• 전기화학회지
• /
• 제12권4호
• /
• pp.329-334
• /
• 2009

본 연구는 연료전지 운전시 전극 촉매 및 전해질막 내에서 발생하는 연료 및 산화제의 산화/환원 반응 메커니즘, 이동현상, 구성품 열화현상 등을 핵자기 공명 (NMR, Nuclear Magnetic Resonance)을 이용하여 연료전지의 분해나 시료 채취 없이 제자리 (in situ) 분석할 수 있는 진단장치용 연료전지 개발에 관한 것이다. NMR에 사용되는 연료전지는 특수하게 제작된 TCD (Toroid Cavity Detector) 탐침 내부에서 작동하여야 하며, TCD 탐침이 가지는 기하학적 제한 요소들로 인해 일반적인 평판형 연료전지와 달리 원통형으로 제작된다. 이로 인해 반응물의 공급이나 생성물의 제거가 어려우며 누수 현상 및 불균일한 압력 분배가 발생하여 성능이 낮다. 따라서, in situ NMR 분석용 연료전지가 가지는 구조상의 특징인 원통형에 적합한 유로를 설계하고 제작하여 물질 전달 특성을 개선해야 할 필요성이 있다. 본 연구에서는 NMR 장비 내의 자기장에 영향을 미치지 않는 비자성 물질을 이용해 원 통형 공기극 유로를 개발하여, 산소의 공급 및 반응물의 제거를 원활하게 하였다. 또한, 체결 압력을막-전극 접합체에 균일하게 분배하여 누수 및 누액을 차단하였다. 이를 통해, 상온에서 약 $36mW/cm^2$의 우수한 성능을 나타내는 in situ NMR 진단용 직접 메탄올연료전지 시스템을 개발하였다.

• 한국건축시공학회지
• /
• 제11권5호
• /
• pp.501-514
• /
• 2011

Recently, there have been many cases in which the difficulty of repair and replacement of principal elements in the bearing wall structure for apartment buildings, which is a major part of apartment buildings in Korea, has led to the reconstruction of buildings rather than their remodeling. To address this problem, the Korea government now allows a floor area ratio of up to 20 %, and has relaxed the building height limits to encourage the use of a rahmen structure instead of a bearing wall structure. However, since reinforced concrete rahmen structures have many problems, including higher floor height and greater construction cost, a great deal of research into rahmen composite precast concrete structures have been conducted. Green Frame, one of the developed prototypes, is expected to provide economic benefits through in-situ production for precast concrete column and beam. For in-situ production of composite precast concrete members, a detailed plan for production, curing, and installation is needed. However, it needs to be confirmed that the space is sufficient to produce the precast concrete members on-site before planning those activities. Therefore, this study proposes in-situ production analysis of composite precast concrete members of Green Frame with the evaluation of structural safety and available area on the parking structure. The result of this study shows that the in-situ production of precast concrete members is possible through a case study.

• Geomechanics and Engineering
• /
• 제16권4호
• /
• pp.363-373
• /
• 2018

The evaluation of Thermo-Hydro-Mechanical (THM) coupling behavior is important for the development of underground space for various purposes. For a high-level radioactive waste repository excavated in a deep underground rock mass, the accurate prediction of the complex THM behavior is essential for the long-term safety and stability assessment. In order to develop reliable THM analysis techniques effectively, an international cooperation project, Development of Coupled models and their Validation against Experiments (DECOVALEX), was carried out. In DECOVALEX-2015 Task B2, the in situ THM experiment that was conducted at Horonobe Underground Research Laboratory(URL) by Japan Atomic Energy Agency (JAEA), was modeled by the research teams from the participating countries. In this study, a THM coupling technique that combined TOUGH2 and FLAC3D was developed and applied to the THM analysis for the in situ experiment, in which rock, buffer, backfill, sand, and heater were installed. With the assistance of an artificial neural network, the boundary conditions for the experiment could be adequately implemented in the modeling. The thermal, hydraulic, and mechanical results from the modeling were compared with the measurements from the in situ THM experiment. The predicted buffer temperature from the THM modelling was about $10^{\circ}C$ higher than measurement near by the overpack. At the other locations far from the overpack, modelling predicted slightly lower temperature than measurement. Even though the magnitude of pressure from the modeling was different from the measurements, the general trends of the variation with time were found to be similar.

• 한국지반공학회논문집
• /
• 제34권2호
• /
• pp.5-17
• /
• 2018

본 연구에서는 연약지반에서의 재하/제하에 대한 안정해석과 응력-변형 해석시 전단 파라미터(UU; Unconsolidated Undrained, CU; Consolidated Undrained(전응력), ${\bar{CU}}$ ; Consolidated Undrained(유효응력))에 따른 초기 지중응력, 강도, 응력-변형 특성을 평가하였다. 시공단계를 고려한 유한요소 해석시 입력하는 전단 파라미터에 따라 초기 지중응력과 이후 해석 결과가 달라질 수 있음을 확인하였다. 특히, Mohr-Coulomb 모델의 입력 파라미터인 내부마찰각(Phi)을 0으로 입력하여 초기 지중응력과 이후 응력-변형 거동을 해석할 경우 잘못된 결과를 도출 할 수 있다는 것을 확인하였다. 전응력 파라미터, CU를 초기 및 전단시 일괄 적용한 해석과 유효응력 파라미터, CU에서 전응력 파라미터, CU로 변경한 해석 결과가 큰 차이를 보이지 않았다. 따라서, 연약지반에 대한 수치해석시 CU 파라미터를 적용하여도 초기 지중응력과 이후 응력-변형 거동에 큰 차이 없이 예측할 수 있음을 알 수 있었다. 또한, 실무에서 적용하기 편한 방법으로 실제 흙의 거동과 동일한 강도를 갖는 Mohr-Coulomb 모델의 전단 파라미터를 산정하는 방법을 제안하였다.

• Ocean and Polar Research
• /
• 제35권4호
• /
• pp.395-405
• /
• 2013

The aim of this study is to suggest an optimal survey method for coastal habitat monitoring around Weno Island in Chuuk Atoll, Federated States of Micronesia (FSM). This study was carried out to compare and analyze differences between in situ survey (PHOTS) and high spatial satellite imagery (Worldview-2) with regard to the coastal habitat distribution patterns of Weno Island. The in situ field data showed the following coverage of habitat types: sand 42.4%, seagrass 26.1%, algae 14.9%, rubble 8.9%, hard coral 3.5%, soft coral 2.6%, dead coral 1.5%, others 0.1%. The satellite imagery showed the following coverage of habitat types: sand 26.5%, seagrass 23.3%, sand + seagrass 12.3%, coral 18.1%, rubble 19.0%, rock 0.8% (Accuracy 65.2%). According to the visual interpretation of the habitat map by in situ survey, seagrass, sand, coral and rubble distribution were misaligned compared with the satellite imagery. While, the satellite imagery appear to be a plausible results to identify habitat types, it could not classify habitat types under one pixel in images, which in turn overestimated coral and rubble coverage, underestimated algae and sand. The differences appear to arise primarily because of habitat classification scheme, sampling scale and remote sensing reflectance. The implication of these results is that satellite imagery analysis needs to incorporate in situ survey data to accurately identify habitat. We suggest that satellite imagery must correspond with in situ survey in habitat classification and sampling scale. Subsequently habitat sub-segmentation based on the in situ survey data should be applied to satellite imagery.

• Carbon letters
• /
• 제21권
• /
• pp.16-22
• /
• 2017

Cobalt was electrodeposited onto chemical vapor deposition (CVD) graphene/Si/$SiO_2$ substrates, during different time intervals, using an electrolyte solution containing a low concentration of cobalt sulfate. The intention was to investigate the details of the deposition process (and the dissolution process) and the resulting magnetic properties of the Co deposits on graphene. During and after electrodeposition, in-situ magnetic measurements were performed using an (AGFM). These were followed by ex situ morphological analysis of the samples with ${\Delta}t_{DEP}$ 30 and 100 s by atomic force microscopy in the non-contact mode on pristine CVD graphene/$SiO_2$/Si. We demonstrate that it is possible to electrodeposit Co onto graphene, and that in-situ magnetic measurements can also help in understanding details of the deposition process itself. The results show that the Co deposits are ferromagnetic with decreasing coercivity ($H_C$) and demonstrate increasing magnetization on saturation ($M_{SAT}$) and electric signal proportional to remanence ($M_r$), as a function of the amount of the electrodeposited Co. It was also found that, after the end of the dissolution process, a certain amount of cobalt remains on the graphene in oxide form (this was confirmed by X-ray photoelectron spectroscopy), as suggested by the magnetic measurements. This oxide tends to exhibit a limited asymptotic amount when cycling through the deposition/dissolution process for increasing deposition times, possibly indicating that the oxidation process is similar to the graphene surface chemistry.

• 한국의류산업학회지
• /
• 제22권3호
• /
• pp.386-398
• /
• 2020

This study compared dip-coating and in situ polymerization methods for the development of nanofiber-based E-textile using polypyrrole. Nanofiber webs were fabricated by electrospinning an aqueous poly (vinyl alcohol) (PVA) solution. Subsequently, the PVA nanofiber web underwent thermal treatment to improve water resistance. Dip-coating and in situ polymerization methods were used to deposit polypyrrole on the surfaces of the nanofiber web. An FE-SEM analysis was also conducted to examine specimen surface characteristics along with EDS and FT-IR that analyzed the chemical bonding between polypyrrole and specimens. The line resistance and sheet resistance of the treated specimens were measured. Finally, an electrocardiogram (ECG) was measured with textile sensors made of the polypyrrole-deposited PVA nanofiber webs. The polypyrrole-deposited PVA nanofiber webs fabricated by dip-coating dissolved in the dip-coating solution and indicated damage to the nanofibers. However, in the case of in situ polymerization, polypyrrole nanoparticles were deposited on the surface and inter-web structure of the PVA nanofiber web. The resistance measurements indicated that polypyrrole-deposited PVA nanofiber webs fabricated by in situ polymerization with an average sheet resistance of 5.3 k(Ω/□). Polypyrrole-deposited PVA nanofiber webs fabricated by dip-coating showed an average sheet resistance of 57.3 k(Ω/□). Polypyrrole-deposited PVA nanofibers fabricated by in situ polymerization showed a lower line and sheet resistance; in addition, they detected the electrical activity of the heart during ECG measurements. The electrodes made from polypyrrole-deposited PVA nanofiber webs by in situ polymerization showed the best performance for sensing ECG signals among the evaluated specimens.

• Nuclear Engineering and Technology
• /
• 제51권3호
• /
• pp.867-876
• /
• 2019

Second harmonic generation using nonlinear ultrasonic waves have been shown to be an early indicator of possible fatigue damage in nuclear power plant components. This technique relies on measuring amplitudes, making it highly susceptible to variations in transducer coupling and instrumentation. This paper proposes an experimental procedure for in-situ surface wave nonlinear ultrasound measurements on specimen with permanently mounted transducers under high cycle fatigue loading without interrupting the experiment. It allows continuous monitoring and minimizes variation due to transducer coupling. Moreover, relations describing the effects of the measurement system nonlinearity including the effects of the material transfer function on the measured nonlinearity parameter are derived. An in-situ high cycle fatigue test was conducted using two 304 stainless steel specimens with two different excitation frequencies. A comprehensive analysis of the nonlinear sources, which result in variations in the measured nonlinearity parameters, was performed and the effects of the system nonlinearities are explained and identified. In both specimens, monotonic trend was observed in nonlinear parameter when the value of fundamental amplitude was not changing.

• Nuclear Engineering and Technology
• /
• 제46권6호
• /
• pp.737-752
• /
• 2014

As condition-based maintenance (CBM) has risen as a new trend, there has been an active movement to apply information technology for effective implementation of CBM in power plants. This motivation is widespread in operations and maintenance, including monitoring, diagnosis, prognosis, and decision-making on asset management. Thermal efficiency analysis in nuclear power plants (NPPs) is a longstanding concern being updated with new methodologies in an advanced IT environment. It is also a prominent way to differentiate competitiveness in terms of operations and maintenance costs. Although thermal performance tests implemented using industrial codes and standards can provide officially trustworthy results, they are essentially resource-consuming and maybe even a hind-sighted technique rather than a foresighted one, considering their periodicity. Therefore, if more accurate performance monitoring can be achieved using advanced data analysis techniques, we can expect more optimized operations and maintenance. This paper proposes a framework and describes associated methodologies for in-situ thermal performance analysis, which differs from conventional performance monitoring. The methodologies are effective for monitoring, diagnosis, and prognosis in pursuit of CBM. Our enabling techniques cover the intelligent removal of random and systematic errors, deviation detection between a best condition and a currently measured condition, degradation diagnosis using a structured knowledge base, and prognosis for decision-making about maintenance tasks. We also discuss how our new methods can be incorporated with existing performance tests. We provide guidance and directions for developers and end-users interested in in-situ thermal performance management, particularly in NPPs with large steam turbines.

• Computers and Concrete
• /
• 제23권3호
• /
• pp.203-215
• /
• 2019

Precast reinforced concrete structure (PRCS) consists of prefabricated members assembled at worksites and has more connections limitations in comparison with the equivalent in-situ reinforced concrete structure (IRCS). As a result of these limitations, PRCSs have less ductility in comparison with IRCSs. Recent studies indicate that the most noticeable failure in PRCSs have occurred in their connection zone. The objective of this study is introducing a type of precast beam-to-column connection (PBC) which in spite of being simple is of the same efficiency and performance as in-situ beam-to-column connection (IBC). To achieve this, the performance of proposed new PBC at exterior joint of a four story PRCS was analyzed by pseudo dynamic analysis and compared with that of IBC in equivalent IRCS. Results indicated that the proposed connection has even better performance in terms of strength, energy dissipation and stiffness, than that of IBC.