• 한국염색가공학회지
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• 제28권1호
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• pp.40-47
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• 2016

As a coating material for loudspeaker dampers, resilient polyurethane/epoxy hybrid resins were synthesized to replace conventional phenol resin and examined the physical properties, which are not only environmentally friendly but also not harmful to human. Five types of polyurethane resins were synthesized in the step-shot method using methylene diisocyanate, three polyols such as poly tetramethylene ether glycol(PTMEG, MW:2000), poly(1,4-buthylene adipate(PBAP, MW:2000), and poly carbonatediol(PCD, MW:2000), and three chain extenders such as ethylene glycol(EG), neopentyl glycol(NPG), and 1,4-buthandiol(1,4-BD). The five types of synthesized polyurethane resins and commercially available bisphenol A type epoxy resin were blended in weight ratios of 90:10, 70:30, and 50:50 to synthesize 15 types of polyurethane/epoxy hybrid resins. Among the polyurethane resins, the one that was synthesized using PCD and 1,4-BD showed excellent tensile strength, 100% modulus, low extension, and relatively high viscosity. Polyurethane/epoxy hybrid resins with higher epoxy resin contents showed better thermal properties and water resistance while those with higher polyurethane contents showed higher flexibility. The polyurethane/epoxy hybrid resin made by blending the polyurethane based on PCD and 1,4-BD with a bisphenol A type epoxy resin in a weight ratio of 70:30 was identified to be the most suitable to be used in speaker dampers.

• 한국응용과학기술학회지
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• 제23권4호
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• pp.319-327
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• 2006

In order to prepare high-solid coatings, first acrylic resins (HSAs) which contain 80% solid were synthesized, and then the prepared resins were cured with isocyanate at room temperature. In the synthesis of HSAs, viscosity, number average molecular weight $(M_n)$ and conversion were $1372{\sim}2700$ cps, $1520{\sim}1650$ and $83{\sim}87%$, respectively. Among the four kinds of initiators used, tert-amylperoxy-2-ethyl hexanoate was the most proper one in the synthesis of HSAs. With increasing $T_g$ values, viscosity increased rapidly and molecular weight increased slowly. As a result of the examination of coated films, it was found that $60^{\circ}$ specular gloss, impact resistance, heat resistance and cross-hatch adhesion were good, and pencil hardness, drying time and pot life were poor.

• Macromolecular Research
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• 제9권6호
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• pp.313-318
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• 2001

The present study relates to a method of manufacturing 100$\mu\textrm{m}$ thick cover layer for the high density digital versatile disc system (HD-DVD), which uses a high numerical aperture of 0.85 at 405 nm wavelength. Spin coating technique was investigated as means for manufacturing the cover layer within sufficient margins of thickness variation and with good mechanical properties including small radial and tangential tilts. The influence of processing variables such as spinning speed, spinning time, and dispensing position was investigated. The effect of viscosity of UV-curable resin was also investigated.

• Restorative Dentistry and Endodontics
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• 제32권5호
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• pp.469-475
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• 2007

본 연구는 물성의 단점이 많은 희석재인 TEGDMA의 사용을 줄이기 위해, Bis-GMA의 유도체로서 중합수축이 적고 점도가 낮은 새로운 단량체인 methoxlyated Bis-GMA (Bis-M-GMA)를 첨가한 복합레진의 법랑질과 상아질 변연에서의 미세누출을 비교하였다. 40개의 발거된 상하악 소구치의 협면과 설면에 $2\;mm\;{\times}\;2\;mm\;{\times}\;2\;mm$ 와동을 형성하여 4개 군으로 분류하였다. Clearfil SE bond와 복합레진을 이용하여 와동을 수복하였다. EX1군은 실험용 복합레진 1 (Bis-M-GMA/TEGDMA = 95/5wt% ,40 nm 나노필러 함유), EX2군은 실험용 복합레진 2 (Bis-M-GMA/TEGDMA = 95/5wt%, 20 nm 나노필러 함유), EX3군은 실험용 복합레진 3 (Bis-GMA/TEGDMA = 70/30wt%, 40 nm 나노필러 함유), Z250군은 Filtek 2250으로 각각 와동을 수복하였다. 모든 시편은 실온의 실온의 생리식염수에서 7일간 보관한 후, $5^{\circ}C$와 $55^{\circ}C$ 의 수조에서 500회의 열순환을 실시하고, 2% methylene blue염색 용액에 24시간 담근 후, 협설측으로 치아 장축에 평행하게 절단하고 광학입체현미경하에서 각 수복물의 법랑질과 상아질 변연부의 색소침투 정도를 관찰하여 미세누출점수로 기록한 후 각 군의 유의성을 검증하였다. 법랑질 변연이 상아질 변연보다 유의성있게 낮은 미세변연누출을 보였다 (p = 0.007). 각 변연에서 EX1, EX2보다 EX3, Z250군의 염색침투도가 증가하는 경향을 보였지만 통계적으로 유의성 있는 차이를 보이지는 않았다 (p > 0.05). 점도가 낮은 새로운 레진단량체인 Bis-M-GMA는 기존의 단량체인 Bis-GMA의 대체재로 고려될 수 있다.

• 한국염색가공학회지
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• 제34권3호
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• pp.157-164
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• 2022

This study tried to analyze the heat resistance properties by blending epoxy and phenolic resin in a certain ratio, and to analyze the adhesive properties at the time of metal-polymer hetero-adhesion by applying Epoxy-phenolic resin between a silicon steel sheet and m-aramid sheet, the viscosity, adhesive peel strength, and adhesive cross section were measured using a rotational rheometer, a tensile tester(UTM), and a field emission scanning electron microscopy(FE-SEM). The thermal stability and heat resistance were confirmed by measuring the mass loss according to the temperature increase using Thermogravimetric analysis(TGA). After blending with epoxy and Phenolic resin(1:0.25 ratio) curing at 110℃ for 10 min, high adhesive strength was improved more than 40% compared to the adhesive strength using epoxy alone. When the space between the silicon steel sheet and m-aramid sheet, which is created during curing of the E-P blend, is cured with a slight weight, it is possible to control the empty space and improve adhesion.

• 보존과학회지
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• 제22권
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• pp.77-86
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• 2008

역사적으로 중요한 의의를 지니는 발굴 유적의 보존을 위한 사전 보호 조치가 반드시 필요하며 최근에 들어 이에 대한 대책으로 합성수지를 이용한 유적의 보존과 복원 작업에 대한 연구가 활발히 진행되고 있다. 그러나 위와 같은 역사적 발굴 유구의 보존을 위해 필수적으로 해결해야 할 문제점은 원형에 손상을 주지 않는 유구 이전재 사용, 유구의 토양에 따른 유구 이전재 선별 사용, 외부 환경(습지, 동절기, 온도)에 영향을 받지 않고 사용 가능하여야 한다. 본 연구에서 유구 이전 전용의 에폭시 resin 및 경화제는 우수한 접착 인장과 자체 인장을 갖으며, 사용자가 원하는 다양한 물성들을 갖고 있는 제품을 개발하고자 하였다. 특히, 본 연구는 그간 지속적인 문제점으로 대두되고 있는 우레탄 1차 전사 생성물과 Epoxy 최종생성물간의 박리 문제를 해결한 것이 특징으로 이를 위한 다양한 성분들의 유구 이전 복원제의 조성에 대하여 연구하였다.

• 한국기계가공학회지
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• 제19권7호
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• pp.67-73
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• 2020

Shrinkage is inevitable in the curing of resins during the nanoimprint process. The degree of shrinkage that occurs as the resin transforms from a viscous liquid to solid differs depending on the type of resin. However, if the cured material is repeatedly cured using the same material, constant shrinkage can be confirmed. In this study, the pattern of change was observed by repeatedly performing the nanoimprint process using a resin with a constant shrinkage rate. The observed pattern for the change of shape was made using a triangular pyramid-shaped aluminum master mold and a flexible replica mold made from the master. Shrinkage that results from the nanoimprint process occurs linearly in the longitudinal direction of the pattern and can be predicted by simple calculations. The change of the pattern due to shrinkage occurred as expected. If the shrinkage rate remains constant, various patterns can be manufactured with high accuracy by correcting these changes before producing a specific shape. This study confirms that the pattern of the desired angle can be obtained by performing the repeated imprint without having to manufacture a master mold.

• 한국전기전자재료학회논문지
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• 제30권12호
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• pp.751-756
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• 2017

A molding-type power inductor is an inductor that uses a hybrid material that is prepared by mixing a ferrite metal powder coated with an insulating layer and an epoxy resin, which is injected into a coil-embedded mold and heated and cured. The fabrication of molding-type inductors requires various techniques such as for coil formation and insertion, improving the magnetic properties of soft magnetic metal powder, coating an insulating film on the magnetic powder surface, and increasing the packing density by well dispersing the powder in the epoxy resin. Among these aspects, researches on additives that can disperse the metal soft magnetic powder having the greatest performance in the epoxy resin with high charge have not been reported yet. In this study, we investigated the effect of silanes, KBM-303 and KBM-403, and a commercial dispersant on the dispersion of metal soft magnetic powders in epoxy resin. The sedimentation height and viscosity were measured, and it was confirmed that the silane KBM-303 was suitable for dispersion. For this silane, the packing density was as high as about 72.49%. Moreover, when 1.2 wt% of dispersant BYK-103 was added, the packing density was about 80.5%.

• 한국응용과학기술학회지
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• 제20권1호
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• pp.8-19
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• 2003

Environmental friendly acrylics/urea high-solid paints (BEHCU) were prepared through the curing reaction of acrylics resin(BEHC) containing 70wt% of solids content and butylated urea curing agent. BEHC was synthesized by addition copolymerization of caprolactone acrylate(CLA), 2-hydroxypropyl methacrylate(2-HPMA), ethyl methacrylate, and n-butyl acrylate. The addition polymerization of these monomers, especially including flexible CLA monomer and 2-HPMA monomer with OH funtional group, under appropriate reaction conditions resulted in polymers with controlled glass transition temperature($T_g$) and crosslinking density. The molecular weight($M_w$) of these polymers(BEHCs) was 2940${\sim}$3240 and polydispersity ($M_w/M_n$) was in the range of 1.61${\sim}$1.72. The viscosity and the molecular weight of these acrylic resins increased with increasing $T_g$. The coated films were prepared using curing reaction between BEHC resin and butylated urea curing agent at 100$^{\circ}C$ for 30 minutes. Our experimental resulted showed that enhancement of the coating properties such as adhesion, flexibility, impact resistance, water resistance, and abrasion resistance could be expected through introducing CLA component in acrylic resin for the high-solid content acrylics/urea coatings.

• 폴리머
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• 제34권1호
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• pp.52-57
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• 2010

고 신뢰도와 높은 물성을 갖는 이방성 전도성접착제(anisotropic conductive adhesive, ACA)용 레진 개발을 위하여, 환원특성을 갖는 카르복실산을 포함한 bisphenol F계열의 에폭시 레진에 저융점 솔더입자(low melting point alloys, LMPA)를 분산시켜 제조하였다. LMPA의 융점에서의 에폭시 레진의 경화특성 및 온도에 따른 유변학 특성을 동적 시차 주사 열량계(differential scanning calorimeter, DSC)와 레오미터(rheometer)로 측정하여 최적화된 ACA 접합 공정을 설계하였다. 접합 공정시 LMPA 표면에 생성되는 산화막을 제거하여 높은 전기전도도와 안정적인 전기적 특성을 얻을 수 있도록 세가지 종류의 카르복실산을 환원제로 사용하여 각각의 젖음(wetting) 특성을 확인하였다. 부틸 카르복실산은 $28^{\circ}$의 낮은 젖음각을 나타내었으나, 경화반응 중 다량의 기포가 발생하는 문제가 있었다. 그러나, 이관능성 카르복실산(1,3-bis(2-carboxypropyl)tetramethyl disaoxane(2-CTMS)) 및 1,3-bis(3-carboxypropyl)tetramethyl disiloxane(3-CTMS))의 경우, 기포의 발생 없이 각각 $18^{\circ}$와 $20.3^{\circ}$의 매우 우수한 젖음 특성을 보였다.