• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.448-454
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• 2012

In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

• 한국수소및신에너지학회논문집
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• 제34권3호
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• pp.292-296
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• 2023

Until recently, ships, automobiles, and drones using hydrogen energy are being actively researched. In addition, stations and facilities for hydrogen supply are being developed widely. Among them, a hydrogen pump is necessary for compressing it and transfer to other stations. The liquid hydrogen pump is operated at very high pressure up to 90 MPa. In our research, a reciprocating plunger pump is studied. Especially, a leakage in a liquid hydrogen pump is predicted using a finite element method. As a result, it was found that leak mass flow rates changed from 0.09 to 2.20 kg/h, when the gaps were given from 2 to 6 ㎛. Thus pump efficiencies were calculated from 99.9 to 97.9%, when the gaps changed from 2 to 6 ㎛. These results are useful for the design of the liquid hydrogen pump.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.565-572
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• 2021

Hydrogen is currently produced from natural gas reforming or industrial process of by-product over than 90%. Additionally, there are green hydrogens based on renewable energy generation, but the import of green hydrogen from other countries is being considered due to the output variability depending on the weather and climate. Due to low density of hydrogen, it is difficult to storage and import hydrogen of large capacity. For improving low density issue of hydrogen, the gaseous hydrogen is liquefied and stored in cryogenic tank. Density of hydrogen increase from 0.081 kg/m³ to 71 kg/m3 when gaseous hydrogen transfer to liquid hydrogen. Density of liquid hydrogen is higher about 800 times than gaseous. However, since density and boiling point of liquid hydrogen is too lower than liquefied natural gas approximately 1/6 and 90 K, to store liquid hydrogen for long-term is very difficult too. To overcome this weakness, this paper introduces storage method of hydrogen based on liquid/solid (slush) and facilities for producing slush hydrogen to improve low density issue of hydrogen. Slush hydrogen is higher density and heat capacity than liquid hydrogen, can be expected to improve these issues.

• 한국수소및신에너지학회논문집
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• 제26권6호
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• pp.516-523
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• 2015

Nickel based oxygen transfer materials supported on two different YSZs were tested to evaluate their performance in methane chemical-looping reforming. The oxygen transfer materials of YSZs were selected with different amount of the doped yittrium in the $ZrO_2$ structure. The yittrium of 8 mol% stabilized the zirconia oxide to a cubic structure compare to the 3 mol% doping, which is known to be a good for oxygen transfer. Various nickel amounts (16wt.%, 32wt.%, 48wt.%) were loaded on the selected supports. The nickel amount of 32% shows the optimized catalyst structure with good physical properties and reducibility from the XRD, BET and H2-TPR analysis, especially when the support of 8YSZ was used. From the methane chemical-looping reforming, hydrogen was produced by methane decomposition catalyzed by Ni on both YSZs. Comparing two YSZ supports of 3YSZ and 8YSZ during the cycling tests, the catalyst with 8YSZ (Ni 32%) exhibits not only the higher methane conversion and hydrogen production but also a faster reaction rate reaching to the stable point.

• 폴리머
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• 제32권6호
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• pp.566-572
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• 2008

메탈로센 [(TMDS)$Cp_2$]$ZrCl_2$, 촉매 1과 Exxon 촉매인 [$(n-Bu)_2Cp_2$]$ZrCl_2$, 촉매 2를 사용하여 폴리에틸렌 왁스를 제조하였다. 분자량을 조절하기 위하여 수소를 연쇄이동제로 사용하였다. 실험결과 수소의 주입량이 증가할수록 중합활성의 감소 생성된 폴리에틸렌 왁스의 분자량과 분자량 분포의 감소 그리고 폴리에틸렌 왁스의 융점 저하가 관찰되었다. 수소의 주입으로 폴리에틸렌의 분자량은 1500, 융점은 60 $^\circ$C까지 조절이 가능하였다. 수소의 양을 조절함으로써 메탈로센을 통해 분자량분포가 좁고 융점이 낮은 고품질의 폴리에틸렌 왁스의 제조가 가능하였다. 본 연구실에서 개발된 촉매 1은 알려진 가장 우수한 메탈로센인 촉매 2와 폴리에틸렌 왁스 제조에서 경쟁이 가능한 유사한 특성을 보였다.

• 대한기계학회논문집B
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• 제22권4호
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• pp.520-529
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• 1998

Heat and mass transfer behaviors of metal hydride beds were predicted by solving a set of volume-averaged equations numerically both for the gas (hydrogen) and the solid(metal hydride) phases. Time variations of temperature and hydrogen concentration ratio distributions were obtained for internally cooled, cylindrical-shaped beds with metal(aluminum) fins imbedded in them. Also, time variations of the space-averaged hydrogen concentration ratio were obtained. Temperature and velocity of the coolant, hydrogen pressure at the gas inlet, and the fin spacing were taken as the parameters. The hydrogen absorption rate increases with the higher velocity and the lower temperature of the coolant, and with the decrease of the fin spacing. Increasing of the hydrogen pressure at the gas inlet also promotes the rate of absorption though the increasing rate gradually slows down. The amount of the hydrogen storage per unit volume of the bed decreases with the tighter fin spacing despite of the higher absorption rate ; therefore, there should be an optimum fin spacing for a given volume of the system and the amount of the hydrogen storage, in which the absorption rate is the highest.

• 한국수소및신에너지학회논문집
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• 제34권4호
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• pp.334-341
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• 2023

The purity of hydrogen finally purified in the hydrogen purification process system is greatly influenced by the uniformity of the purification temperature of the dry tower. A in-house code that can be easily used by field designers has been developed to predict the capacity of the appropriate heat source and the time to reach the temperature of the dry tower. A code was developed to predict unsteady heat transfer using Visual Basic for Applications. To verify the developed code, a grid independence test was performed, and finally, calculations were performed for two cases. In the first case, the time for the temperature of the heater jacket to reach 360℃ was about 1,400 seconds when the supply heat source was 1,000 W. And in the second case, the time for the temperature of the heater jacket to reach 360℃ was about 710 seconds when the supply heat source was 2,000 W. It was confirmed that the developed code well describes the actual test data of the regeneration process of adsorption and desorption, and it is judged that the code developed in the design process of various capacity systems will be effectively applied to the heat capacity calculation in the future.

• 설비공학논문집
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• 제3권5호
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• pp.337-349
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• 1991

Heat and mass transfer rates to spray water droplets for spray transients in a high pressure vessel have been predicted by two different droplet models: the complete mixing model and the non-mixing model. In this process, the ambient fluid surrounding the droplets is a real-gas mixture composed of saturated steam and noncondensable hydrogen gas at high pressure. The physical properties of the mixture are estimated by applying the concept of compressibility factor and using appropriate correlations. A computer program, DROPHMT, to calculate the heat and mass transfer rates for two different droplet models has been developed. As an illustrative application of the computer program to engineering practices, heat and mass transfer rates to spray water droplets for spray transients in a Pressurized Water Reactor (PWR) pressurizer have been calculated, and the typical results have been provided.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.183-190
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• 2014

Our lab designs a heat exchangers for air and carbondioxide gas. Coolant is water, thus it is very difficult to determine heat transfer parameters in this gas-liquid system. Repeated experiments gives overdesign value 35%, overall heat transfer coefficient $33.8(kcal/m2-hr-^{\circ}C)$ for carbondioxide. Another series of experiments determine overdesign 18.7%, overall heat transfer coefficient $21.4(kcal/m2-hr-^{\circ}C)$ for Air. These parameters are in same range of literature. Overdesign is increasing as tube length increases, also increases as wall thickness of heat exchanger increases. To get proper fluid linear velocity in heat exchanger, we change the diameter of tube and finally we can have optimum fluid linear velocity in the heat exchanger.

• 천문학회보
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• 제41권1호
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• pp.77.4-78
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• 2016

Binary interactions may have significant impact on Pop III stellar evolution. Pop III single star evolution indicates that for primary masses less than $20M_{\odot}$, no significant binary mass transfer would occur before core helium exhaustion. We perform binary system evolution for various primary masses ($20M_{\odot}$ < $M_1$ < $60M_{\odot}$) and initial periods under same mass ratio $M_2/M_1=0.9$, and follow the evolution and mass transfer of the primary star. If binary mass transfer occurs during post main sequence, the primary star does not evolve into naked helium star and still contain significant hydrogen in the envelope. During the post mass transfer phase, the primary star evolves redward, and does not become sufficiently hot to enhance the number of ionizing photons, compared to the case of single star evolution for a given initial mass. This result implies that primary stars of massive Pop III binary systems would have little contribution to the reionization in the early universe. Given the large hydrogen content ($0.326-1.793M_{\odot}$), the primary stars that underwent stable mass transfers would explode as a Type IIb supernova, and it would be difficult for Pop III binary stars to produce Type Ib/c supernovae that look similar to those found in the local universe.