• The Journal of Advanced Prosthodontics
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• 제7권1호
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• pp.39-46
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• 2015

PURPOSE. The mechanical and interfacial characterization of laser welded Co-Cr alloy with two different joint designs. MATERIALS AND METHODS. Dumbbell cast specimens (n=30) were divided into 3 groups (R, I, K, n=10). Group R consisted of intact specimens, group I of specimens sectioned with a straight cut, and group K of specimens with a $45^{\circ}$ bevel made at the one welding edge. The microstructure and the elemental distributions of alloy and welding regions were examined by an SEM/EDX analysis and then specimens were loaded in tension up to fracture. The tensile strength (TS) and elongation (${\varepsilon}$) were determined and statistically compared among groups employing 1-way ANOVA, SNK multiple comparison test (${\alpha}$=.05) and Weibull analysis where Weibull modulus m and characteristic strength ${\sigma}_0$ were identified. Fractured surfaces were imaged by a SEM. RESULTS. SEM/EDX analysis showed that cast alloy consists of two phases with differences in mean atomic number contrast, while no mean atomic number was identified for welded regions. EDX analysis revealed an increased Cr and Mo content at the alloy-joint interface. All mechanical properties of group I (TS, ${\varepsilon}$, m and ${\sigma}_0$) were found inferior to R while group K showed intermediated values without significant differences to R and I, apart from elongation with group R. The fractured surfaces of all groups showed extensive dendritic pattern although with a finer structure in the case of welded groups. CONCLUSION. The K shape joint configuration should be preferred over the I, as it demonstrates improved mechanical strength and survival probability.

• 한국콘텐츠학회논문지
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• 제10권10호
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• pp.219-225
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• 2010

티타늄 표면처리방법 중 gold 코팅, TiN 코팅, 그리고 전용결합재를 복합적으로 사용하여 티타늄과 세라믹의 결합강도에 미치는 영향을 분석하고자 하였다. 티타늄과 세라믹의 3점 굽힘 결합강도를 측정한 결과, TiN 코팅과 전용결합재로 처리한 SPTB군이 $72.20({\pm}5.25)MPa$로 가장 높게 나타났으며, 전용결합재로 처리한 SPB군($67.66({\pm}12.10)MPa$), gold 코팅과 전용결합재로 처리한 SPGB군($46.95({\pm}12.48)MPa$), 코팅과 전용결합재로 처리하지 않은 SP군$(43.80({\pm}5.12)MPa)$ 순으로 나타났다. 시편들의 결합강도를 통계 분석한 결과, 전용 결합재로 처리한 SPB군과 TiN코팅과 전용결합재로 처리한 SPTB군이 결합력이 유사하게 나타났으며, 전용결합재로 처리한 군(SPB)이 처리하기 않은 군(SP)에 비하여 결합력이 높게 나타났으며, TiN 코팅한 군(SPTB)이 gold 코팅한 군(SPGB)에 비하여 결합력이 높게 나타난 것으로 관찰되었다.

• 한국재료학회지
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• 제19권2호
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• pp.111-114
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• 2009

For the fabrication of core-shell structure bimetallic lead-free solder balls, both the critical temperature ($T_{cr}$) for the phase separation of two immiscible liquid phases and the temperature coefficient of the interfacial tension between the two separated liquid phases are required. In order to obtain this information, the temperature dependence of the surface tension of 60%Bi-24%Cu-16%Sn(-REM) alloys was measured using the constrained drop method. The slope of the temperature dependence of the surface tension changed clearly at a critical temperature for the separation of two immiscible liquid phases. The critical temperature of the 60%Bi-24%Cu-16%Sn alloy was estimated to be 1097K. An addition of 0.05% Ce decreased the critical temperature to 1085K, whereas that of 0.05% La increased it to 1117K. It was found that the surface tension and its temperature coefficient of the 60%Bi-24%Cu-16%Sn alloy were slightly increased by the addition of 0.05% Ce and 0.05% La. In addition, additions of Ce and La increased the temperature coefficient of the interfacial tension.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.234-238
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• 2008

The efficiency of fiber reinforced CMC(ceramic matrix composite) on the SiC materials have been investigated, in conjunction with the fabrication process by liquid phase sintering and the characterization. LPS-$SiC_f$/SiC composites was studied with the detailed analysis such as the microstructure, sintered density, flexural strength and fracture behavior. The applicability of carbon interfacial layer has been also investigated in the LPS process. Submicron SiC powder with the constant total amount and composition ratio of $Al_2O_3,\;Y_2O_3$ as sintering additives was used in order to promote the performance of the SiC matrix material. LPS-$SiC_f$/SiC composites were fabricated with hot press under the sintering temperature and applied pressure of $1820^{\circ}C$ and 20MPa for 1hr. The typical property of monolithic LPS-SiC materials was compared with LPS-$SiC_f$/SiC composites.

• 한국응용과학기술학회지
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• 제26권3호
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• pp.288-296
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• 2009

In this study, the silica-based hybrid material with high barrier property was prepared by incorporating ethylene-vinyl alcohol (EVOH) copolymer, which has been utilized as packaging materials due to its superior gas permeation resistance, during sol-gel process. In preparation of this EVOH/$SiO_2$ hybrid coating materials, the (3-glycidoxy-propyl)-trimethoxysilane (GPTMS) as a silane coupling agent was employed to promote interfacial adhesion between organic and inorganic phases. As confirmed from FT-IR analysis, the physical interaction between two phases was improved due to the increased hydrogen bonding, resulting in homogeneous microstructure with dispersion of nano-sized silica particles. However, depending on the range of content of added silane coupling agent (GPTMS), micro-phase separated microstructure in the hybrid could be observed due to insufficient interfacial attraction or possibility of polymerization reaction of epoxide ring in GPTMS. The oxygen barrier property of the mono-layer coated BOPP (biaxially oriented polypropylene) film was examined for the hybrids containing various GPTMS contents. Consequently, it is revealed that GPTMS should be used in an optimum level of content to produce the high barrier EVOH/$SiO_2$ hybrid material with an improved optical transparency and homogeneous phase morphology.

• Composites Research
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• 제27권5호
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• pp.196-200
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• 2014

A novel, simple and totally recyclable method has been developed for the synthesis of nontoxic, biocompatible and biodegradable bio-composite films from soy protein and silk protein. Bio films are defined as flexible films prepared from biological materials such as protein. These materials have potential application in medical and food as a packaging material. Their use depends on various parameters such as mechanical (strength and modulus), thermal, among others. In this study, prepare and characterization of bio films made from Soy Protein Isolate (SPI) (matrix) and Silk Fiber (SF) (reinforcement) through solution casting method by the addition of plasticizer and crosslinking agent. The obtained SPI and SPI/SF composites were subsequently subjected to evaluate their mechanical and thermal properties by using Universal Testing Machine and Thermal Gravimetric Analyzer respectively. The tensile testing showed significant improvements in strength with increasing amount of SF content and the % elongation at break of the composites of the SPI/SF was lower than that of the matrix. Though the interfacial bonding was moderate, the improvement in tensile strength and modulus was attributed to the higher tensile properties of the silk fiber.

• 센서학회지
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• 제5권6호
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• pp.60-67
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• 1996

저온 remote PECVD $SiO_{2}$막을 이용하여 제조된 InSb MIS구조에서의 계면의 전기적 특성에 대하여 연구하였다. $105^{\circ}C$에서 증착시킨 $SiO_{2}$막을 이용한 MIS구조의 중간 에너지 대역폭에서의 계면상태밀도가 $1{\sim}2{\times}10^{11}\;cm^{-2}eV^{-1}$으로 평가되었다. 그러나, $105^{\circ}C$이상의 고온에서 제조된 MIS소자의 계면에는 다량의 계면준위 및 트랩 준위가 존재하였다. G-V측정으로부터 계산된 계면준위들의 시상수는 $10^{-4}{\sim}10^{-5}\;sec$였으며, 증착온도가 증가할수록 트랩밀도가 증가하여 C-V특성곡선의 이력특성이 증대되었다.

• Membrane and Water Treatment
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• 제8권4호
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• pp.323-336
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• 2017

The main challenge in many applications of acetic acid is acid dehydration and its recovery from wastewater streams. Therefore, the performance of polyamide thin film composite is evaluated to separate acetic acid from water. To reach this goal, the formation of polyamide layer on polysulfone support membrane was investigated via interfacial polymerization (IP) of meta-phenylenediamine (MPD) in water with trimesoyl chloride (TMC) in hexane. Also, the effect of synthesis conditions, such as concentration of monomers and curing temperature on separation of acetic acid from water were investigated by reverse osmosis process. Moreover, the separation mechanism was discussed. The solute permeation was carried out under applied pressure of 5 bar at $25^{\circ}C$. Surface properties of TFC membrane were characterized by ATR-FTIR, SEM and AFM. The performance test indicated that 3.5 wt% of MPD, 0.35 wt% of TMC and curing temperature of $75^{\circ}C$ are the optimum conditions. Moreover, the permeate flux was $4.3{\frac{L}{m^2\;h}}$ and acetic acid rejection was about 43% at these conditions.

• Membrane and Water Treatment
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• 제6권4호
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• pp.309-321
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• 2015

We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

• 한국의류학회지
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• 제34권11호
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• pp.1889-1899
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• 2010

This study examines the preparation and characterization of Kenaf/Starch bio-composites used as filler and a matrix. Kenaf was cultivated in Chung-ju in Korea, and the Kenaf/Starch bio-composites were prepared under various conditions of kenaf fiber length (1-5 centimeters); the content of Kenaf fiber was 10%, 20%, 30%, and 40%, and the number of composite layers (one-four). Depending on the formation conditions of Kenaf/Starch composites, the physical properties such as tensile strength, elongation, and the young modulus of the Kenaf/Starch composites were measured. In addition, we measured the SEM cross-section images in order to investigate the interfacial adhesion properties of fractured surfaces. As a result, the tensile strength and elongation of the Kenaf/Starch composites were highest in the molding conditions of a hot press at $120^{\circ}C$, 3000PSI of pressure, and for 30 minute periods. The result of measuring the physical properties of the composites manufactured by varying the content of Kenaf fiber when the content of Kenaf fiber was 30% as well the physical properties of the Kenaf/Starch composite was found desirable. It was found that the physical properties improved with more overlapped layers in the composites manufactured by varying the number of overlapped layers. Through the measuring of the SEM cross-section images, we found that the interfacial adhesion state between the filler and matrix of Kenaf/Starch composite greatly affects the physical properties.