• Bulletin of the Korean Chemical Society
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• 제18권9호
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• pp.1010-1013
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• 1997

Nucleophilic substitution reactions of (Z)-phenylethyl (X)-benzenesulfonates with (Y)-pyridines were investigated in acetonitrile at 60 ℃ under respective pressures. The magnitudes of the Hammett reaction constants, ρX, ρY and ρZ indicate that a stronger nucleophile leads to a greater degree of bond formation of C-N and a better leaving group is accompanied by a less degree of bond breaking. The magnitude of correlation interaction term, ρij can be used to determine the structure of the transition state (TS) for the SN reaction. As the pressure is increased, the Hammett reaction constants, ρX and |ρY|, are decreased, but correlation interaction coefficient, ρXZ and |ρYZ|, are increased. The results indicate that the reaction of (Z)-phenylethyl (X)-benzenesulfonates with (Y)-pyridines probably moves from a dissociative SN2 to early-type concerted SN2 mechanism by increasing pressure. This result shows that the correlation interaction term ρij can be useful tool to determine the structure of TS, and also the sign of the product ρXZ·ρYZ can be predict the movement of the TS.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2004년도 추계학술대회 논문집
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• pp.119-122
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• 2004

Since a derailment of rolling stocks results in huge losses in properties and lives, the measurement of a derailment coefficient is a very important test item to estimate the running safety of rolling stocks. For a measurement of the derailment measurement of forces between the wheel and rail a measuring wheel-set should be made first. The process to make a measuring wheel-set has some stages for correct measurement. They are as follows; a finite element analysis of a wheel to find a position of holes at which vertical force shall be measured, a finite element analysis for the position of strain gauges.

• International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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• 제6권1호
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• pp.7-14
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• 2003

The interaction of monochromatic incident waves with a submerged horizontal porous membrane is investigated in the context of two-dimensional linear hydro-elastic theory. It is assumed that the membrane is made of material with very fine pores so that the normal velocity of the fluid passing through the porous membrane is linearly proportional to the pressure difference between two sides of the membrane (e.g. Darcy's law). Using the Eigen-function expansion method, the wave-blocking performance of a submerged horizontal porous membrane is tested with various membrane tensions, porosities, lengths, and submerged depths. It is found that an optimal combination of design parameters exists for given water depth and wave characteristics.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.743-748
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• 2007

The important factor to evaluate the running safety of a railway vehicle would be the interaction force between wheel and rail(derailment coefficient), for which is one of important factors to check the running safety of a railway vehicle that may cause a tragic accident. Especially, a newly developed vehicle that first runs commercially requires necessarily the measurement and evaluation of derailment coefficient for securing the safety of a vehicle while measuring the derailment coefficient in view of securing running safety could be the more important factor than any other factors. In this paper, examined possibility that can forecast derailment possibility to behavior of only vibration and displacement by measuring vibration acceleration and displacement in vehicles that travel actuality rail track, and compares with data of wheel load/lateral force result.

• Communications for Statistical Applications and Methods
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• 제19권6호
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• pp.809-817
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• 2012

We propose a semiparametric inference for a generalized varying coefficient partially linear model(VCPLM) for negative binomial data. The VCPLM is useful to model real data in that varying coefficients are a special type of interaction between explanatory variables and partially linear models fit both parametric and nonparametric terms. The negative binomial distribution often arise in modelling count data which usually are overdispersed. The varying coefficient function estimators and regression parameters in generalized VCPLM are obtained by formulating a penalized likelihood through smoothing splines for negative binomial data when the shape parameter is known. The performance of the proposed method is then evaluated by simulations.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• 제3B권3호
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• pp.115-121
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• 2003

This paper proposes a radiation model, which considers radiation transport as an important component in hot gas analysis. This radiation model is derived from combining the method of partial characteristics (MPC) with net emission coefficient (NEC), and it covers the drawbacks of existing models. Subsequently, using this proposed model, the arc-flow interaction in an arcing chamber can be efficiently computed. The arc is represented as an energy source term composed of ohmic heating and the radiation transport in the energy conservation equation. Ohmic heating term was computed by the electric field analysis within the conducting plasma region. Radiation transport was calculated by the proposed radiation model. Also, in this paper, radiation models were introduced and applied to the gas circuit breaker (GCB) model. Through simulation results, the efficiency of the proposed model was confirmed.

• Bulletin of the Korean Chemical Society
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• 제6권3호
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• pp.128-131
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• 1985

A series of copolymer membranes of 2-hydroxyethylmethacrylate (HEMA) with selected hydrophobic monomers were prepared without crosslinking agents. The equilibrium water content, the partition coefficient, and the permeability of the solutes such as urea, methylurea, 1,3-di-methylurea, and acetamide via these membranes were measured. The partition coefficient data show that as the hydrophobicity of solutes increased, the partition of solutes were dictated by hydrophobic interaction between solute and polymer matrix. Diffusion coefficients obtained in these experiments decrease as the water content of polymer membrane decreases. This decrease is blunt as the excess heat capacities, ${\phi}C^0_p$ (excess) in aqueous solution at infinite dilution of solute increases. To investigate the relationship between water content and diffusion coefficient, the results of the diffusion experiments were examined in light of a free-volume model of diffusive transport. The remarkable increase of urea mobility in the polymer network containing relatively larger bulk water can be considered as water structure breaking effect.

• 컴퓨터교육학회논문지
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• 제14권3호
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• pp.63-72
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• 2011

사이버 공간에서 학업을 병행하는 직장인 학생에게 강의만족은 매우 역동적이고 다차원적인 과정으로 개개인의 학업 니즈와 능력을 반영된 결과이기도 하다. 본 연구는 사이버 경영대학원에 재학 중인 직장인 학생을 대상으로 교수 학생 간 상호작용, 학생 상호간 상호작용, 몰입, 콘텐츠의 질과 구조화, 실시간 Q&A와 사이버 강의를 보완하는 수단으로서의 오프라인 보충강의 등이 만족도에 미칠 직 간접적 영향 정도를 분석하는 데 목적이 있다. 인과관계 검증에 집중하기 보다는 수강생 입장에서 흥미롭다고 인지된 과목과 어렵다고 판단된 과목을 중심으로 인과관계의 강약 정도를 그룹 별로 비교하였다. 분석결과, 어렵다고 인지된 과목을 중심으로 답한 그룹의 경우 교수 학생 간 상호작용에서 만족도, 콘텐츠품질에서 몰입, Q&A에서 교수 학생 간 상호작용 그리고 Q&A에서 학생 간 상호작용으로 이어지는 경로계수값이 흥미롭다고 인지된 과목을 택한 그룹의 경우보다 더 높은 것으로 나타났다. 반대로 학생 간 상호작용에서 만족도와 콘텐츠 구조에서 몰입으로 이어지는 경로계수값은 흥미롭다고 인지된 과목을 택한 그룹이 더 높은 것으로 나타났다. 이를 토대로 이러닝 설계상의 시사점도 간략히 제시하였다.

• 대한기계학회논문집B
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• 제37권2호
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• pp.111-117
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• 2013

탄성튜브가 연결된 펌핑 챔버를 이용한 무밸브 펌프를 가상경계방법을 이용하여 수치적으로 연구하였다. 탄성 튜브와 펌핑 챔버 사이의 상호작용으로 인하여 무밸브 펌프 내의 유동이 생성되었으며, 탄성튜브의 스트레칭 계수, 벤딩 계수, 종횡비가 무밸브 펌프의 전체 유량에 미치는 영향을 살펴보았다. 펌프의 메커니즘을 이해하고자, 시간에 따른 탄성 튜브의 움직임과 그에 따른 유동 속도의 변화를 자세히 살펴보았으며, 탄성 튜브의 직경 크기와 펌프의 평균 유량 사이의 관계를 분석하였다.

• 한국전산유체공학회지
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• 제20권4호
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• pp.93-101
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• 2015

This paper provides numerical results of the simulation for the flow around the hull and the propeller of KCS model ship advancing in shallow water conditions. A finite volume method is used to solve the unsteady Reynolds averaged Navier-Stokes(RANS) equations, where the wave-making problem is solved by using a volume-of-fluid(VOF) method. The wave formed near the hull surface in shallow water conditions shows a deep trough dominant pattern that causes the loss of buoyancy followed by hull squat. The flow past the hull increases as the depth of water decreases. However, the axial flow velocity around the stern shows a reduction in magnitude by the effect of shallow water accompanied by the hull-propeller interaction. As a results, the thrust and torque coefficient increase about 8.3% and 6.2%, respectively for a depth of h/T=3.0 corresponding to a depth Froude number of $F_h=0.693$. The resistance coefficient increases about 11.6% at this Froude number condition.