• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.307-311
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• 2004

The unsaturated zone is a significant pathway of the surface contaminant movement and is a highly heterogeneous medium. Therefore, there are limitations in applying conventional convection-dispersion equation(CDE). Artificial neural network(ANN) is considered to be a versatile tool for approximating complex functions. For evaluating the applicability of ANN, numerical tests using ANN were conducted with training set generated by HYDRUS-2D which is based on CDE. The results represent that ANN can estimate the solute transport and the choice of network parameters and generation of training set patterns are important for efficient estimation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.10
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• pp.859-864
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• 2003

We prepared SOI(silicon-on-insulator) wafer pairs of Si II SiO$_2$/Si$_3$N$_4$ II Si using wafer direct bonding with an electric furnace annealing(EFA), a fast linear annealing(FLA), and a rapid thermal annealing(RTA), respectively, by varying the annealing temperatures at a given annealing process. We measured the bonding area and the bonding strength with processes. EFA and FLA showed almost identical bonding area and theoretical bonding strength at the elevated temperature. RTA was not bonded at all due to warpage, We report that FLA process was superior to other annealing processes in aspects of surface temperature, annealing time, and bonding strength.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.287-291
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• 2003

To delineate the internal structures of alluvial aquifer, high resolution seismic and GPR methods were adopted in Buyeo Gunsu-Ri area. The result of seismic refraction survey shows the water table of the aquifer and the result of seismic reflection reveals the basement and somewhat dominant internal structures of alluvial aquifer. The internal heterogeneity due to variations in channel behavior can be delineated using GPR survey. GPR profiles for the point bar deposits near Buyeo county reveals two different stratigraphic units the lower inclined heterogeneous strata and the upper horizontally stratified strata. According to the increase of demand for water resource using artificial recharge in alluvium, it is believed that the information acquired by high resolution geophysical methods will have an important roles for the effective and sustainable development and usage of groundwater in alluvial aquifer.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.317-317
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• 2011

Water dissociation on oxide surface has been researched in many fields because of its importance as fundamental phenomenas. MgO(001) is a good model system to understand heterogeneous catalysis, gas sensors, ground-water contaminants, and atmosphere chemistry. Over decades, ultrathin film of MgO on Ag(100) have attracted research activities thanks to its enhanced catalytic property. Correlation of the oxide and the metal, potential screening, charge fluctuation from interface reconstruction makes different energetics of hydroxylation of waters on film. We calculate the water-spliting energetics under the vacuum system.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.77.3-77.3
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• 2016

In our previous study, we showed that the peculiar globular cluster M22 contains two distinct stellar populations with different physical properties, having different chemical compositions, spatial distributions and kinematics. We proposed that M22 is most likely formed via a merger of two GCs with heterogeneous metallicities in a dwarf galaxy environment and accreted later to our Galaxy. In their recent study, Mucciarelli et al. claimed that M22 is a normal mono-metallic globular cluster without any perceptible metallicity spread among the two groups of stars, which challenges our results and those of others. We devise new strategies for the local thermodynamic equilibrium abundance analysis of red giant branch stars in globuar clusters and show there exists a spread in the iron abundance distribution in M22.

• Journal of the Korean Geophysical Society
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• v.6 no.4
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• pp.245-259
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• 2003

Two multichannel analysis of surface wave (MASW) surveys were conducted over a soil site in Tacoma Water's Green River Facility, Washington, where construction of a chemical treatment facility had been planned. The purpose of the surveys was to compare soil stiffness characterized by shear-velocity (Vs) distribution before and after Deep Dynamic Compaction (DDC) operation that was designed to improve the soil stiffness. Site soil consisted of very heterogeneous gravel and cobbles in a sand-and-silt matrix. Results from each survey are represented by two 2-D Vs maps delineating Vs variation of soil below the surveyed lines. One map was constructed from those dispersion curves that were analyzed with a significant amount of subjective judgment involved, whereas the other map was constructed from those dispersion curves analyzed with as much objective information as possible. Comparison of 2-D Vs maps indicates that Vs actually decreased after the DDC operations, possibly due to the loss (or reduction) of cohesive bonding between soil particles caused by the compaction operations.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1856-1860
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• 2012

$SnO_2/SiO_2$ nanocomposite has been synthesized by using sol-gel method. Prepared catalytic materials has been well characterized by using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmer-Teller (BET) surface area, and temperature-programmed desorption of ammonia ($NH_3$-TPD). $SnO_2/SiO_2$ nanocomposite catalyzed synthesis of 2-arylbenzothiazoles by the cyclocondensation of 2-aminothiophenol and aromatic aldehydes under reflux condition in 1:1 EtOH:$H_2O$. After completion of the reaction, catalyst can be recovered efficiently and reused with consistent activity.

• Journal of the Korean Electrochemical Society
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• v.9 no.3
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• pp.113-117
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• 2006

The electrochemical properties of the redox mediator, 2,2'-azinobis (3-ethylbenzothiazoline-6-sulfonate) ($ABTS^{2-}$) were studied using cyclic voltammetry. The measured potentials (${E^o}'$ vs SCE) of the two redox couples of ABTS are 0.45 V for $ABTS^{2-}/ABTS^{\cdot-}$ and 0.87 V for $ABTS^{\cdot-}/ABTS^0$. The rate constant for heterogeneous electron transfer and the diffusion coefficients for $ABTS^{2-}$ are $5x10^{-3}cm\;s^{-1}$ and $3.1x10^{-6}cm^2\;s^{-1}$, respectively. Our interest in $ABTS^{2-}$ stems from the fact that this molecule functions as a substrate to the copper oxidase, laccase, by providing the reducing equivalents necessary for the biocatalyzed reduction of dioxygen to water. Consequently, when laccase is tethered to an electrode surface or dissolved in solution, $ABTS^{2-}$ can be used to quantify enzyme activity electrochemically.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.81-84
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• 1988

The CO oxidation was performed on $H_2$-reduced NiO-${\alpha}-Fe_2O_3$ in the temperature range 150-$250^{\circ}C$. The kinetic study and the conductivity measurements indicate the oxidation reaction follows Langmuir-Rideal type process that is uncommon in heterogeneous catalyst$^1$. No active site is found on the catalyst surface for CO adsorption, but an oxygen vacancy adsorbs an oxygen, and this step is rate initiation. The partial orders are half for $O_2$ and first for CO, respectively. Apparent activation energy for over-all reaction is 9.05 kcal/mol.

• Bulletin of the Korean Chemical Society
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• v.15 no.7
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• pp.563-567
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• 1994

The electroreduction of dioxygen at glassy carbon electrodes with irreversible self-assembly of N-hexadecyl-N'-methyl viologen $(C_{16}VC_1)$ proceeds at potentials more positive than those where the reduction occurs at bare electrodes. The electrocatalyzed reduction takes place at potentials well ahead of those where the catalyst is reduced in the absence of dioxygen and the limiting currents observed at rotating disk electrodes did not deviate from the thoretical Levich line up to 6400 rpm, indicating that the electrocatalysis is extremely rapid. The rate constant for the heterogeneous reaction between $C_{16}V^+C_1$ immobilized on the electrode surface and $O_2$ in solution was estimated to be ca. $10^8\;M^{-1}s^{-1}$. The half-wave potential of dioxygen reduction was independent of solution pH.