• Title/Summary/Keyword: In situ analysis

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Tubular Type Direct Methanol Fuel Cell for in situ NMR Diagnosis (In Situ NMR 진단용 원통형 직접 메탄올 연료전지)

  • Joh, Han-Ik;Um, Myung-Sup;Han, Kee-Sung;Han, Oc-Hee;Ha, Heung-Yong;Kim, Soo-Kil
    • Journal of the Korean Electrochemical Society
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    • v.12 no.4
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    • pp.329-334
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    • 2009
  • This study is to develop a fuel cell system applicable to an in situ NMR (Nuclear magnetic resonance) diagnosis. The in situ NMR can be used in real time monitoring of various reactions occurring in the fuel cell, such as oxidation of fuel, reduction of oxygen, transport phenomena, and component degradation. The fuel cell for this purpose is, however, to be operated in a specifically designed tubular shape toroid cavity detector (TCD), which constrains the fuel cell to have a tubular shape. This may cause difficulties in effective mass transport of reactants/products and uniform distribution of assembly pressure. Therefore, a new flow field designed in a particular way is necessary to enhance the mass transport in the tubular fuel cell. In this study, a tubular-shaped close-type flow field made of non-magnetic material is developed. With this flow field, oxygen is effectively delivered to the cathode surface and the produced water is readily removed from the membrane-electrode assembly to prevent flooding. The resulting DMFC (direct methanol fuel cell) outperforms the open-type flow field and exhibits $36\;mW/cm^2$ even at room temperature.

In-situ Production Analysis of Composite Precast Concrete Members of Green Frame

  • Lim, Chae-Yeon;Joo, Jin-Kyu;Lee, Goon-Jae;Kim, Sun-Kuk
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.5
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    • pp.501-514
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    • 2011
  • Recently, there have been many cases in which the difficulty of repair and replacement of principal elements in the bearing wall structure for apartment buildings, which is a major part of apartment buildings in Korea, has led to the reconstruction of buildings rather than their remodeling. To address this problem, the Korea government now allows a floor area ratio of up to 20 %, and has relaxed the building height limits to encourage the use of a rahmen structure instead of a bearing wall structure. However, since reinforced concrete rahmen structures have many problems, including higher floor height and greater construction cost, a great deal of research into rahmen composite precast concrete structures have been conducted. Green Frame, one of the developed prototypes, is expected to provide economic benefits through in-situ production for precast concrete column and beam. For in-situ production of composite precast concrete members, a detailed plan for production, curing, and installation is needed. However, it needs to be confirmed that the space is sufficient to produce the precast concrete members on-site before planning those activities. Therefore, this study proposes in-situ production analysis of composite precast concrete members of Green Frame with the evaluation of structural safety and available area on the parking structure. The result of this study shows that the in-situ production of precast concrete members is possible through a case study.

THM analysis for an in situ experiment using FLAC3D-TOUGH2 and an artificial neural network

  • Kwon, Sangki;Lee, Changsoo
    • Geomechanics and Engineering
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    • v.16 no.4
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    • pp.363-373
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    • 2018
  • The evaluation of Thermo-Hydro-Mechanical (THM) coupling behavior is important for the development of underground space for various purposes. For a high-level radioactive waste repository excavated in a deep underground rock mass, the accurate prediction of the complex THM behavior is essential for the long-term safety and stability assessment. In order to develop reliable THM analysis techniques effectively, an international cooperation project, Development of Coupled models and their Validation against Experiments (DECOVALEX), was carried out. In DECOVALEX-2015 Task B2, the in situ THM experiment that was conducted at Horonobe Underground Research Laboratory(URL) by Japan Atomic Energy Agency (JAEA), was modeled by the research teams from the participating countries. In this study, a THM coupling technique that combined TOUGH2 and FLAC3D was developed and applied to the THM analysis for the in situ experiment, in which rock, buffer, backfill, sand, and heater were installed. With the assistance of an artificial neural network, the boundary conditions for the experiment could be adequately implemented in the modeling. The thermal, hydraulic, and mechanical results from the modeling were compared with the measurements from the in situ THM experiment. The predicted buffer temperature from the THM modelling was about $10^{\circ}C$ higher than measurement near by the overpack. At the other locations far from the overpack, modelling predicted slightly lower temperature than measurement. Even though the magnitude of pressure from the modeling was different from the measurements, the general trends of the variation with time were found to be similar.

Embankment and Excavation Behaviour with Shear Parameters of Soft Clayey Soil in FEM (점성토의 유한요소해석에서 전단파라미터에 따른 성토 및 굴착 거동)

  • Kim, Byung Il;Choi, Chanyong;Hong, Kang Han;Han, Sang Jae
    • Journal of the Korean Geotechnical Society
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    • v.34 no.2
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    • pp.5-17
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    • 2018
  • In this study, the in-situ stress, strength and stress-strain characteristics with shear parameters (UU, CU, ${\bar{CU}}$) are analytically evaluated and the stability analyses are carried out under loading/unloading conditions. The in-situ stress and the stress-strain behaviour may become different according to input shear parameters in finite element analyses with construction step, Especially, if the internal friction angle in Mohr-Coulomb model is set to zero, the in-situ stress and the stress-strain behaviour might not be properly predicted. The results from CU parameter of total stress analysis have no significant difference with the results from CU of effective stress analysis. Therefore, in the numerical analysis for soft ground, CU parameters can be applied to predict in-situ stress and stress-strain behaviors. In addition, the calculation method was proposed to determine the shear parameter of Mohr-Coulomb model, which is corresponding to the shear strength equivalent to that of in-situ soil.

Comparison between in situ Survey and Satellite Imagery with Regard to Coastal Habitat Distribution Patterns in Weno, Micronesia (마이크로네시아 웨노섬 연안 서식지 분포의 현장조사와 위성영상 분석법 비교)

  • Kim, Taihun;Choi, Young-Ung;Choi, Jong-Kuk;Kwon, Moon-Sang;Park, Heung-Sik
    • Ocean and Polar Research
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    • v.35 no.4
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    • pp.395-405
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    • 2013
  • The aim of this study is to suggest an optimal survey method for coastal habitat monitoring around Weno Island in Chuuk Atoll, Federated States of Micronesia (FSM). This study was carried out to compare and analyze differences between in situ survey (PHOTS) and high spatial satellite imagery (Worldview-2) with regard to the coastal habitat distribution patterns of Weno Island. The in situ field data showed the following coverage of habitat types: sand 42.4%, seagrass 26.1%, algae 14.9%, rubble 8.9%, hard coral 3.5%, soft coral 2.6%, dead coral 1.5%, others 0.1%. The satellite imagery showed the following coverage of habitat types: sand 26.5%, seagrass 23.3%, sand + seagrass 12.3%, coral 18.1%, rubble 19.0%, rock 0.8% (Accuracy 65.2%). According to the visual interpretation of the habitat map by in situ survey, seagrass, sand, coral and rubble distribution were misaligned compared with the satellite imagery. While, the satellite imagery appear to be a plausible results to identify habitat types, it could not classify habitat types under one pixel in images, which in turn overestimated coral and rubble coverage, underestimated algae and sand. The differences appear to arise primarily because of habitat classification scheme, sampling scale and remote sensing reflectance. The implication of these results is that satellite imagery analysis needs to incorporate in situ survey data to accurately identify habitat. We suggest that satellite imagery must correspond with in situ survey in habitat classification and sampling scale. Subsequently habitat sub-segmentation based on the in situ survey data should be applied to satellite imagery.

In-situ magnetization measurements and ex-situ morphological analysis of electrodeposited cobalt onto chemical vapor deposition graphene/SiO2/Si

  • Franco, Vinicius C. De;Castro, Gustavo M.B.;Corredor, Jeaneth;Mendes, Daniel;Schmidt, Joao E.
    • Carbon letters
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    • v.21
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    • pp.16-22
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    • 2017
  • Cobalt was electrodeposited onto chemical vapor deposition (CVD) graphene/Si/$SiO_2$ substrates, during different time intervals, using an electrolyte solution containing a low concentration of cobalt sulfate. The intention was to investigate the details of the deposition process (and the dissolution process) and the resulting magnetic properties of the Co deposits on graphene. During and after electrodeposition, in-situ magnetic measurements were performed using an (AGFM). These were followed by ex situ morphological analysis of the samples with ${\Delta}t_{DEP}$ 30 and 100 s by atomic force microscopy in the non-contact mode on pristine CVD graphene/$SiO_2$/Si. We demonstrate that it is possible to electrodeposit Co onto graphene, and that in-situ magnetic measurements can also help in understanding details of the deposition process itself. The results show that the Co deposits are ferromagnetic with decreasing coercivity ($H_C$) and demonstrate increasing magnetization on saturation ($M_{SAT}$) and electric signal proportional to remanence ($M_r$), as a function of the amount of the electrodeposited Co. It was also found that, after the end of the dissolution process, a certain amount of cobalt remains on the graphene in oxide form (this was confirmed by X-ray photoelectron spectroscopy), as suggested by the magnetic measurements. This oxide tends to exhibit a limited asymptotic amount when cycling through the deposition/dissolution process for increasing deposition times, possibly indicating that the oxidation process is similar to the graphene surface chemistry.

Fabrication of Polypyrrole Deposited Poly (vinyl alcohol) Nanofiber Webs by Dip-coating and In situ Polymerization and their Application to Textile Electrode Sensors (Polypyrrole을 증착시킨 Poly(vinyl alcohol) 나노섬유 제조 및 전극용 텍스타일 센서로의 활용 가능성 탐색 -딥 코팅과 현장중합 증착 방식을 중심으로-)

  • Yang, Hyukjoo;Kim, Jaehyun;Lee, Seungsin;Cho, Gilsoo
    • Fashion & Textile Research Journal
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    • v.22 no.3
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    • pp.386-398
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    • 2020
  • This study compared dip-coating and in situ polymerization methods for the development of nanofiber-based E-textile using polypyrrole. Nanofiber webs were fabricated by electrospinning an aqueous poly (vinyl alcohol) (PVA) solution. Subsequently, the PVA nanofiber web underwent thermal treatment to improve water resistance. Dip-coating and in situ polymerization methods were used to deposit polypyrrole on the surfaces of the nanofiber web. An FE-SEM analysis was also conducted to examine specimen surface characteristics along with EDS and FT-IR that analyzed the chemical bonding between polypyrrole and specimens. The line resistance and sheet resistance of the treated specimens were measured. Finally, an electrocardiogram (ECG) was measured with textile sensors made of the polypyrrole-deposited PVA nanofiber webs. The polypyrrole-deposited PVA nanofiber webs fabricated by dip-coating dissolved in the dip-coating solution and indicated damage to the nanofibers. However, in the case of in situ polymerization, polypyrrole nanoparticles were deposited on the surface and inter-web structure of the PVA nanofiber web. The resistance measurements indicated that polypyrrole-deposited PVA nanofiber webs fabricated by in situ polymerization with an average sheet resistance of 5.3 k(Ω/□). Polypyrrole-deposited PVA nanofiber webs fabricated by dip-coating showed an average sheet resistance of 57.3 k(Ω/□). Polypyrrole-deposited PVA nanofibers fabricated by in situ polymerization showed a lower line and sheet resistance; in addition, they detected the electrical activity of the heart during ECG measurements. The electrodes made from polypyrrole-deposited PVA nanofiber webs by in situ polymerization showed the best performance for sensing ECG signals among the evaluated specimens.

In-situ fatigue monitoring procedure using nonlinear ultrasonic surface waves considering the nonlinear effects in the measurement system

  • Dib, Gerges;Roy, Surajit;Ramuhalli, Pradeep;Chai, Jangbom
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.867-876
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    • 2019
  • Second harmonic generation using nonlinear ultrasonic waves have been shown to be an early indicator of possible fatigue damage in nuclear power plant components. This technique relies on measuring amplitudes, making it highly susceptible to variations in transducer coupling and instrumentation. This paper proposes an experimental procedure for in-situ surface wave nonlinear ultrasound measurements on specimen with permanently mounted transducers under high cycle fatigue loading without interrupting the experiment. It allows continuous monitoring and minimizes variation due to transducer coupling. Moreover, relations describing the effects of the measurement system nonlinearity including the effects of the material transfer function on the measured nonlinearity parameter are derived. An in-situ high cycle fatigue test was conducted using two 304 stainless steel specimens with two different excitation frequencies. A comprehensive analysis of the nonlinear sources, which result in variations in the measured nonlinearity parameters, was performed and the effects of the system nonlinearities are explained and identified. In both specimens, monotonic trend was observed in nonlinear parameter when the value of fundamental amplitude was not changing.

APPLICATION OF MONITORING, DIAGNOSIS, AND PROGNOSIS IN THERMAL PERFORMANCE ANALYSIS FOR NUCLEAR POWER PLANTS

  • Kim, Hyeonmin;Na, Man Gyun;Heo, Gyunyoung
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.737-752
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    • 2014
  • As condition-based maintenance (CBM) has risen as a new trend, there has been an active movement to apply information technology for effective implementation of CBM in power plants. This motivation is widespread in operations and maintenance, including monitoring, diagnosis, prognosis, and decision-making on asset management. Thermal efficiency analysis in nuclear power plants (NPPs) is a longstanding concern being updated with new methodologies in an advanced IT environment. It is also a prominent way to differentiate competitiveness in terms of operations and maintenance costs. Although thermal performance tests implemented using industrial codes and standards can provide officially trustworthy results, they are essentially resource-consuming and maybe even a hind-sighted technique rather than a foresighted one, considering their periodicity. Therefore, if more accurate performance monitoring can be achieved using advanced data analysis techniques, we can expect more optimized operations and maintenance. This paper proposes a framework and describes associated methodologies for in-situ thermal performance analysis, which differs from conventional performance monitoring. The methodologies are effective for monitoring, diagnosis, and prognosis in pursuit of CBM. Our enabling techniques cover the intelligent removal of random and systematic errors, deviation detection between a best condition and a currently measured condition, degradation diagnosis using a structured knowledge base, and prognosis for decision-making about maintenance tasks. We also discuss how our new methods can be incorporated with existing performance tests. We provide guidance and directions for developers and end-users interested in in-situ thermal performance management, particularly in NPPs with large steam turbines.

Introducing a precast moment resistant beam-to-column concrete connection comparable with in-situ one

  • Esmaeili, Jamshid;Ahooghalandary, Neyram
    • Computers and Concrete
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    • v.23 no.3
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    • pp.203-215
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    • 2019
  • Precast reinforced concrete structure (PRCS) consists of prefabricated members assembled at worksites and has more connections limitations in comparison with the equivalent in-situ reinforced concrete structure (IRCS). As a result of these limitations, PRCSs have less ductility in comparison with IRCSs. Recent studies indicate that the most noticeable failure in PRCSs have occurred in their connection zone. The objective of this study is introducing a type of precast beam-to-column connection (PBC) which in spite of being simple is of the same efficiency and performance as in-situ beam-to-column connection (IBC). To achieve this, the performance of proposed new PBC at exterior joint of a four story PRCS was analyzed by pseudo dynamic analysis and compared with that of IBC in equivalent IRCS. Results indicated that the proposed connection has even better performance in terms of strength, energy dissipation and stiffness, than that of IBC.