• Title/Summary/Keyword: HS-GC-MSD

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Survey on the Use of Hand Sanitizer and Component Analysis (손소독제 사용 실태 조사 및 성분 분석)

  • Yoon, Hye-Kyung;Lee, Eun-Ji;Hur, Ye Lim;Park, Na-Youn;Kho, Younglim
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.702-709
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    • 2020
  • Objectives: Hand sanitizer is made with ethyl alcohol as the main ingredient. Problems related to the use of hand sanitizers and cases of harm caused by the use of hand sanitizers are occurring. This study investigated the usage behavior and recognition level of people using hand sanitizer and identified the chemical components listed in the component label of hand sanitizer. In addition, the methanol and isopropanol contained in hand sanitizer were quantified using HS-GC-MSD. Methods: The investigation of the behavior and recognition of hand sanitizer usage was conducted through a survey of 143 college students and adults. The components marked on 34 types of hand sanitizers were investigated, and methanol and isopropanol concentrations were analyzed using the HS-GC-MSD method. Results: According to the survey, 57% of respondents use hand sanitizers two to three times per day, 92.3% of them do so when in public places and 41.3% of them do so at home. Ethanol, purified water, carbomer, glycerin, and triethanolamine were the ingredients listed in the hand sanitizer. Among the 34 samples, methanol and isopropyl alcohol were detected in 33 samples, the concentration range for methanol was ND-567 ppm, and the concentration range of isopropyl alcohol was ND-2121 ppm. Conclusion: The results of this study have shown that hand sanitizers are being used constantly every day, and methanol, which is not included in the marked content, was detected in a significant concentration compared to wet tissue. It has been found that maintenance of hand sanitizer manufacturing standards and training on how to use them are needed.

Analysis of Blood Toluene and Butane in Death Cases of Inhalant Abusers (사망사고 관련된 유해화학 물질 남용자들의 혈액 중 톨루엔과 부탄의 분석)

  • Kim, Nam-Yee;Yang, Young-Geun;Chung, Hee-Sun;Park, Sung-Woo
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.577-582
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    • 1999
  • The blood toluene concentration was determined by using the GC/MSD with HS-SPME technique in postmortem blood, quantitatively. Butane gases was analyzed by using the GC/FID with HS technique in postmortem blood, qualitatively. Seventy five cases of dead associated with inhalation of glue or butane gases happened in Korea for the last 3 years (1996-1998). In 27 cases of deah due to glue sniffing, nine persons died as a result of a fall while intoxication and their blood tolucne concentration was fairly high in the range of $1.3{\sim}21.6{\mu}g/mL$. In case of death due to butane sniffing, fifty four persons died of acute butane gases inhalation or suffocation, and 6 persons died of butane gases as well as glue inhalation.

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Thermal Changes of Aroma Components in Soybean Pastes (Doenjang) (된장 가열조리 시 생성되는 향기성분 변화)

  • Lee, Seung-Joo;Ahn, Bo-Mi
    • Korean Journal of Food Science and Technology
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    • v.40 no.3
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    • pp.271-276
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    • 2008
  • In this study, volatile compounds were isolated from traditional and commercial fermented soybean pastes according to different heating temperatures (room temperature, $50^{\circ}C$, $100^{\circ}C$) using headspace-solid phase microextraction (HS-SPME). The compounds were then analyzed by gas chromatography-mass spectrometry (GC-MS). A total of 51 volatile components, including 18 esters, 3 alcohols, 6 acids, 8 pyrazines, 5 volatile phenols, 6 aldehydes, and 5 miscellaneous compounds, were identified. Esters and acids such as ethyl hexadecanoate, acetic acid, and 2/3-methyl butanoic acid were the largest groups among the quantified volatiles. By applying principal component analyses to the GCMS data sets, differences were observed in the volatile components of the soybean pastes as to the different heating temperatures. A large variation was shown between the volatile components of the traditional and commercial soybean pastes by increasing the heating temperature. Commercial samples had significantly higher levels of longer chain ethyl esters, aldehydes, and thermal degradation products such as maltol and 2-acetyl pyrrole, while traditional samples showed higher concentrations of acids and pyrazines.

Volatile Compounds of Elsholtzia splendens (꽃향유의 휘발성 향기성분)

  • Lee, So-Young;Chung, Mi-Sook;Kim, Mi-Kyung;Baek, Hyung-Hee;Lee, Mi-Soon
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.339-344
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    • 2005
  • Volatile compounds, isolated from Elsholtzia splendens using simultaneous steam distillation extraction (SDE) and headspace solid phase microextraction (HS-SPME), were analyzed by gas chromatography/mass spectrometry(GC-MS). Twenty-nine compounds, comprising 3 aldehydes, 7 alcohols, 11 hydrocarbons, 5 ketones, and 3 miscellaneous ones, were tentatively identified from volatile compounds of Elsholtzia splendens flowers. From leaves, 30 compounds, comprising 3 aldehydes, 6 alcohols, 11 hydrocarbons, 6 ketones, and 11 miscellaneous ones, were tentatively identified. Volatile compounds extracted by HS-SPME in E. splendens flowers were 3 alcohols, 18 hydrocarbons, 3 ketones, and 2 miscellaneous ones. In leaves, 31 compounds, comprising 7 alcohols, 15 hydrocarbons, 7 ketones, and 2 miscellaneous ones, were tentatively identified. Major volatile compounds identified by SDE and HS-SPME were naginataketone and elsholtziaketone, which were identified as aroma-active compounds, representing characteristic aroma of E. splendens.

Comparison of Analytical Methods for Volatile Flavor Compounds in Leaf of Perilla frutescens

  • Kim, Kwan-Su;Ryu, Su-Noh;Song, Ji-Sook;Bang, Jin-Ki;Lee, Bong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.2
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    • pp.154-158
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    • 1999
  • Volatile flavor compounds from perilla leaves were extracted and analyzed with different methods, head-space analysis (HS), simultaneous steam distillation and extraction (SDE) , and solvent extraction (SE), and to compare their efficiencies for quick analysis. Over 30 volatile compounds were isolated and 28 compounds were identified by GC/MSD. Major compound was perillaketone showing the compositions of which were 92% in SDE method, 86% in headspace analysis, and 62% in solvent extraction method. For quick evaluation of leaf flavor in perilla, it was desirable because the headspace analysis method had a shorter analyzing time and smaller sample amount than the other methods.

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Distribution of Antifouling Agent Using Headspace Solid Phase Microextraction(HS-SPME) Method in Southwestern Coast of Korea (HS-SPME법을 이용한 한국 서남해 연안 해역에서의 방오제 분포 특성)

  • Han, Sang-Kuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.85-93
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    • 2012
  • We study on the distribution characteristics of antifouling agents such as Sea-nine 211, Irgarol 1051, Diuron using HS-SPME method in southwestern coast of Korea. Short half-life of Sea-nine 211 was distributed in very low concentrations and/or below detection limits in all of the sampling points, both water and sediments samples. Irgarol 1051 was detected to have the highest concentration respectively $6.98{\mu}g/L$, 28.50 ng/g-dry wt in the seawater and sediments, and regional distribution characteristics did not appeared. Strong bioaccumulation and long half-life of Diuron was distributed higher concentration than in all sampling point and was analyzed to have the highest concentration(3882.22 ng/g-dry wt) Mo7(Mokpo)'s sediment. Irgarol 1051 and Diuron distributed in the shipbuilding industry and ship marina are located just at the point to found in high concentrations. In addition, the distribution of the antifouling agent materials were lower in concentration than in inner bay to outter bay in sediments. Antifouling agent materials from these results were contaminated high potential from port and shipbuilding industry located in inner bay.

Characteristics of Antimicrobial Organic Acids Produced by lactobacillus pentosus K34 isolated from Small Intestines of Korean Native Chickens (한국토종닭 소장에서 분리한 Lactobacillus pentosus K34가 생산하는 항균성 유기산의 특성)

  • Lee, Jae-Yeon;Hwang, Kyo-Yeol;Kim, Geun;Sung, Soo-Il;Park, Young-Sik;Baek, Man-Jung;Kim, Kyung-Rye
    • Microbiology and Biotechnology Letters
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    • v.30 no.3
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    • pp.241-246
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    • 2002
  • Seven lactic acid bacteria showing highly inhibitory activities against Salmonella gallinarum, Staphylococcus aureus, and Escherichia coli were isolated from Korean native chickens. The inhibitory activities were insensitive to various pretenses indicating that the inhibitory substance is not proteinaceous. The culture broths seem to contain other inhibitory substances in addition to lactic acid. The metabolic profile of organic acids produced by Lactobacillus pentosus K34 was investigated by GC-MSD and 28 different organic acids were detected in the culture broth. Compared with the prominent lactic acid, acetic acid, formic acid, the thirdly most abundant phenyllactic acid showed high inhibitory activity against S. gallinarum. After pHs of the acids were adjusted to S, the inhibitory activities of lactic acid, acetic acid, formic acid against S. gallinarum were greatly reduced while the inhibitory activity of phenyllactic acid was unchanged. The inhibitory activity of the phenyllactic acid was specifically high against S. gallinarum and S. aureus but very low against yeast and mold.