 동적 접촉각을 측정했고, 계면 접착에서 젖음성과 상호 관련시켜서 해석하였다. Ramie와 Kenaf 섬유의 기계적 물성은 단섬유 인장시험을 통해 조사했고, 통계학적으로 uni-와 bimodal Weibull 분포를 통해서 분석하였다. Ramie와 Kenaf 섬유에 대한 실제 신장율의 clamping 효과의 영향도 평가할 수 있었다. 두 가지의 다른 미세파괴 형상은 섬유다발과 단섬유 복합재료로부터 오는 축방향의 debonding과 섬유상의 fracture는 인장과 압축하중하에서 관찰할 수 있었다.

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알루미늄으로 제작된 심해 장비의 부식 저항 능력 향상 방법 및 측정 방법 조사 (Study on Methods of Enhancement and Measurement of Corrosion Resistance for Subsea Equipment made of Aluminum)

  • 서영균;정정열
    • 플랜트 저널
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    • 제16권3호
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    • pp.47-52
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    • 2020
  • 본 연구에서는 알루미늄으로 제작된 심해 장비의 부식 저항 능력 향상시키기 위해 알루미늄 부식 방지 방법과 측정방법을 조사하였다. 조사된 부식 방지 방법은 Cathodic Protection(음극화 보호), Conversion Coating, Anodizing, 및 Organic Coating이었다. 그리고 간단하게 조사된 측정 방법은 Scanning Electron Microscope (SEM), Electrochemical Impedance Spectroscopy (EIS), Glow discharge optical emission spectrum spectroscopy (GD-OES), Fourier Transform Infrared Spectroscopy (FT-IR), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Scanning Vibrating Electrode Technique (SVET), Contact Angle(접촉각), Interfacial Tension (경계면 장력)이었다. 알루미늄 부식을 방지하기 위해 널리 사용되는 방법은 Anodizing과 Organic Coating이었으며, 부식 측정을 위해서는 여러 방법들이 골고루 사용되었다. 그 중 많이 사용되는 방법은 표면의 구조를 관찰하 위한 SEM과 부식 저항 능력을 측정하기 위한 접촉각 측정이었다.

섬유보강재로 전단보강된 RC보의 전단강도예측을 위한 해석모델에 대한 연구 (A Study on the Prediction Model of Shear Strength of RC Beams Strengthened for Shear by FRP)

  • 심종성;오홍섭;유재명
    • 콘크리트학회논문집
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    • 제12권5호
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    • pp.35-46
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    • 2000
  • In this paper, an analytical model is proposed to predict the shear strenth of RC beams strengthened by FRP. This predictional model is composed of two basic models-the upper bound theorem for shear failure (shear tension or shear compression criteria) and a truss model based on the lower bound theorem for diagonal tension creteria. Also, a simple flexural theory based on USD is used to explain flexural failure. The major cause of destruction of RC beams shear strengthened by FRP does not lie in FRP fracture but in the loss of load capacity incurred by rip-off failure of shear strengthening material. Since interfacial shear stree between base concrete and the FRP is a major variable in rip-off failure mode, it is carefully analyzed to derive the shear strengthening effect of FRP. The ultimate shear strength and failure mode of RC beams, using different strengthening methods, estimated in this predictional model is then compared with the result derived from destruction experiment of RC beams shear strengthened using FRP. To verify the accuracy and consistency of the analysis, the estimated results using the predictional model are compared with various other experimental results and data from previous publications. The result of this comparative analysis showed that the estimates from the predictional model are in consistency with the experimental results. Therefore, the proposed shear strength predictional model is found to predict with relative accuracy the shear strength and failure mode of RC beams shear strengthened by FRP regardless of strengthening method variable.