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http://dx.doi.org/10.5394/KINPR.2014.38.3.269

Stabilization of mixed heavy metals in contaminated marine sediment using steel slag  

Shin, Woo-Seok (Institute of Marine Science and Technology Research, Hankyong National University)
Kim, Young-Kee (Department of Chemical Engineering, Hankyong National University)
Publication Information
Journal of Navigation and Port Research / v.38, no.3, 2014 , pp. 269-275 More about this Journal
Abstract
In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using steel slag. Moreover, heavy-metal stabilization treatment of contaminated marine sediment was achieved using steel slag as stabilizing agents. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in steel slag. The adsorption uptake of heavy metals were higher in the order of $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$ > $Ni^{2+}$. The steel slage was applied for a wet-curing duration of 150 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Ni, Zn, Cu, Pb, and Cd in sediment decreased by 13.0%, 6.0%, 1.3%, 17.0%, and 50.0%, respectively.
Keywords
Steel Slag; Heavy metals; Adsorption; Stabilization; Capping Material; Marine Contaminated Sediment;
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Times Cited By KSCI : 5  (Citation Analysis)
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1 Kim, D. H. and Yim, S. B.(2012), "Removal characteristics of heavy metals in acid wastewater by ceramics using natural zeolite and coverter slag", Joural of KSEE, Vol. 34, No. 4, pp. 239-246.   과학기술학회마을   DOI   ScienceOn
2 Duan, J. and Su, B.(2014), "Removal characteristics of Cd(II) from acidic aqueous solution by modified steel-making slag, Chem. Eng. J., Vol. 245, pp. 160-167.
3 Hatje, V., Payne, T.E., Hill, D.M., McOrist, G., Birch, G.F. and Sztmczak, R.(2003), "Kinetics of trace element uptake and release by particles in estuarine waters: effects of pH, salinity, and particle loading", Environ. Inter., Vol. 29, pp. 619-629.   DOI   ScienceOn
4 Hyun, J. H. and Kim, M. G.(1997), "Heavy metal removal from a synthetic wastewater by steel slag & steel sludge", Journal of KSEE, pp.82-84.
5 Liu, S. Y., Gao, J., Yang, Y. J., Yang, Y. C. and Ye, Z. X.(2010), "Adsorption intrinsic kinetics and isotherms of lead ions on steel slag", J. Hanzard. Mater., Vol. 173, pp. 558-562.   DOI   ScienceOn
6 Ministry of Land, Transport and Maritime Affairs, MLTMA(2010), Guidance for Remediation.Restoration of marine contaminated sediment.
7 Misak, N.Z., Ghoneimy, H.F. and Morcos, T.N.(1996), "Adsorption of $Co^{2+}$ and $Zn^{2+}$ ions on hydrous Fe(III), Sn(IV), and Fe(III)/Sn(IV) oxides", J. Coll. Inter. Sci., Vol. 134, pp. 31-43.
8 Na, C. K., Han, M. Y. and Park, H. J.(2011), "Applicability of theoretical adsorption models for studies on adsorption properties of adsorbents(I)". Journal of KSEE, Vol. 33, No. 8, pp. 606-616.   과학기술학회마을   DOI   ScienceOn
9 National Oceanic and Atmospheric Administration, NOAA(1999), "Sediment quality guidelines developed for the national status and trends program", http://ccma.nos.noaa.gov/publications/sqg.pdf.
10 Park, G.O. and Jun, S.H.(2008), "Chemical forms and release potential of heavy metals from the lime treated sediments", Korean J. Limnol., Vol. 41, pp. 166-173.   과학기술학회마을
11 Port and Airport Research Institute, PARI(2010), Management of hazardous chemicals in port and harbor sediment, Technical note of the Port and Airport Research Institute (No.1219).
12 Shin, W. S. and Kim, Y. G.(2013), "Removal characteristics of mixed heavy metals from aqueous solution by recycled aggregate as construction waste". Journal of KSMEE, Vol.16, No. 2, pp. 115-120.   과학기술학회마을   DOI   ScienceOn
13 Weber, J. and Miller, C. T.(1989), Organic chemical movement over and through soil, In: sawhney, B.L., Broen, K. (ed) Reactions and movement of organic chemical, Soil Sciences, American Madison, pp. 305-334.
14 USEPA(2005), Contaminated sediment remediation guidance for hazardous waste sites.
15 Wang, S., Peng, X., Tang, L., Lu, Z. and Lan, C.(2014), "Influence of inorganic admixtures on the 11 A-tobermorite formation prepared from steel slags: XRD and FTIR analysis", Construction and Building Materials, Vol. 60, pp.42-47.   DOI   ScienceOn
16 Ahmaruzzaman, M.(2011), "Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metal", Adv. Colloid Interface Sci., Vol.166, pp. 36-59.   DOI
17 Weng, C. H. and Huang, C. P.(1994), "Treatment of metal industrial waste water by fly ash and cement fixation". J. Environ. Eng., Vol. 120, No. 6, pp. 1470-1487.   DOI   ScienceOn
18 Xue, Y., Hou, H. and Zhu, S.(2009), "Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag", J. Hazard. Mater., Vol. 162, pp. 391-401.   DOI   ScienceOn
19 Yang, Z., Lin, Q., Lu, S., He, Y., Liao, G and Ke, Y.(2014), "Effect of CaO/$SiO_2$ ratio on the preparation and crystallization of glass-ceramics from copper slag", Ceramics International, Vol. 40, pp. 7297-7305.   DOI   ScienceOn
20 Choi, I. W., Kim, S. U., Seo, D. C., Kang, B. H., Sohn, B. K., Rim, Y. S., Heo, J. S. and Cho, J. S.(2005), "Biosoroption of heavy metals by biomass of seaweeds, Laminaria species, Ecklonia stolonifera, Gelidium amansii and Undaria pinnatifida". Korean Journal of Environmental Agriculture, Vol. 24, No. 4, pp. 370-378.   과학기술학회마을   DOI
21 Tessier, A., Camphell, P.G.C. and Bisson, M.(1979), "Sequential extraction procedure for the speciation of particulate trace metals", Anal. Chem., Vol. 51, 844-851.   DOI   ScienceOn
22 Chen, G.Z. and Fray, D.J.(2001), "Cathodic refining in molten salts: Removal of oxygen, sulfur and selenium from static and flowing molten copper", J. Appl. Electrochem., Vol. 31, pp. 155-164.   DOI   ScienceOn