• 제목/요약/키워드: Infrared Reflection

검색결과 187건 처리시간 0.024초

Infrared spectroscopy of the effect of metal electrode on adsorbate under electric field: Electrochemical model study of CO on Pt(111) with ice film capacitor method in ultrahigh vacuum

  • Kang, Hani;Shin, Sunghwan;Park, Youngwook;Kang, Heon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.143.2-143.2
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    • 2016
  • The influence of electric field on CO adsorbed on Pt(111) was investigated with reflection-absorption infrared spectroscopy (RAIRS) in ultrahigh vacuum system. The ice film capacitor method was used to apply electric field to the amorphous ice film with CO on Pt(111). Two systems were compared by measuring the change of the CO stretching vibrational mode under applied electric field; one is CO on Pt(111), and the other is CO buried inside an ice film on Pt(111). By comparing them, we were able to calculate the additional effect of adsorption of CO on Pt(111) on peak shift. The CO adsorbed on Pt(111) has shown larger peak shift than CO adsorbed with H2O when we applied stronger electric field. Additionally, the differences were observable when the applied electric field exceeds $1{\times}10V/m^8$.

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졸-겔법으로 제조된 SiO2막의 적외선 복사특성에 관한 연구 (Infrared Radiation Properties for SiO2 Films Made by Sol-Gel Process)

  • 강병철;김영근;김기호
    • 한국재료학회지
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    • 제13권10호
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    • pp.697-702
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    • 2003
  • FT-IR and thermograph were used to investigate the infrared radiation characteristics of $SiO_2$film made by the sol-gel method. FT-IR spectrum of the $SiO_2$film showed high infrared absorption by Si-O-Si vibration at 1220, 1080, 800 and cm$460^{-1}$ The infrared absorption and radiation wavelength ranges of the $SiO_2$film measured by the integration method coincided with the reflection method, and the infrared emissivity was 0.65, equally. Depending on the bonding of elements, the infrared emissivity was high in the wavelength range where the infrared absorption rate was high, that follows the Kirchhoff's law. The emissivity showed the highest value in the wavelength range between $8∼10\mu\textrm{m}$. $SiO_2$film was considered as an efficient materials for infrared radiator at temperature below 10$0^{\circ}C$. The heat radiation temperature was $117^{\circ}C$ for the aluminum plate, but $146^{\circ}C$ for the $SiO_2$film after 7 minutes heat absorption, consiquently, $29^{\circ}C$ higher than the former.

INLINE NEAR INFRARED (NIR) SPECTROSCOPY FOR PROCESS CONTROL IN POLYMER EXTRUSION

  • Rohe, Thomas;Koelle, Sabine;Becker, Wolfgang;Eisenreich, Norbert;Eyerer, Peter
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1082-1082
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    • 2001
  • Extrusion is one of the most important processes in polymer industry. The characterization of the polymer melt during processing will improve this process noticeably, One possibility of characterizing the actual processed polymer melt is the inline near infrared (NIR) spectroscopy, With this method several polymer properties can be observed during processing, e.g. composition, moisture ormechanical properties of the melt. For this purpose probes for transmission and reflection measurements have been developed, withstanding the high temperatures and pressures appearing during extrusion process (tested up to 300$^{\circ}C$ and 10 ㎫). For the transmission system an optical bypass was developed to eliminate disturbing spectral influences and hence increase the long term stability, which is the prerequisite for an industrial application. Measurements in transmission and reflection produced comparable results (or blending processes, where the prediction error was less than 1%. An optimum RMSEP of only 0.24% was found for preprocessed polymer blends measured in transmission on a laboratory extruder. A transflection measurement allowed for the first time the recording of relevant NIR-spectra in the screw area of an extruder. The application to a (PE+PP) blending process delivered promising results. This new measurement mode allows the observation of the ongoing processes within the screw area, which is of maximum Interest for reactive extrusion processes. Due to economic reasons the calibration transfer between different extrusion systems is also of high importance. Investigations on simulated and real-world spectra showed that a calibration transfer is possible. A new method alternatively to the well-known direct standardization procedures was developed, which is based on an automatic data pretreatment. This procedure delivers comparable results for the calibration transfer. Overall this paper presents concepts, components and algorithms for the inline near infrared (NIR) spectroscopy for polymer extrusion, which allows the use of it in a real industrial extrusion process.

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Cloud-Type Classification by Two-Layered Fuzzy Logic

  • Kim, Kwang Baek
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • 제13권1호
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    • pp.67-72
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    • 2013
  • Cloud detection and analysis from satellite images has been a topic of research in many atmospheric and environmental studies; however, it still is a challenging task for many reasons. In this paper, we propose a new method for cloud-type classification using fuzzy logic. Knowing that visible-light images of clouds contain thickness related information, while infrared images haves height-related information, we propose a two-layered fuzzy logic based on the input source to provide us with a relatively clear-cut threshold in classification. Traditional noise-removal methods that use reflection/release characteristics of infrared images often produce false positive cloud areas, such as fog thereby it negatively affecting the classification accuracy. In this study, we used the color information from source images to extract the region of interest while avoiding false positives. The structure of fuzzy inference was also changed, because we utilized three types of source images: visible-light, infrared, and near-infrared images. When a cloud appears in both the visible-light image and the infrared image, the fuzzy membership function has a different form. Therefore we designed two sets of fuzzy inference rules and related classification rules. In our experiment, the proposed method was verified to be efficient and more accurate than the previous fuzzy logic attempt that used infrared image features.

고반사 도료를 사용한 차열성 아스팔트 도로포장의 온도저감특성 (Properties of Temperature Reduction of Cooling Asphalt Pavements Using High-Reflectivity Paints)

  • 홍창우
    • 대한토목학회논문집
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    • 제33권1호
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    • pp.317-327
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    • 2013
  • 도심지의 대기오염 및 인공열 등으로 인해 도시열섬현상이 발생되고 있으며, 특히 아스팔트 포장의 경우 낮에는 일사열을 흡수하고 밤에 방출하기 때문에 도심부의 환경을 개선하기 위해서는 도심 도로포장의 온도를 저하시키는 차열성 포장에 대한 연구의 필요성이 제기되고 있다. 도로포장에 차열성 도료를 적용하기 위해서는 시인성을 높이기 위해 흑색명도를 저하시켜야 하며, 적외선 반사율은 증가시키고, 가시광선 반사율은 최소화 하는 특성이 요구된다. 본 연구에서는 1액형 아크릴 에멀젼을 주 바인더로 사용하고 안료의 종류(카본블랙, 합성무기안료) 및 중공세라믹 혼입률(0%, 15%, 30%)변화, 흑색명도의 변화를 주요 실험인자로 선정하였다. 차열성 도로포장의 온도저감 성능은 분광반사율과 일사반사율, 램프 조사 방법을 통해 분석하였다. 그리고 마모저항성, 자외선 촉진내후성, 미끄럼 저항성에대한 현장적용성을 평가하였다. 그리고 고반사 도료 시험포장에 대해서 열화상 촬영을 통해 온도저감 효과를 분석하였다. 실험결과 합성무기안료와 중공세라믹 30%를 혼입한 경우에 흑색 명도 $L^*$= 42.89에서 분광반사율이 근적외선 영역에서 43%, 가시광선 영역에서 17%를 보였으며, 일사반사율은 27.5%로 나타났다. 그리고 자외선 촉진내후성 시험에 의한 총색차 ${\Delta}E$가 0.27로 색변화가 거의 발생되지 않았으며, 규사 2호, 4호를 상도, 하도에 $0.12kg/m^2$이상 산포할 경우 BPN은 53이상을 보였다. 또한 테이버 마모시험에 의한 마모감량은 500회전시 최대 86.4mg이하로 나타났다. 아스팔트 포장에 고반사 도료를 시공한 시험구간의 열저감 성능을 열화상 촬영에 의해 평가한 결과 CI-30-40 차열성포장($L^*$=38.76)은 $12.7^{\circ}C$, CI-30-60 차열성포장($L^*$=57.12)은 $14.2^{\circ}C$의 온도저감효과를 보였다.

반사 적외선 사진을 위한 평판 스캐너의 개발 (Development of a Flatbed Scanner for Reflection Infrared Photography)

  • 최영호;황민구;하동환
    • 한국콘텐츠학회논문지
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    • 제11권4호
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    • pp.57-66
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    • 2011
  • 현재 디지털 카메라가 적외선 카메라로 예술과 법과학 분야에서 활용 되고 있다. 하지만 디지털 카메라는 촬영이나 광원과 같은 기본적인 이론에 대한 이해가 필요하다는 단점이 있기 때문에 본 논문에서는 적외선 평판 스캐너를 개발하였다. 적외선 카메라의 개발 과정은 다음과 같다. 첫 번째, 가시광선용 형광램프를 적외선 LED로 교체하였다. 두 번째, 완전한 적외선 평판 스캐너를 위하여 유리판 위해 810nm이상 투과가 가능한 롱 패스 필터를 장착하였다. 적외선 디지털 카메라는 촬영을 할 경우 매번 적외선 광원을 조사(Irradiation)해 주어야 하는 번거로움과 가시광선 과 다른 적외선의 특성으로 인하여 생기는 초점문제 그리고 직접 컴퓨터로 옮겨야 하는 작업들이 여전히 존재한다. 이러한 문제를 개선하기 위해 본 논문에서 개발한 적외선 평판 스캐너는 적외선 광원을 개별적으로 조사할 필요가 없으며, 최소 2mm 이상 되는 피사계 심도로 인하여 초점 문제가 없다. 또한 적외선 평판 스캐너는 일반 평판 스캐너와 마찬가지로 12800dpi의 고해상도를 만들어 낼 수 있다는 것 역시 장점으로 작용한다. 본 논문에서 개발한 적외선 평판 스캐너가 많은 분야에서 활용되기를 기대한다.

비냉각형 적외선 센서를 이용한 열상시스템과 냉각형 적외선 센서를 이용한 열상시스템의 화재 진압 시 성능 비교 (Performance Comparison of Thermal Imagers with Uncooled and Cooled Detectors For Fire Fighting Application)

  • 김병혁;정한;김영호
    • 제어로봇시스템학회논문지
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    • 제13권2호
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    • pp.128-132
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    • 2007
  • Thermal Imaging systems are reported to be crucial for fire fighting and beginning to be used by fire fighters. The performance of thermal imaging system is determined by both the radiation of infrared from the target and the attenuation of infrared signal in the optical path by the absorption, scattering, diffraction and reflection. In the scene of fire, water drops with various sizes such as vaporized water, wafer mist from sprinkler, and wafer to suppress the fire reside with various gas generated by burning. To measure the transmission of infrared radiation in the scene of fire, fire simulating system and thermal imagers with cooled detector which detects $3{\sim}5{\mu}m$ infrared and uncooled detector fabricated by the MEMS technology which detects $8{\sim}12{\mu}m$ infrared. are made. With thermal imagers and Ire simulating system, the change of thermal image with respect to the change of visibility controlled with the burned fas was measured. It was found that the transmission of infrared was not reduced by the burned gas, which could be explained by the long wavelength of infrared ray compared with visible ray. However, the transmission of infrared ray was largely reduced by the combination of burned gas and water mist supplied by sprinkler. This is contrary to the results of calculated transmission through the pure water mist and shows that the transmission of infrared ray is mostly affected by the compounds of water mist and burned gas. In this case, it was found that the uncooled detector which detects $8{\sim}12{\mu}m$ infrared ray is better than cooled detector which detects $3{\sim}5{\mu}m$ infrared ray for fire fighting.

원적외선 가열에 의한 고추의 건조특성 (Drying Characteristics of Red Peppers by Infrared Heating)

  • 배내경;이종붕;상희선
    • 한국산업융합학회 논문집
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    • 제6권1호
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    • pp.65-71
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    • 2003
  • Infrared heating has been traditionally used in industrial applications for processes such as dehydration of food industrial. This heating method involves the application of radiation in the wavelength range of 5~50 micrometers. In this work, simultaneous heat balance equations were developed to simulate the infrared radiation heating of red peppers. The equations assume that moisture diffuses to the outer boundaries of the material in liquid form and evaporation occurs at the surface of the red peppers. Energy for moisture evaporation is supplied by the infrared radiant energy. The equations were validated with experimental data on surface temperature and average moisture content of red peppers. Average deviations of predicted surface red peppers temperature and average red peppers moisture from experimental data were 323~353K and 50~80%, respectively. The spectral extinction coefficients in the wavelength range $1.5<{\lambda}<27$ micrometer at 293K for Red Peppers were determined from results of reflection measurements and the four flux radiative heat transfer calculation. The radiation extinction coefficients were obtained from effective drying factor the temperature 373K.

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근적외분광분석법을 사용한 암브록솔 정제의 비파괴적 정량분석 (Nondestructive Quantification of Intact Ambroxol Tablet using Near-infrared Spectroscopy)

  • 임현량;우영아;김도형;김효진;강신정;최현철;최한곤
    • 약학회지
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    • 제48권1호
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    • pp.60-64
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    • 2004
  • Near-infrared (NIR) spectroscopy was used to determine rapidly and nondestructively the content of ambroxol in intact ambroxol tablets containing 30 mg (12.5% m/m nominal concentration) by collecting NIR spectra in range 1100-1750 nm. The laboratory-made samples had 10.3∼15.9% m/m nominal ambroxol concentration. The measurements were made by reflection using a fiber-optic probe and calibration was carried out by partial least square regression (PLSR) with autoscaling. Model validation was performed by randomly splitting the data set into calibration and validation data set (7 samples as a calibration data set and 5 samples as a validation data set). The developed NIR method gave results comparable to the known values of tablets in a laboratorial manufacturing Process, standard error of calibration (SEC) and standard error of prediction (SEP) being 0.49% and 0.49% m/m respectively. The method showed good accuracy and repeatability NIR spectroscopic determination in intact tablets allowed the potential use of real time monitoring for a running production process.