• Title/Summary/Keyword: Hybrid electrolyte

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Study on the Heat Dissipation Behavior of Diecast Mg Inverter Housing for Eco-friendly Hybrid Vehicles (친환경 전기 하이브리드 자동차용 마그네슘 다이캐스팅 인버터 하우징의 열방출 특성)

  • Cho, In-Sung;Han, Yo-Sub;Lee, Seung-Jae;Lee, Byung-jun
    • Journal of Korea Foundry Society
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    • v.38 no.3
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    • pp.60-65
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    • 2018
  • In the present study, the characteristics of Mg inverter cases for hybrid cars are investigated. Concerns over the use of lightweight materials to reduce energy use and to mitigate emission problems are inevitable in the twenty-first century. Magnesium is a promising material for the manufacturing of lightweight parts. Several cases for thermal cooling channels have been designed and simulated, and the effects of materials and coatings on the thermal cooling efficiency have been discussed. The effects of the coating thickness on heat extraction in an Mg inverter housing case using the PEO (plasma electrolyte oxidation) coating method were also discussed. In order to produce an inverter case by the diecasting process, the filling sequence and cooling behavior during the diecasting process were simulated. The optimized process conditions from the simulation result were then used in a trial diecasting experiment.

Hybrid & Fuel Cell Connection Power System for Ocean Structure (하이브리드 및 연료전지 연계형 해양구조물용 전력체계)

  • Park, Do-Young;Oh, Jin-Seok
    • Journal of Navigation and Port Research
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    • v.35 no.8
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    • pp.637-641
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    • 2011
  • Ocean structure's power system is difficult to construct a stand-alone power system. Therefore, to manage effectively power system of ocean structure, it's important to construct power system which is connected fuel-cell with hybrid power system. This paper designs power system of fuel-cell for the sea based on hydrogen generation mechanism, calculation of using electric power, etc. Designed power system is analysed & simulated using LabVIEW program. And, this paper suggests design method of power system for ocean structure based on analysed & simulated results.

Electrochemical Characterization of Hybrid Semiconductor-Based Dye-Sensitized Solar Cells (혼성반도체로 제조된 염료감응형 태양전지의 전기화학적 특성)

  • Lee, Sung-Kyu;Jeong, Eui-Gyung;Im, Ji-Sun;Lee, Young-Seak
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.175-180
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    • 2011
  • In this study, the $TiO_{2}/V_{2}O_{5}$ hybrid semiconductors were prepared by mixing $TiO_{2}$ and $V_{2}O_{5}$, and a subsequent smash process to reduce the recombination of electron and improve the efficiency of solar cells. Dye-sensitized solar cells were constructed using the resultant hybrid semiconductor, and their electrochemical properties were also investigated. The photocurrent-voltage curve obtained with the cells indicated a significant increase in the efficiency from 2.9 to 5.7% by the factor of 2 compared to the result obtained only with $TiO_{2}$. It is believed that the introduction of $V_{2}O_{5}$ effectively transport electrons in the $TiO_{2}$ conduction band to FTO glass and suppress recombination with the dye and/or the electrolyte, thus yielding an efficient performance of the dye sensitized solar cell. The impedance values also indicated a decrease of resistance in the interface of $TiO_{2}$/dye/electrolyte supporting the constructive contributions of the smashed $TiO_{2}/V_{2}O_{5}$ hybrid semiconductors for the efficiency.

Improvement of Properties in Solid Polymer Electrolyte Using New Preparation Method (새로운 막 제조 방법에 의한 고분자 전해질막의 특성 향상)

  • Kim, Tae-Hee;Lee, Jung-Hun;Park, Kwon-Pil
    • Journal of Hydrogen and New Energy
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    • v.17 no.3
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    • pp.331-337
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    • 2006
  • 높은 이온전도도와 충분한 기계적 강도, 전해질 누수가 적은 새로운 형태의 고분자 전해질막(pore-gel SPE)을 연구 개발하였다. 다공성 PVDF-HFP 고분자막의 기공 내에 전해질 용액을 흡수시킨 후 막 내에서 젤화를 진행시켰다. 전해질 용액은 2:2:1의 비를 갖는 PC/EC/DMA에 1M SA(Salicylic acid)를 용해하고 여기에 고분자막을 용해시킬 수 있는 아세톤을 첨가하였다. 초음파를 이용함으로써 고분자막의 용액 흡수율을 증가시키고 또 고분자막에서 젤화를 촉진 시킬 수 있었다. 이렇게 젤화한 막의 이온전도도는 젤화 전 막보다 $1{\sim}2.2$ 배 향상되었고, 인장강도는 gel-type SPE 보다 40 배 증가하였으며, 전해질 누수실험결과 hybrid-type SPE는 13%의 누수를 보였으나 본 연구의 막(pore-gel SPE)은 6%로 감소함을 보였다.

MWCNTs/V2O5 Nanowire Hetero-junction Actuator Devices (탄소나노튜브/V2O5 나노선 헤테로 구동소자 특성연구)

  • Lee Kang-Ho;Yee Seong-Min;Park So-Jeong;Huh Jung-Hwan;Kim Gyu-Tae;Park Sung-Joon;Ha Jeong-Sook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.250-254
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    • 2006
  • Hetero-junction sheet actuator composed of carbon nanotubes and $V_{2}O_5$ nanowires were demonstrated in a bimetal configuration. The successive filtration of $V_{2}O_5$ nanowire solution followed by carbon nanotube dispersed water solution in the same way produced a dark-gray colored sheet. A significant actuation was observed in sodium chloride electrolyte solution with a bending direction to the carbon nanotube side at the positive bias voltage against the copper counter-electrode. As the frequency of the applied voltage increased, the amplitudes decreased, indicating a rather slow response of the hetero-film actuator in the electrolyte solution. The hybrid structure enabled an easy fabrication of the film actuator with the enhanced efficiencies.

Characteristics of Oxide Layers Formed on Al2021 Alloys by Plasma Electrolytic Oxidation in Aluminate Fluorosilicate Electrolyte

  • Wang, Kai;Koo, Bon-Heun;Lee, Chan-Gyu;Kim, Young-Joo;Lee, Sung-Hun;Byon, Eung-Sun
    • Journal of Surface Science and Engineering
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    • v.41 no.6
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    • pp.308-311
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    • 2008
  • Oxide layers were prepared on Al2021 alloys substrate under a hybrid voltage of AC 200 V (60 Hz) combined with DC 260 V value at room temperature within $5{\sim}60\;min$ by plasma electrolytic oxidation (PEO). An optimized aluminate-fluorosilicate solution was used as the electrolytes. The surface morphology, thickness and composition of layers on Al2021 alloys at different reaction times were studied. The results showed that it is possible to generate oxide layers of good properties on Al2021 alloys in aluminate-fluorosilicate electrolytes. Analysis show that the double-layer structure oxide layers consist of different states such as ${\alpha}-{Al_2}{O_3}$ and ${\gamma}-{Al_2}{O_3}$. For short treatment times, the formation process of oxide layers follows a linear kinetics, while for longer times the formation process slows down and becomes a steady stage. During the PEO processes, the average size of the discharge channels increased gradually as the PEO treatment time increased.

A Review on Prognostics of Polymer Electrolyte Fuel Cells (고분자전해질 연료전지 예지 진단 기술)

  • LEE, WON-YONG;KIM, MINJIN;OH, HWANYEONG;SOHN, YOUNG-JUN;KIM, SEUNG-GON
    • Journal of Hydrogen and New Energy
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    • v.29 no.4
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    • pp.339-356
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    • 2018
  • Although fuel cell systems have advantages in terms of electric efficiency and environmental impact compared with conventional power systems, fuel cell systems have not been deployed widely due to their low reliability and high price. In order to guarantee the lifetime of 10 years, which is the commercialization goal of Polymer electrolyte fuel cells (PEFCs), it is necessary to improve durability and reliability through optimized operation and maintenance technologies. Due to the complexity of components and their degradation phenomena, it's not easy to develop and apply the diagnose and prognostic methodologies for PEFCs. The purpose of the paper is to show the current state on PEFC prognostic technology for condition based maintenance. For the prognostic of PEFCs, the model driven method, the data-driven, and the hybrid method can be applied. The methods reviewed in this paper can contribute to the development of technologies to reduce the life cycle cost of fuel cells and increase the reliability through prognostics-based health management system.

Preparation and Characterization of Sulfonated Poly(phthalazinone ether sulfone ketone) (SPPESK)/Silica Hybrid Membranes for Direct Methanol Fuel Cell Applications

  • Kim, Dae-Sik;Shin, Kwang-Ho;Park, Ho-Bum;Lee, Young-Moo
    • Macromolecular Research
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    • v.12 no.4
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    • pp.413-421
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    • 2004
  • Sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK) membranes and sol-gel derived SPPESK/silica hybrid membranes have been investigated as potential polymer electrolyte membranes for direct methanol fuel cell (DMFC) applications. In comparison with the SPPESK membrane, the SPPESK/silica membranes exhibited higher water content, improved proton conductivity, and lower methanol permeability. Notably, the silica embedded in the membrane acted as a material for reducing the fraction of free water and as a barrier for methanol transport through the membrane. From the results of proton conductivity and methanol permeability studies, we suggest that the fractions of bound and free water should be optimized to obtain desirable proton conductivities and methanol permeabilities. The highly sulfonated PPESK hybrid membrane (HSP-Si) displayed higher proton conductivity (3.42 ${\times}$ 10$^2$ S/cm) and lower methanol permeability (4.15 ${\times}$ 10$\^$7/ $\textrm{cm}^2$/s) than those of Nafion 117 (2.54 ${\times}$ 10$^2$ S/cm; 2.36 ${\times}$ 10$\^$6/ $\textrm{cm}^2$/s, respectively) at 30$^{\circ}C$. This characteristic of the SPPESK/silica membranes is desirable for future applications related to DMFCs.

Preparation and Characterization of SPAES/SPVdF-co-HFP Blending Membranes for Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지용 술폰화된 폴리(아릴렌 이써 설폰)/SPVdF-co-HFP 브렌딩 멤브레인의 제조 및 특성 분석)

  • PARK, CHUL JIN;KIM, AE RHAN;YOO, DONG JIN
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.227-236
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    • 2019
  • In this work, preparation and characterizations of hybrid membranes containing sulfonated poly(arylene ether sulfone) (SPES) and sulfonated poly(vinylidene fluoride-co-hexafluoropropylene) (SPVdF-co-HFP) (20, 30 or 40 wt%) were carried out. The structure of hybrid membranes was confirmed using X-ray diffraction (XRD) analysis and the Fourier transform infrared (FT-IR) spectroscopy. The prepared SPAES/SPVdF-30 membrane exhibits higher ionic conductivity of 68.9 mS/cm at $90^{\circ}C$ and 100% RH. Besides, the other studies showed that the hybrid membrane has good oxidation stability, thermal stability, and mechanical stability. Thus, we believe that the prepared hybrid membrane is suitable for the development of membranes for fuel cell applications.

Highly Durable Pt catalyst Supported on the Hybrid Carbon Materials for Polymer Electrolyte Membrane Fuel Cell (탄소계 복합담지체에 담지된 고내구성 고분자전해질 연료전지용 백금촉매)

  • Park, Hyang Jin;Hur, Seung Hyun
    • Journal of the Korean Electrochemical Society
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    • v.17 no.3
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    • pp.201-208
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    • 2014
  • A Pt catalyst ($Pt/G_xC_y$) supported on the hybrid supporting materials composed of graphene oxide (GO) and carbon black (C) was fabricated using polyol method to improve the durability of electrocatalysts. The electrochemical performances measured by cyclic voltammograms using three-electrode system revealed that the properly designed $Pt/G_xC_y$ catalyst exhibited higher durability than that of Pt/C catalyst without sacrificing an electrocatalytic acivity. In the oxygen reduction reaction (ORR) performed in acid solution with the rotating disk electrode, the $Pt/G_xC_y$ catalyst showed greater mass and area-specific activity than those of Pt/C catalyst.