• Title/Summary/Keyword: ILs

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Development of PolymerElectrolytes Based on Ionic Liquids forHigh Temperature/Low Humidity PEFC Applications (고온/저가습 고분자전해질 연료전지를 위한 이온성 액체 기반 고분자 전해질막 개발)

  • Sekhon, Satpal Singh;Park, Jin-Soo;Cho, Eun-Kyung;Park, Gu-Gon;Kim, Chang-Soo;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.40-43
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    • 2008
  • High temperature polymer electrolyte membranes incorporating ionic liquids (ILs) in different polymers such as commercial fluorinated polymers, sulfonated polymers and recasted nafion have been developed. ILs based on imidazolium cation and different anions possess high ionic conductivity and good thermal stability and have been used in the present study. The membranes containing IL show conductivity ${\sim}10^{-2}S\;cm^{-1}$ above $100^{\circ}C$ under anhydrous conditions and are thermally stable up to $250-300^{\circ}C$. IL acts as a conducting medium in these electrolytes and plays the same role as played by water in fully hydrated nafion membranes. Due to high conductivity and good thermal stability, these membranes are promising materials for PEFCs at higher temperatures under anhydrous conditions.

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Identification of Structural Damage with Limited Output Measurement (제한된 출력자료를 이용한 구조물의 손상도 추정)

  • 최영민;조효남;황윤국;김정호
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.10a
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    • pp.101-108
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    • 2001
  • In the previous study, an improved QRD (QR Decomposition)-ILS(Iterative Least-Squares) method is proposed to estimate the structural parameters at the element level using response data alone without using any information of excitation measurements for the assessment of local damages and deterioration in complex and large structural systems. But for a complex and large structural system, where response measurement at every dynamic degree of freedom(DDOF) is not possible, the absence of some observation points of responses and its effect on the proposed SI method must be studied In the paper, a QRD-ILS technique that utilizes the known intact stiffness information estimated based on the visual inspection, field measurements and/or NDT tests is proposed to identify local damages of fracture critical members using measured responses only at limited DDOFs. A numerical example is used to illustrate the application of this technique. The results indicate that the proposed SI technique is very simple but efficient, since no input information are required with only limited observations.

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The Soft Material Obtained from an Europium (III)-Containing Ionic Liquid

  • Shao, Huifang;Wang, Yige;Li, Dan
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.973-976
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    • 2011
  • The addition of organic ligand (${\beta}$-diketone or heterocyclic compound) to the europium (III)-containing ionic liquid resulted in bright luminescent soft materials with the molar ratio of europium/ionic liquid (IL)/ligand being 1:3:1 that exhibit bright red light under UV lamp. The luminescent properties such as emission features and lifetime of $^5D_0$ $Eu^{3+}$ excited level are dependent on the organic ligands. The materials were characterized by FT-IR and luminescence spectroscopy. The data shows that at least parts of the ILs (carboxylic acid) are replaced with ${\beta}$-diketone ligand rather than the formation of europium complex with the molar ratio of $Eu^{3+}$:IL: ligand being 1:3:1, while no ILs could be replaced by the heterocyclic ligand such as Bpy and Phen.

Solubility of Carbon Dioxide in Strongly Basic Ionic Liquid

  • Sung, Jun-Kyung;Kim, Sung-Hyun;Cheong, Min-Serk;Baek, Il-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2797-2800
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    • 2010
  • For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low $CO_2$ solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving $CO_2$ absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [$C_n$-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [$C_n$-mim]OPh can be easily synthesized from corresponding [$C_n$-mim]Cl and sodium phenoxide and has been found to be good $CO_2$ absorbents.

Structural Analysis of Conductive Polypyrroles Synthesized in an Ionic Liquid

  • Song, Eun-Ah;Jung, Woo-Gwang;Ihm, Dae-Woo;Kim, Jin-Yeol
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1009-1011
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    • 2009
  • Nano-structured conducting polypyrroles were synthesized in the ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium family with tetrachloroferrate as an anion ($C_n\;mim\;[FeCl_4]\;with\;n\;=\;4,\;8,\;and\;12$). The polypyrrole nanostructures synthesized in ILs were formed as spherical shapes. For ionic liquids with alkyl side chain length $C_4,\;C_4\;mim\;[FeCl_4]$, the size of particles was ranged around 60-nm with a relatively narrow size distribution. As the length of alkyl chain increases, the particle sizes become larger and their distributions become wider. The self-assembled local structures in the solvent ionic liquids are likely to serve as templates of highly organized nano-structured polymers. The length of the alkyl chain in ionic liquids seems to affect these local structures.

Development of Biopolymer-based Materials Using Ionic Liquids and Its Biotechnological Application (이온성 액체를 이용한 바이오폴리머 기반의 소재 개발 및 생명공학 분야로의 응용)

  • Lee, Sang-Hyun;Park, Tae-Joon
    • KSBB Journal
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    • v.25 no.5
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    • pp.409-420
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    • 2010
  • Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

Impact of solar storm on Navaids system (태양폭풍이 항행안전시설에 미치는 영향분석)

  • Jo, Jin-Ho;Park, Jae-Woo;Jeong, Cheol-Oh;Kim, Jae-Hoon;Kim, Gye-Hyeun;Park, Hyeung-Tak
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.20 no.2
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    • pp.13-17
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    • 2012
  • The solar storm generated by solar activity can be impact on earth in various area. If solar storm impact on Navaids system, it will be a serious problem for aviation and human safety. The impact analysis of solar strom on Navaids system are performed in three area, ILS, GPS navigation and radio communication for aviation. Analysis result show that Instrument Landing System(LLZ, GP, MB) and Navaids system(VOR, DME, Radar) are not impacted by the solar storm, but GPS system is impacted by solar storm. Also analysis result show that VHF/UHF radio system are not impacted by solar storm, but HF radio system is impacted by solar storm.

Software ILS Proposed (소프트웨어에 대한 종합군수지원(ILS) 적용 방안)

  • 심행근;김인중;고재영
    • Journal of the Korea Institute of Military Science and Technology
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    • v.2 no.2
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    • pp.173-185
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    • 1999
  • 고품질의 소프트웨어를 개발하는 사업의 중요성이 나날이 증대되고 있는 시점에서 소프트웨어를 종합군수지원 관점에서 해석하려고 하는 연구가 최근에 진행되고 있다. 즉, 소프트웨어 설계자의 입장은 소프트웨어 개발도 중요한 문제이지만 소프트웨어를 얼마나 가용성 있게 유지하는가에 더 많은 관심을 갖게 된다. 하드웨어는 개발 시부터 종합군수지원이라는 기법을 적용하여 체계 배치 시 체계 장비가 최상의 가용도를 가질 수 있도록 하는 노력이 이루어지고 있으며, 그 결과도 현실화되고 있다. 본 논문에서는 하드웨어에서만 적용하고 있는 종합군수지원 개발 기법을 소프트웨어에 적용하여 소프트웨어에 대한 종합군수지원 적용방안을 제시하고, 향후 소프트웨어 개발/배치 시에 경제적이고 가용도가 높은 소프트웨어의 개발/활용이 가능하도록 군수지원 분석을 통한 종합군수지원 활용 방안을 제안한다.

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A Comparison of Reliability Growth Assessment Models Centered on MIL-HDBK-189C (MIL-HDBK-189C의 신뢰성성장 평가 모델의 비교)

  • Kim, Myung Soo;Chung, Jae Woo;Lee, Jong Sin
    • Journal of Applied Reliability
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    • v.13 no.3
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    • pp.217-227
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    • 2013
  • Reliability growth is defined as the positive improvement in a reliability parameter over a period of time due to implementation of corrective actions to system design, operation or maintenance procedures, or the associated manufacturing process. In recent, the importance of reliability growth management has emerged in the military authority and industries. For effective application of reliability growth models, it is necessary to understand their characteristics and differences. This paper presents the concepts of reliability growth management and compares the features of reliability tracking and projection models centered on MIL-HDBK-189C for selecting the appropriate model for an one-shot system under development.

A Method of Failure Detection Rate Calculation for Setting up of Guided Missile Periodic Test and Application Case (유도탄 점검주기 설정을 위한 고장 탐지율 산출 방안 및 적용 사례)

  • Choi, In-Duck
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.42 no.2
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    • pp.28-35
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    • 2019
  • Since guided missiles with the characteristics of the one-shot system remain stored throughout their entire life cycle, it is important to maintain their storage reliability until the launch. As part of maintaining storage reliability, period of preventive test is set up to perform preventive periodic test, in this case failure detection rate has a great effect on setting up period of preventive test to maintain storage reliability. The proposed method utilizes failure rate predicted by the software on the basis of MIL-HDBK-217F and failure mode analyzed through FMEA (Failure Mode and Effect Analysis) using data generated from the actual field. The failure detection rate of using the proposed method is applied to set periodic test of the actual guided missile. The proposed method in this paper has advantages in accuracy and objectivity because it utilizes a large amount of data generated in the actual field.