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http://dx.doi.org/10.5012/bkcs.2011.32.3.973

The Soft Material Obtained from an Europium (III)-Containing Ionic Liquid  

Shao, Huifang (School of Chemical Engineering and Technology, Hebei University of Technology)
Wang, Yige (School of Chemical Engineering and Technology, Hebei University of Technology)
Li, Dan (School of Chemical Engineering and Technology, Hebei University of Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.3, 2011 , pp. 973-976 More about this Journal
Abstract
The addition of organic ligand (${\beta}$-diketone or heterocyclic compound) to the europium (III)-containing ionic liquid resulted in bright luminescent soft materials with the molar ratio of europium/ionic liquid (IL)/ligand being 1:3:1 that exhibit bright red light under UV lamp. The luminescent properties such as emission features and lifetime of $^5D_0$ $Eu^{3+}$ excited level are dependent on the organic ligands. The materials were characterized by FT-IR and luminescence spectroscopy. The data shows that at least parts of the ILs (carboxylic acid) are replaced with ${\beta}$-diketone ligand rather than the formation of europium complex with the molar ratio of $Eu^{3+}$:IL: ligand being 1:3:1, while no ILs could be replaced by the heterocyclic ligand such as Bpy and Phen.
Keywords
Ionic liquid; Europium (III); Luminescence; Organic ligand;
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