Bulletin of the Korean Chemical Society

  • 제30권5호
  • /
  • Pages.1009-1011
  • /
  • 2009
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Structural Analysis of Conductive Polypyrroles Synthesized in an Ionic Liquid

  • Song, Eun-Ah (School of Advanced Materials Engineering, Kookmin University) ;
  • Jung, Woo-Gwang (School of Advanced Materials Engineering, Kookmin University) ;
  • Ihm, Dae-Woo (Department of Semiconductor and Display Engineering, Hoseo University) ;
  • Kim, Jin-Yeol (School of Advanced Materials Engineering, Kookmin University)
  • 발행 : 2009.05.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Nano-structured conducting polypyrroles were synthesized in the ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium family with tetrachloroferrate as an anion ($C_n\;mim\;[FeCl_4]\;with\;n\;=\;4,\;8,\;and\;12$). The polypyrrole nanostructures synthesized in ILs were formed as spherical shapes. For ionic liquids with alkyl side chain length $C_4,\;C_4\;mim\;[FeCl_4]$, the size of particles was ranged around 60-nm with a relatively narrow size distribution. As the length of alkyl chain increases, the particle sizes become larger and their distributions become wider. The self-assembled local structures in the solvent ionic liquids are likely to serve as templates of highly organized nano-structured polymers. The length of the alkyl chain in ionic liquids seems to affect these local structures.

키워드

참고문헌

  1. Seddon, K. R.; Stark, A.; Torres, M. Pure Appl. Chem. 2000, 72, 2275 https://doi.org/10.1351/pac200072122275
  2. Sheldon, R. Chem. Commun. 2001, 23, 2399
  3. Fuller, J. R.; Carkin, T. J. Electrochem. Soc. 1997, 144, 3881 https://doi.org/10.1149/1.1838106
  4. Zhao, Y. L.; Zhang, J. M. J.; Jiang, C. F.; Chen, F. Xi. J. Polym. Sic. Part A 2002, 40, 3360 https://doi.org/10.1002/pola.10433
  5. Kubisa, P. Pro. Polym. Sic. 2004, 29, 3 https://doi.org/10.1016/j.progpolymsci.2003.10.002
  6. Hayashi, S.; Hamaguchi, H. Chem. Lett. 2004, 33, 1590 https://doi.org/10.1246/cl.2004.1590
  7. Kim, J. Y.; Kim, J. T.; Song, E. A.; Min, Y. K.; Hamaguchi, H. Macromolecules 2008, 41, 2886 https://doi.org/10.1021/ma071333k
  8. Wasserscheid, P. Ionic liguid in Syntheses; Welton, T., Eds. ; Wiley-VCH: Weinheim, Germany, 2003
  9. Davis, Jr.; Fox, J. H. P. A. Chem. Commun. 2003, 11, 1209
  10. Yao, Z.; Postma, H. W. C.; Balents, L.; Dekker, C. Nature 1999, 402, 273 https://doi.org/10.1038/46241
  11. Normile, D. Science 1999, 286, 2056 https://doi.org/10.1126/science.286.5447.2056b
  12. Kong, J.; Franklin, N. R.; Zhoum, C.; Chapline, M. G.; Peng, S.; Cho, K.; Dai, H. Science 2000, 287, 622 https://doi.org/10.1126/science.287.5453.622
  13. Baughman, R. H.; Cui, C.; Zakhidov, A. A.; Iqbal, Z.; Barisci, J. N.; Spinks, G. M.; Wallace, G. G.; Mazzoldi, A.; De Rossi, D.; Rinzler, A. G.; Jaschinski, O.; Roth, S.; Kertesz, M. Science 1999, 284, 1340 https://doi.org/10.1126/science.284.5418.1340
  14. Sitze, M. S.; Schreiter, E. R.; Patterson, E. V.; Freeman, R. G. Inorg. Chem. 2001, 40, 2298 https://doi.org/10.1021/ic001042r
  15. Menon, V. P.; Lei, J.; Martin, C. R. Chem. Mater. 1996, 8, 2382 https://doi.org/10.1021/cm960203f
  16. Jerome, C.; Jerome, R. Angew. Chem. Int. Ed. 1998, 37, 2488 https://doi.org/10.1002/(SICI)1521-3773(19981002)37:18<2488::AID-ANIE2488>3.0.CO;2-O
  17. José, N.; Lopes, C.; Margarida, F.; Costa Gomes, C.; Agílio, A. H.; Padua, A. H. J. Phys. Chem. B 2006, 110(34), 3330 https://doi.org/10.1021/jp056006y
  18. Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, A.; Watanabe, B. H. M. J. Phys. Chem. B 2005, 109, 6103 https://doi.org/10.1021/jp044626d
  19. Pringle, J. M.; Ngamna, O.; Chen, J.; Wallace, G. G.; Forsyth, M.; MacFarlane, D. R. Synth. Met. 2006, 156, 979 https://doi.org/10.1016/j.synthmet.2006.06.009
  20. Furukawa, Y.; Tazawa, S.; Fujii, Y.; Harada, I. Synth. Met. 1988, 24, 329 https://doi.org/10.1016/0379-6779(88)90309-8

피인용 문헌

  1. mim]Cl Ionic Liquids vol.116, pp.22, 2012, https://doi.org/10.1021/jp206819h
  2. Interface properties of ionic liquids containing metal ions: features and potentialities vol.14, pp.15, 2012, https://doi.org/10.1039/c2cp24012b