• 전기학회논문지
• /
• 제66권12호
• /
• pp.1740-1744
• /
• 2017

This paper describes the preparation and characteristics of a battery capacitor and module for solar power system. A cylindrical 30,000F battery capacitor ($60{\times}138mm$) was assembled by using the $LTO(Li_4Ti_5O_{12})$ electrode as an anode and $NMC(LiNiMnCoO_2)-LCO(LiCoO_2)$ as a cathode. The battery capacitor has reduced energy density and power density under high CC(constant current) and CP(constant power) conditions. Battery capacitor module (16V, 11Ah) was fabricated using an asymmetric hybrid capacitor with a capacitance of 30,000F. In order to determine the characteristics of the battery capacitor Module for solar power system, battery capacitor cells were connected in series with active balancing circuit. As a result of measuring the 100w LED lamp, it was discharged at the voltage of 15V~10V, and the compensation time at discharge was measured to be about 4979s. Experimental results show that it can be applied to applications related to solar power system by applying battery capacitor module.

• Journal of Electrical Engineering and Technology
• /
• 제7권2호
• /
• pp.207-211
• /
• 2012

Spinel-$Li_4Ti_5O_{12}$ was successfully synthesized by a solid-phase method at 800, 850, and $900^{\circ}C$ according to the $Li_4Ti_5O_{12}$ cubic spinel phase structure. To achieve higher EDLC energy density with the $Li_4Ti_5O_{12}$, the negative electrode of the hybrid supercapacitor was studied in this work. The electrochemical performances of the hybrid supercapacitor and EDLC were characterized by constant current discharge curves, c-rate, and cycle performance testing. The capacitance (1st cycle) of the hybrid supercapacitor and EDLC was 209 and 109 F, respectively, which is higher than EDLC. The capacitance of the hybrid supercapacitor decreases from 209 F to 101 F after 20 cycles when discharged at several specific current densities ranging from 1 to 10 A. In contrast, capacitance of the EDLC hardly decreases after 20 cycles. Results show that hybrid supercapacitor benefits from the high rate capability of supercapacitor and high capacity of the battery. Findings also prove that the hybrid supercapacitor is an energy storage device where the supercapacitor and the Li ion secondary battery coexist in one cell system.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2004년도 전력전자학술대회 논문집(2)
• /
• pp.501-505
• /
• 2004

The study on the hybrid power source for the IMT2000 application has been presented. The hybrid power source is composed of solar cell, super-capacitor and battery. To compensate for the pulse loader of the IMT2000 application, the super-capacitor is connected through the Lithium-ion battery to absorb the pulse current. The solar cell provides the additional current to compensate for the depleted current. The controller design for the hybrid source has been presented and verified through experiment.

• 전기학회논문지
• /
• 제67권7호
• /
• pp.854-859
• /
• 2018

This paper describes the characteristics of a hybrid supercapacitor module for power quality stabilization. Hybrid supercapacitor is an promising energy storage device that positioned between conventional EDLC and Li-ion battery. A cylindrical 7500F hybrid supercapacitor ($60{\times}138mm$) was assembled by using the $Li_4Ti_5O_{12}$ electrode as an anode and activated carbon as a cathode. Considering the ESR and efficiency has been designed to module with 41.6F 480V design results in 180 series combination. In order to determine the characteristics of the hybrid supercapacitor module for power system, hybrid supercapacitor cells were connected in series with active balancing circuit. As a result of measuring the 50kw UPS, it was discharged at the current of 104A~143A during the discharge in the voltage range of 350V~480V, and the compensation time at discharge was measured to be about 30s. These results can be used to stabilization of power quality by applying hybrid supercapacitor module.

• Korean Chemical Engineering Research
• /
• 제52권1호
• /
• pp.52-57
• /
• 2014

본 연구에서는 낮은 사이클 안정성을 갖는 MCMB의 단점을 향상시키기 위하여 높은 사이클 안정성과 부피팽창이 없는 장점을 갖는 물질인 $Li_4Ti_5O_{12}$를 코팅하여 core-shell 구조의 $MCMB/Li_4Ti_5O_{12}$를 합성하고 $MCMB/Li_4Ti_5O_{12}$를 음극으로, $LiMn_2O_4$, Active carbon fiber를 양극으로 사용하여 단위 셀을 제조하였다. $LiPF_6$ 염과 EC/DMC/EMC 용매를 전해질로 사용하여 제조한 하이브리드 커패시터 단위 셀로 충방전, 사이클, 순환전압전류, 임피던스 테스트를 진행하여 전기화학적 특성을 평가한 결과, MCMB-$Li_4Ti_5O_{12}/LiMn_2O_4$ 전극을 사용한 하이브리드 커패시터가 MCMB 전극의 하이브리드 커패시터 보다 좋은 충/방전 성능을 보였고, 67 Wh/kg, 781 W/kg의 에너지밀도와 출력밀도를 나타내었다.

• 전기전자학회논문지
• /
• 제18권3호
• /
• pp.313-319
• /
• 2014

전력계통운영의 목표는 전력시스템의 안정성과 신뢰성을 유지하여 원활한 전력을 공급하는 것이다. 안정적인 전력 공급을 위하여 무효전력과 모선 전압에 대한 고려를 해야 하는데, 모선의 전압을 일정 범위 이내로 유지하기 위하여 커패시터 뱅크를 비롯한 다양한 방안이 사용되고 있다. 본 논문에서는 계통 안정도와 전력공급 신뢰도를 상시키기 위한 하이브리드 타입의 커패시터 뱅크 설계 과정에 대하여 기술하였다. 설계 과정에는 커패시터 뱅크의 용량 산정, 리액터 타입 결정 및 리액터 용량 산정과정이 포함된다. 기존의 커패시터 뱅크의 설계과정과 같이 정상상태 Q-V 해석이나 상정사고 분석과 같은 방법을 통하여 무효전력 마진을 계산하여 저전압이 발생하는 모선에 무효전력 보상량을 산정한다. 그리고 고조파 실측을 통해 산출된 개별 고조파의 성분 크기를 기반으로 직렬 리액터의 크기를 산정하는 방식으로 설계과정을 제안하였다. 논문에서는 제안된 방법을 통하여 고조파의 크기가 감소함을 증명하였으며, 특히 5차와 7차 고조파의 저감에 효율적임을 보여주었다.

• 전기학회논문지
• /
• 제65권4호
• /
• pp.617-621
• /
• 2016

In addition to the energy storage facilities based on high power technologies, Electric double layer capacitors(EDLC) are today's candidate for power quality stabilization. However, its low energy density is often inhibiting factor for application of electric power industry. Hybrid supercapacitor is an promising energy storage device that positioned between conventional EDLC and Li-ion battery. This paper describes the preparation and characteristics of a hybrid supercapacitor and module for power quality stabilization. A cylindrical 3200F hybrid supercapacitor ($60{\times}74.5mm$) was assembled by using the $Li_4Ti_5O_{12}$ electrode as an anode and activated carbon as a cathode. It shows 2.5 times higher energy density than conventional EDLC with the same volume. In order to determine the characteristics of the hybrid supercapacitor Module for uninterruptible power supply (UPS), hybrid supercapacitor cells were connected in series with active balancing circuit. At even the high current density of 14A(10C), Module prepared by 18 cells showed the capacitance of 170F at 30~50V, suggesting the applicability for UPS.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2019년도 전력전자학술대회
• /
• pp.315-316
• /
• 2019

This paper proposes the operation scheme and control method for a four-level hybrid half-bridge flying-capacitor inverter (4L-HHBFCI). With in-phase disposition level-shifted modulation (IPD), the flying capacitor voltage ripple is less than 1% of the reference value, while the line-to-line voltage total harmonic distortion is 23.27% at unity modulation index. The performance and effectiveness of the proposed inverter operation have been verified by simulation results.

• Journal of Electrochemical Science and Technology
• /
• 제1권2호
• /
• pp.97-101
• /
• 2010

In order to apply hybrid capacitor, $Li_2Mn_3O_7$ was synthesized by combustion method using $LiNO_3$, $Li(CH_3COO){\cdot}2H_2O$ and $Mn(CH_3COO){\cdot}4H_2O$. Spinel pattern was identified the samples calcined over $400^{\circ}C$ in XRD. Intensity of $Mn_2O_3$ peak increased as the calcination temperature increased. To decide n/p ratio and to investigate electrochemical properties, charge-discharge tests of Li/$Li_2Mn_3O_7$ and Li/AC half-cell were carried out. Applying to AC/$Li_2Mn_3O_7$ hybrid capacitor, it had high discharge capacitance of 32.8 F/cc at 100 mA/g.

• Journal of Power Electronics
• /
• 제14권6호
• /
• pp.1119-1129
• /
• 2014

This study proposes a novel five-level three-phase hybrid-clamped converter composed of only six switches and one flying capacitor (FC) per phase. The capacitor-voltage-drift phenomenon of the converter under the classical sinusoidal pulse width modulation (SPWM) strategy is comprehensively analyzed. The average current, which flows into the FC, is a function of power factor and modulation index and does not remain at zero. Thus, a specific modulation strategy based on space vector modulation (SVM) is developed to balance the voltage of DC-link and FCs by injecting a common-mode voltage. This strategy applies the five-segment method to synthesize the voltage vector, such that switching losses are reduced while optional vector sequences are increased. The best vector sequence is then selected on the basis of the minimized cost function to suppress the divergence of the capacitor voltage. This study further proposes a startup method that charges the DC-link and FCs without any additional circuits. Simulation and experimental results verify the validity of the proposed converter, modulation strategy, and precharge method.