• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.11a
• /
• pp.149-152
• /
• 2000

AC impedance measurements on poly-p-phenylenevinylene (PPV) LEDs in the frequency range between 10 Hz and 10$\^$6/ Hz were carried out. The complex-plane impedance spectra indicate that PPV devices can be represented by equivalent circuits that corresponds to the bulk and interfacial regions at high and low frequencies, respectively. As a result of complex impedance analysis through the separation of bulk and interfacial region impedances, increase of forward bias in Al/PPV/ITO devices gave rise to relative decrease of the interfacial region impedance. Above the electric field of 10$\^$6/ V/cm the PPV device showed a space charge limited current (SCLC) conduction. The dependence of the transport mechanism and dielectric properties on the applied bias voltage is discussed.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.14 no.1
• /
• pp.44-51
• /
• 2005

Material degradation is a multibillion-dollar problem which affects all the industries amongst others. The last decades have seen the development of newer and more effective techniques such as Focused-ion beam(FIB), Transmission electron microscopy(TEM), Secondary-ion mass spectroscopy(SIMS), auger electron spectroscopy(AES), X-ray Photoelectron spectroscopy(XPS) , Electrochemical impedance spectroscopy(EIS), Photo- stimulated luminescence spectroscopy(PSLS), etc. to study various forms of material degradation. These techniques are now used routinely to obtain information on the chemical state, depth profiling, composition, stress state, etc. to understand the degradation behavior. This paper describes the use of these techniques specifically applied to materials degradation and failure analysis.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.9
• /
• pp.1523-1530
• /
• 2007

The first reduction peak of the cyclic voltammogram (CV) for sulfur reduction in dimethyl sulfoxide has been studied using time resolved Fourier transform electrochemical impedance spectroscopic (FTEIS) analysis of small potential step chronoamperometric currents. The FTEIS analysis results reveal that the impedance signals obtained during short potential steps can be resolved into electron transfer reactions of two different time constants in a high frequency region. The FTEIS method provides snap shots of impedance profiles during an earlier phase of the reaction, leading to time resolved EIS measurements. Our results obtained by the FTEIS analysis are consistent with a series of electron transfer and chemical equilibrium steps of a complex reaction, making up an ECE (electrochemical-chemical-electrochemical) mechanism postulated from the results of computer simulation.

• Journal of Ocean Engineering and Technology
• /
• v.17 no.6
• /
• pp.77-82
• /
• 2003

The absorption of water into an anti-corrosive organic coating, such as alkyd and urethane resin coating, was investigated, using a quartz crystal microbalance (QCM). Anticorrosive properties of the coatings were also measured, by means of electrochemical impedance spectroscopy (EIS). The overall absorption of water in the coating is determined by the chemical nature of resin, and decreases with increasing thickness. The enhancement of anti-corrosive performance, through increase of coating thickness, was more remarkable in the case of the coating that hadlower equilibrium water absorption. The absorption kinetics curves were Fickian in nature. The EIS analysis confirmed that the resin, having lower equilibrium water absorption, shows higher anti-corrosive performan.

• Smart Structures and Systems
• /
• v.7 no.1
• /
• pp.27-40
• /
• 2011

Geopolymer concrete is finding a growing number of niche applications in the field of civil engineering due to its high compressive strength and strength gain rate, retainage of structural properties in elevated temperature environments, chemical stability in highly acidic conditions and environmental benefits. Combining the above mentioned characteristics with induced electrical conductivity, could enable geopolymer cement to serve as a smart and sustainable cementitious material suitable for health monitoring of civil structures. Carbon fibers were added to fresh geopolymer and OPC (ordinary Portland cement) mixes to enhance their electrical conductivities. AC-impedance spectroscopy analysis was performed on the specimens with fiber fraction ranging from 0.008 to 0.8 with respect to the weight of cementitious binder, to measure their electrical resistivity values and to determine the maximum beneficial fiber content required to attain electrical percolation. Experimental observations suggest that CFR-geopolymer cement exhibits superior performance to CFR-OPC in terms of conducting electrical current.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.11a
• /
• pp.151-152
• /
• 2023

Lightweight aggregates has a dry specific gravity of 2.0 or less, which is lower than natural aggregates. Lightweght aggregate is efficient for weight reduction but has low compressive strength. In this study, EIS(electrochemical Impedance Spectroscopy) was used to confirm the ITZ(Interfacial Transition Zone) between the lightweight aggregate and cement paste according to the coated of blast furnace slag powder. As a result of EIS measurement, the correlation between ITZ characteristics and compressive strength was determined. The phase angle of EIS was different depending on the blast furnace slag powder coated of the lightweight aggregate. The surface-cotead lightweight aggregate was improved and the ITZ was strengthened.

• International Journal of Internet, Broadcasting and Communication
• /
• v.15 no.3
• /
• pp.129-134
• /
• 2023

Although the use of batteries is rapidly increasing worldwide to improve carbon neutrality and energy efficiency, performance degradation due to the increase in the number of uses is inevitable as it is a finite resource that can be applied according to capacity and specifications. Deterioration and failure of batteries are recognized as important problems in various applications using batteries, including electric vehicles. In order to solve these problems, a diagnostic technology capable of accurately predicting battery life and grasping state information is required, but it is difficult in a non-linear form due to internal structure or chemical change. In this paper, the factors that generally cause battery performance change are directly applied to check whether there are external changes and impedance changes in the battery, and to analyze whether they affect battery life. Impedance change trends and result values were confirmed using a universal impedance spectroscopy method and a self-developed internal impedance measurement method. The results did not significantly affect the impedance change trend. It was confirmed that the increase in the number of times of battery use was prominent in the impedance change trend.

• Applied Chemistry for Engineering
• /
• v.20 no.6
• /
• pp.700-704
• /
• 2009

The electrochemical properties of porous carbon electrodes as a function of their internal electrolyte concentration were investigated. Cyclic voltammetry, chronoamperometry, and impedance spectroscopic analysis were conducted for carbon electrodes equilibrated with 0.01, 0.05, 0.1, and 0.5 M KCl solution and covered with a cation-exchange membrane. The specific capacitance of the electrodes increased as the internal electrolyte concentration increased, due to a decrease in charging resistance. Experimental results indicated that the salt removal efficiency of the membrane capacitive deionization process could be enhanced by increasing the internal electrolyte concentration, even for an influent with a low salt concentration.

• Corrosion Science and Technology
• /
• v.5 no.1
• /
• pp.33-38
• /
• 2006

Current coating practice requires the thickness of anti-corrosion organic coatings to be over $250{\mu}m$ for immersion parts of ships and offshore structures and the corrosion resistance of these coatings has been evaluated by destructive and qualitative analysis. Recently, Electrochemical Impedance Spectroscopy(EIS) method has been employed, as an alternative, to evaluate corrosion resistance of organic coatings. This method is characterized as being nondestructive, reproducible, and quantitative in evaluating aging of organic coatings. In this study, EIS method was adopted to quantitatively and effectively select the coating systems having optimized protective performance. Evaluations of several epoxy and epoxy/polyurethane coating systems typically used for ships and offshore structures were carried out in wet($50^{\circ}C$, $90^{\circ}C$) and dry(room temp.) environments to accelerate the degradation of the organic coatings. These results were compared with the conventional scribed(scratched) test results. The plausible prediction model for determining the remaining life-time of coating systems was also proposed based on variations of impedance data, FT-IR and $T_g$ measurements results.

• Journal of the Korean institute of surface engineering
• /
• v.54 no.6
• /
• pp.371-379
• /
• 2021

The use of anti-corrosive oil (AC) is inevitable for production of industrial steels to prevent corrosion. The AC is degreased before application of steels, which crucially effects on final products, such as automobile, electricity etc. However, qualitative/quantitative evaluation of degreasing performance are steal insufficient. In this study, degreasing performance of anti-corrosive oil on steel have been studied through X-ray photon spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). Commercial automotive steels (AMS) are coated with 4 different anti-corrosive oils (namely AC1-AC4). In XPS, intensity of C1s peak remained after degreasing indirectly indicates incomplete degreasing. Thus, higher C1s peak intensity means less effective degreasing by degreasing agent. peak intensity of C1s peak shows opposite tendency of peak intensity of O1s. We found that EIS analysis is not applicable to mild steel (such as AMS1) due to corrosion during measurement. However, alloy steel can be fully analyzed by EIS and XPS depth profile.