• 제목/요약/키워드: Hydrogen behavior

검색결과 702건 처리시간 0.024초

가솔린.메탄의 연소특성 비교 (Comparison of the Combustion Characteristics of Methane-Air and Gasoline-Air Mixtures)

  • 박명호
    • 한국분무공학회지
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    • 제7권3호
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    • pp.7-11
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    • 2002
  • Comparison of the combustion characteristics of methane-air and gasoline-air mixtures has been conducted experimentally by a spherical bomb technique. The results indicate 1) the burning velocity of gasoline is slightly higher than that of methane, but their basic behavior of combustion characteristics, positive dependence on temperature and negative one on pressure, are the same, and 2) 20 vol.% addition of hydrogen to methane enhances the burning velocity by about 30%, but does not come to reverse the tendency of pressure dependence to that of pure hydrogen.

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메탄-수소 층류확산화염에서 $H_2$와 H의 선호확산이 NO 거동에 미치는 영향에 관한 연구 (A Study on NO Emission Behavior through Preferential Diffusion of $H_2$ and H in $CH_4-H_2$ Laminar Diffusion Flames)

  • 박정;권오붕;윤진한;길상인
    • 한국수소및신에너지학회논문집
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    • 제18권3호
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    • pp.265-274
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    • 2007
  • A study has been conducted to clarify NO emission behavior through preferential diffusion effects of $H_2$ and H in methane-hydrogen diffusion flames. A comparison is made by employing three species diffusion models. Special concerns are focused on what is the deterministic role of the preferential diffusion effects in flame structure and NO emission. The behavior of maximum flame temperatures with three species diffusion models is not explained by scalar dissipation rate but the nature of chemical kinetics. The preferential diffusion of H into reaction zone suppresses the populations of the chain carrier radicals and then flame temperature while that of $H_2$ produces the increase of flame temperature. These preferential diffusion effects of $H_2$ and H are also discussed about NO emissions through the three species diffusion models.

수소가 장입된 Zircaloy-4 합금의 부식 후의 Ac Impedance 특성 (AC Impedance Characteristics of the Corroded Hydrogen-Charged Zircaloy-4 Alloy)

  • 김선재;김경호;백종혁;최병권;정용환
    • 한국재료학회지
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    • 제9권2호
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    • pp.205-210
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    • 1999
  • The 250ppm hydrogen-charged Zircaloy-4 sheets, homogenized at $400^{\circ}C$ for 72hrs in vacuum, were corroded under the autoclave conditions of $350^{\circ}C$, 2350psi. The corrosion behavior of the Zircaloy-4 sheets was evaluated by measuring their weight gains with the exposure time. The electrical characteristics were investigated in the ranges of 5000~1x10\ulcornerHz using AC impedance technique in 1N $H_2$$SO_4$aqueous solution. The corrosion rate of the hydrogen charged specimen was more rapid than the normal specimen at the early stage of the corrosion. With a longer corrosion time, however, the normal specimen corroded faster than the hydrogen-charged specimen. At the same time the hydrogen pickup in the hydrogen-charged specimen was more suppressed compared with the normal specimen. Such appears to be occurred because the impedance for the movement of the hydrogen ion into the metal was higher in the hydrogen-charged specimen compared to normal specimen at the interface between the oxide layer and the uncorroded metal. Thus the corrosion rate of the hydrogen-charged specimen was likely to be decreased with a longer corrosion time.

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Type III 수소 저장 용기에서 난류 모델(Turbulence Model)에 따른 충전(Filling)현상의 수치 해석적 연구 (Numerical Analysis of Fillling Flow in Type III Hydrogen Tank with Different Turbulence Models)

  • 김무선;류준형;이성권;최성웅
    • 한국수소및신에너지학회논문집
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    • 제32권6호
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    • pp.483-488
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    • 2021
  • With continuous emission of environmental pollutants and an increase in greenhouse gases such as carbon dioxide, demand to seek other types of energy sources, alternative energy, was needed. Hydrogen, an eco-friendly energy, is attracting attention as the ultimate alternative energy medium. Hydrogen storage technology has been studied diversely to utilize hydrogen energy. In this study, the gas behavior of hydrogen in the storage tank was numerically examined under charge conditions for the Tpe III hydrogen tank. Numerical results were compared with the experimental results to verify the numerical implementation. In the results of pressure and temperature values under charge condition, the Realizable k-ε model and Reynold stress model were quantitatively matched with the smallest error between numerical and experimental results.

The thermal cycling stability of V-Ti based alloy

  • Park, Jeoung-Gun;Kim, Dong-Myung;Jang, Kuk-Jin;Han, Jai-Sung;Lee, Jai-Young
    • 한국수소및신에너지학회논문집
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    • 제9권3호
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    • pp.111-118
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    • 1998
  • The intrinsic degradation behavior of $(V_{0.53}Ti_{0.47})_{0.925}Fe_{0.075}$ alloy with BCC structure and the two plateau regions (the low and high plateau region) has been investigate during the temperature-induced hydrogen absorption-desorption cycling (thermal cycling). After 400 thermal cycles between room temperature and $600^{\circ}C$ under 10atm $H_2$, the total reversible hydrogen absorption capacity decreased by about 40%. From thermal desorption analysis it was found that the degradation behavior at each plateau region was different. In addition, XRD analysis showed that the crystal structure of the sample in de-hydrided state was changed from BCC to BCT after degradation, and that of the sample in hydrided state it was maintained as FCC although peaks were broadened after degradation. From the result of static isothermal hydrogenation treatment it were found that crystal structure change from BCC to BCT was caused by the thermal energy. TEM analysis showed that the peak broadening was due to the formation of an amorphous phase in FCC matrix.

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C-Type LH2 운송선박 운항 및 하역공정 전산모사를 통한 LH2 탱크 거동 분석 (Analysis of LH2 Tank Behavior through Computational Simulation of C-Type LH2 Carrier on Voyage and Unloading Process)

  • 김동혁;이영범;서흥석;모용기;이치훈
    • 한국수소및신에너지학회논문집
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    • 제33권6호
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    • pp.827-837
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    • 2022
  • If the hydrogen industry is activated, the introduction of C-type and pressurized liquefied hydrogen (LH2) tank suitable for small and medium-sized transp- ortation and storage will be given priority in the future. Therefore in this paper, the behavior for the LH2 property changes and boil-off gas (BOG) treatment of the C-type cargo tank through voyage of the LH2 carrier and pressurized tank of the LH2 receiving terminal were analyzed through computational simulations by making assumptions about the carrier operation and unloading conditions.

AMESet 기반 20 kW급 수소 연료전지 시스템 동특성 모델 해석 (Analysis of Dynamic Characteristics of 20 kW Hydrogen Fuel Cell System Based on AMESet)

  • 우종빈;김영현;유상석
    • 한국수소및신에너지학회논문집
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    • 제34권5호
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    • pp.465-477
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    • 2023
  • In proton exchange membrane fuel cell (PEMFC), proper thermal management of the stack and moisture generation by electrochemical reactions significantly affect fuel cell performance. In this study, the PEMFC dynamic characteristic model was developed through Simcenter AMESim, a development program. In addition, the developed model aims to understand the thermal resin balance of the stack and performance characteristics for input loads. The developed model applies the thermal management model of the stack and the moisture content and permeability model to simulate voltage loss and stack thermal behavior precisely. This study extended the C based AMESet (adaptive modeling environment submodeling tool) to simulate electrochemical reactions inside the stack. Fuel cell model of AMESet was liberalized with AMESim and then integrated with the balance of plant (BOP) model and analyzed. And It is intended to be used in component design through BOP analysis. The resistance loss of the stack and thermal behavior characteristics were predicted, and the impact of stack performance and efficiency was evaluated.

연료전지 트럭의 운전 부하 패턴에 따른 고분자 연료전지 스택의 동특성 시뮬레이션 (Dynamic Simulation of Proton Exchange Membrane Fuel Cell Stack under Various Operating Pattern of Fuel Cell Powered Heavy Duty Truck)

  • 손나민;무자히드 나심;김의연;이영덕
    • 한국수소및신에너지학회논문집
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    • 제35권2호
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    • pp.121-128
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    • 2024
  • In this study, a dynamic simulation model of a heavy-duty truck, equipped with a fuel cell power-train, has been developed and the dynamic behavior of the fuel cell stack has bee investigated using. Output change simulations were performed according to several drive cycle load change of a fuel cell truck. Mathworks' Simulink and Simscape program were used to develop the model. The model is comprised of fuel cell power train, power converter system and truck vehicle part. The vehicle runs at targeted speed of the truck, which is set as the load of the system. The dynamic behavior of the fuel cell stack according to the weight difference were analyzed, and based on this, the dynamic characteristics of the fuel cell output power and battery state with simple load was analyzed.

Design and construction of fluid-to-fluid scaled-down small modular reactor platform: As a testbed for the nuclear-based hydrogen production

  • Ji Yong Kim;Seung Chang Yoo;Joo Hyung Seo;Ji Hyun Kim;In Cheol Bang
    • Nuclear Engineering and Technology
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    • 제56권3호
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    • pp.1037-1051
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    • 2024
  • This paper presents the construction results and design of the UNIST Reactor Innovation platform for small modular reactors as a versatile testbed for exploring innovative technologies. The platform uses simulant fluids to simulate the thermal-hydraulic behavior of a reference small modular reactor design, allowing for cost-effective design modifications. Scaling analysis results for single and two-phase natural circulation flows are outlined based on the three-level scaling methodology. The platform's capability to simulate natural circulation behavior was validated through performance calculations using the 1-D system thermal-hydraulic code-based calculation. The strategies for evaluating cutting-edge technologies, such as the integration of a solid oxide electrolysis cell for hydrogen production into a small modular reactor, are presented. To overcome experimental limitations, the hardware-in-the-loop technique is proposed as an alternative, enabling real-time simulation of physical phenomena that cannot be implemented within the experimental facility's hardware. Overall, the proposed versatile innovation platform is expected to provide valuable insights for advancing research in the field of small modular reactors and nuclear-based hydrogen production.