• Title/Summary/Keyword: Heavy cu

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Stabilization of mixed heavy metals in contaminated marine sediment using steel slag (제강슬래그를 이용한 해양오염퇴적물 내 혼합 중금속 안정화)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.38 no.3
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    • pp.269-275
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    • 2014
  • In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using steel slag. Moreover, heavy-metal stabilization treatment of contaminated marine sediment was achieved using steel slag as stabilizing agents. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in steel slag. The adsorption uptake of heavy metals were higher in the order of $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$ > $Ni^{2+}$. The steel slage was applied for a wet-curing duration of 150 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Ni, Zn, Cu, Pb, and Cd in sediment decreased by 13.0%, 6.0%, 1.3%, 17.0%, and 50.0%, respectively.

Studies on Endpoints of Toxicological Evaluation of Heavy Metals in Brachinella kugenumaensis (카드뮴과 구리에 노출된 풍년새우의 생태독성)

  • Park, Ki-Yun;Lee, Dong-Ju;Lee, Chang-Hoon;Won, Du-Hee;Lee, Won-Choel;Kwak, Inn-Sil
    • Environmental Analysis Health and Toxicology
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    • v.24 no.3
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    • pp.241-249
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    • 2009
  • Heavy metal contaminants on the aquatic environment are of interest because they can have severe effects on economy and public health. Recently, the studies for monitoring of heavy metals try to do on aquatic system to assess safety and health of ecosystem by heavy metals. Thus, biological responses were investigated on Korean fairy shrimp Branchinella kugenumaensis exposed to cadmium (Cd) or copper (Cu) for long-periods (30 days). The survival rate decreased significantly (p<0.05) on B. kugenumaensis exposed to Cd and Cu at all concentrations. Especially, the highest decrease was observed at the relatively high concentration of Cd and Cu (p<0.01) and the response by Cd exposure was at dose-dependent. The growth rates were also decreased significantly (p<0.05) on B. kugenumaensis exposed to Cd and Cu for at all concentrations. Then, the reproduction rate, numbering cyst, was decreased significantly (p<0.01) on B. kugenumaensis after Cd or Cu exposures. Long exposure of the relatively high concentration Cd and Cu can have severe effects on the reproduction, while exposures of Cd and Cu can not have effects on sex ratios of B. kugenumaensis. Additionally, asymmetric telson deformity was only observed after Cd exposure. Therefore, these results suggest that B. kugenumaensis is a sensitive bio-indicator of heavy metal exposure and these biological responses of B. kugenumaensis give important information for long-term monitoring on aquatic ecosystem.

Riverbed Structures and Correlationships between Heavy Metals of Sediments in the Naktong River, Western Naktong River, and Suyoung Stream (낙동강, 서낙동강 및 수영천의 하상 구조와 저토중 중금속간의 상관성)

  • 황선출;이봉헌;박원우;이부용;박흥재
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.45-54
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    • 1998
  • The riverbed structures and heavy metal concentrations of the sediments in the Naktong River, Western Naktong River, and Suyoung Stream were investigated, and then the correlationships between heavy metals were examined. Naktong River was the deepest among the three streams. The deepest and the shallowest sites were site 11(11.58m) and 9(3.35m) in Naktong River, site 7(6.25m) and 4(2.06m) in Western Naktong River, add site 8(2.89m) and 1(0.61m) in Suyoung Stream, respectively. The mean concentration of Cd(45.79ppm) was higher in the sediment of Western Naktong River than in other two streams and those of Pb(76.25ppm), Cr(48.13ppm), and Cu(77.50ppm) were higher in the sediment of Suyovng Stream than in other two streams. The analytical results for correlationships between heavy metals showed that Cu was highly correlated with Cr and Pb was very highly correlated with Cr and Cu in Naktong River. Cu was relatively highly correlated with Cd and Cr and Cr was highly correlated with Pb in Western Naktong River Cd was relatively higlky correlated with Pb and Cu and Cr and Cd, Pb, Cu and Pb, Cr were highly correlated in Suyoung Stream.

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The Effects of Ni Addition in Cu Base Sintered Friction Material-Microstructure and Tribological Behavior

  • Chung, D.Y.;Kim, K.Y.;Lee, B.J.;Kim, J.G.
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.55-58
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    • 1995
  • The effects of Ni contents in Cu base sintered friction material were studied. The contents of Ni were increased up to 9 wt% in the Cu-Sn matrix. The microstincture and tribological behavior of the friction material were examined. Pin on disk type of constant speed friction test rig were used to measure the friction and the wear rates. The results show that Ni addition increased the friction coefficients and decreased the wear rates of the materials. Relations between microhardness of the matrix and friction properties have been discussed. In addition optimum Ni content is recommended through the analysis of wear debris.

The Effect of Weld Metal Copper Content on HAZ Cracking in Austenitic Stainless Steel welded with Al-brass

  • Lee, H.W.;Lee, J.S.;Choe, W.H.
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.152-154
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    • 2005
  • Austenitic stainless steel has good weldability but is sensitive to hot cracking such as solidification crack and liquation crack. In this study, the specimens of dissimilar metals made between austenitic stainless steel and Al-brass were welded by GTAW process using four different filler metals. Cracks were detected in the heat-affected zone of the stainless steel when welded with CuAl, CuSn and NiCu filler metals, but no cracks were detected a Ni filler metal was used. The cracks propagated along the grain boundary in the heat affected zone near the fusion line to base metal of 316L stainless steel. The cracks were located inside the weld bead with very fine hairline crack. All cracks initiated at the fusion line and moved forward in the base metal. From energy dispersion spectroscopy (EDS), Cu peak was detected only in the crack-opening area.

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A Study on the Reduction of Exposure Dose and Contrast Improvement by Use of Heavy Elements Filter (X선 진단영역에서 중원소(Ho) 여과판 사용에 따른 피폭선량 감소와 대조도 개선에 관한 연구)

  • Kim, Young-Keun
    • Journal of radiological science and technology
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    • v.23 no.1
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    • pp.91-96
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    • 2000
  • This work was on the reduction of exposure dose and contrast improvement by Use of Heavy Elements Filter From the result of experimental evaluation, it was found that the beam harding of X-ray was not showed in Ho and Gd, heavy elements filters, contrast to Cu and Al filters In which the harding showed. And the ratio of transit dose to surface dose and the load of X-ray tube increase in order of Al, Cu, Gd and Ho, respectively. The contrast of X-ray images using the intensifying screen and the input phosphor showed the higher value in order of Cu, Al, Gd and Ho. Therefore, in the case of using contrast media and phosphor in region of diagnostic radiology, X-ray image quality depends primarily on kVp and heavy elements filters.

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석회석을 활용한 광미와 폐석의 Cd, Cu, Pb 및 Zn의 제거

  • Ji Han-Gu;Jeong Myeong-Chae;Jeong Mun-Yeong;Choi Yeon-Wang;Lee Mun-Hyeon;Lee Jae-Yeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.20-23
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    • 2005
  • The objective of this study is to examine a stabilized efficiency of heavy metals including Cd, Cu, Pb and Zn using slaked lime. Tailings from the Janggun Pb-Zn mine, the second Yeonhwa Pb-Zn mine, the Jisi Au-Ag mine and the Sangdong W mine were sampled and measured heavy metal concentrations contents using AAS as various extraction methods. During 156 hours, column test were undertaken to evaluate the possibility of stabilization by slaked lime. The result shows that $Ca(OH)_2$ has a good efficiency in heavy metal stabilization, especially at the Jisi mine with stabilized efficiencies of 97%(Cd), 99%(Cu), 86%(Pb) and 99%(Zn), respectively.

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우리나라 토양의 중금속 배경농도 및 특성 조사

  • Kim Dong-Ho;Kim Tae-Seung;Yun Jeong-Gi;Jeon Seong-Hwan;Jeong Il-Rok;Kim Jong-Ha
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.6-8
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    • 2005
  • The forest soils of 92 sites in Korea were analyzed to survey heavy metal background levels using aqua regia digestion method and 0.1N HCl extraction method. From these results, the average natural contents of heavy metals were Cd 0.287, Cu 15.26, Pb 18.43, Cr 25.36, Zn 54.27, Ni 17.68mg/kg for aqua regia method, and Cd 0.040, Cu 0.48, Pb 3.06, Cr 0.09, Zn 1.54, Ni 0.27mg/kg for 0.1N HCl extraction method. The range of correlation coefficients between heavy metal contents obtained from two methods(aqua regia and 0.1N HCl) was significant as $0.24{\sim}0.88$, and the correlation coefficients were decreased in order of Cd, Pb, Cu, Ni, Cr, Zn.

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Contamination Characteristics of Heavy Metals in Indoor, Outdoor and Playground of Schools in the Gochang-Gun, Chonbuk Province of South Korea (전북 고창지역 학교 실내외 환경의 중금속 오염 특성)

  • Kim, Yong-Hwan;Chung, Duk-Ho;Cho, Kyu-Seong
    • Journal of the Korean earth science society
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    • v.27 no.1
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    • pp.73-82
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    • 2006
  • Dust samples were collected from 10 middle and high schools in the Gochang-Gun, Korea. Heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cu, Pb and Zn in indoor's dusts were highly concentrated. Also concentrations of Cu, Ni, Pb and Zn in outdoor's dusts were highly concentrated. Concentrations of Cd, Cu and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools and high schools located in Jeonju-city, Korea. Compared with concentrations of heavy metals in soils and dusts in Korea, the environment of indoor and outdoor of classroom is highly concentrated except for Cu, Zn. The concentrations of playground is less than that of residential dust and main road dust and playground in Jeonju-city. Playground dusts in 1 school exhibited the enhanced heavy metal pollution with a pollution index (Kloke, 1979) greater than 1.0, but indoor and outdoor dusts in 7 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) yester than 1.0.

Studies on Removal of Water Pollutants by Aquatic Plants II. Removal of Water Polluted Nutrients and Heavy Metals by Water Hyacinth (수생식물(水生植物)을 이용(利用)한 수질오염원제거(水質汚染源除去)에 관(關)한 연구(硏究) - 제2보(第2報) 부레옥잠의 영양염류(營養鹽類) 및 중금속(重金屬) 제거효과(除去效果))

  • Lee, Kyu-Seung;Kim, Moon-Kyu;Pyon, Jong-Yeong;Lee, Jong-Sik
    • Korean Journal of Weed Science
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    • v.5 no.2
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    • pp.149-154
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    • 1985
  • Removal of water pollutants by water hyacinth was examined with two nutrients, $NO_3$-N, $PO_4$-P and four heavy metals, Cu, Pb, Cd, Cr under laboratory conditions. $NO_3$-N was reduced to 0.7, 0.9 and 1.2 ppm, and 0.1, 0.2 and 0.5 ppm in $NO_4$-P from 10, 25 and 50 ppm 3 days after treatment, respectively. Among heavy metals Cu and Pb were removed faster and higher than Cd and Cr and also amount of heavy metals absorbed by water hyacinth was higher in the order of Cu > Pb > Cr > Cd. Distribution of heavy metals in this plant was higher in roots than in leaves and amount absorbed in roots was related to the treated concentrations. The harmful effect on growth of water hyacinth was observed in Cu and Cd.

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