• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.429-434
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• 2009

The OH($X^2{\Pi},\;{\nu}$"=0, 1) internal state distributions from the reaction of electronically ground state oxygen atoms with HSi$Cl_3$ were measured using laser-induced fluorescence. The ground-state O$(^3P_J)$ atoms with kinetic energies above the reaction barrier were produced by photolysis of N$O_2$ at 355 nm. The OH product revealed strong vibrational population inversion, P(${\nu}$"=1)/P(${\nu}$"=0) = 4.0 ${\pm}$ 0.6, and rotational distributions in both vibrational states exhibit substantial rotational excitations to the limit of total available energy. However, no preferential populations in either of the two $\Lambda$ doublet states were observed from the micropopulations, which supports a mechanism involving a direct abstraction of hydrogen by the atomic oxygen. It was also found that the collision energy between O and HSi$Cl_3$ is effectively coupled into the excitation of the internal degrees of freedom of the OH product ($$ = 0.62, and $<\;f_{rot}>$ = 0.20). The dynamics appear consistent with expectations for the kinematically constrained reaction which supports the reaction type, heavy + light-heavy $\rightarrow$ heavy-light + heavy (H + LH′ $\rightarrow$ HL + H′). The dynamics of oxygen atom collision with HSi$Cl_3$ are discussed in comparison to those with Si$H_4$.

• Bulletin of the Korean Chemical Society
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• 제18권12호
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• pp.1274-1280
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• 1997

The photodissociation dynamics of CH2I2 has been studied at 304 nm by state-selective photofragment translational spectroscopy. Velocity distributions, anisotropy parameters, and relative quantum yields are obtained for the ground I(2P3/2) and spin-orbit excited state I*(2P1/2) iodine atoms, which are produced from photodissociation of CH2I2 at this wavelength. These processes are found to occur via B1 ← A1 type electronic transitions. The quantum yield of I*(2P1/2) is determined to be 0.25, indicating that the formation of ground state iodine is clearly the favored dissociation channel in the 304 nm wavelength region. From the angular distribution of dissociation products, the anisotropy parameters are determined to be β(I)=0.4 for the I(2P3/2) and β(I*)=0.55 for the I*(2P1/2) which substantially differ from the limiting value of 1.13. The positive values of anisotropy parameter, however, show that the primary processes for I and I* formation channels proceed dominantly via a transition which is parallel to I-I axis. The above results are interpreted in terms of dual path formation of iodine atoms from two different excited states, i.e., a direct and an indirect dissociation via curve crossing between these states. The translational energy distributions of recoil fragments reveal that a large fraction of the available energy goes into the internal excitation of the CH2I photofragment; < Eint > /Eavl=0.80 and 0.82 for the I and I* formation channels, respectively. The quantitative analysis for the energy partitioning of available energy into the photofragments is used to compare the experimental results with the prediction of direct impulsive model for photodissociation dynamics.

• Structural Engineering and Mechanics
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• 제20권6호
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• pp.655-672
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• 2005

Seismic random responses due to the wave passage effect are extensively investigated by using the pseudo excitation method (PEM). Two examples are used. The first is very simple but also very informative, while the second is a realistic suspension bridge. Numerical results show that the seismic responses vary significantly with wave speed, especially for low velocity or large span. Such variations are not monotonic, especially for flexible structures. The contributions of the dynamic and quasi-static components depend heavily on the seismic wave velocity and the natural frequencies of structures. For the lower natural frequency cases, the dynamic component has significant effects on the dynamic responses of the structure, whereas the quasi-static component dominates for higher natural frequencies unless the wave speed is also high. It is concluded that if insufficient data on local seismic wave velocity is available, it is advisable to select several possible velocity values in the seismic analysis and to choose the most conservative of the results thus obtained as the basis for design.

• 한국전기전자재료학회논문지
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• 제24권12호
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• pp.992-995
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• 2011

The optical properties of ZnO thin film, being treated by O-plasma, have been studied using Photoluminescence(PL) spectroscopy with the change of temperature from 10 K to 290 K. Two characteristic peaks were identified at 10 K : 3.357 eV($D^{\circ}X$) and 3.324 eV(TES). The peak of $D^{\circ}X$ is believed to be due to neutral donor bound excitons where the donor is in the ground state. However, the TES(Two Electron Satellite) peak indicates the excited state of the donor(excitation energy was ~30 meV). The donor binding energy was estimated to be 44 meV, which indicates the possible presence of the neutral donor bound excitons at RT. The thermal effect including thermal broadening was identified from temperature evolution of the spectrum. Both the peak intensity and the peak energy have decreased as the temperature increases. As the temperature approaches to RT, the two peak merges into one broad peak, which is considered a combination of multiple peaks having different physical origins.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2093-2098
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• 2013

Density functional theory (DFT) was used to determine the ground state geometries of indigo and new design dyes (IM-Dye-1 IM-Dye-2 and IM-Dye-3). The time dependant density functional theory (TDDFT) was used to calculate the excitation energies. All the calculations were performed in both gas and solvent phase. The LUMO energies of all the dyes were above the conduction band of $TiO_2$, while the HOMOs were below the redox couple (except IM-Dye-3). The HOMO-LUMO energy gaps of new design dyes were smaller as compared to indigo. All new design dyes were strongly red shifted as compared to indigo. The improved light harvesting efficiency (LHE) and free energy change of electron injection ${\Delta}G^{inject}$ of new designed sensitizers revealed that these materials would be excellent sensitizers. The broken coplanarity between the benzene near anchoring group having LUMO and the last benzene attached to TPA unit in all new design dyes consequently would hamper the recombination reaction. This theoretical designing will the pave way for experimentalists to synthesize the efficient sensitizers for solar cells.

• Smart Structures and Systems
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• 제16권5호
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• pp.807-833
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• 2015

While tuned mass dampers are found to be effective in suppressing vibration in a tall building, integrating it with a semi-active control system enables it to perform more efficiently. In this paper a forty-story tall steel-frame building designed according to the Canadian standard, has been studied with and without semi-active and passive tuned mass dampers. The building is assumed to be located in the Vancouver, Canada. A magneto-rheological fluid based semi-active tuned mass damper has been optimally designed to suppress the vibration of the structure against seismic excitation, and an appropriate control procedure has been implemented to optimize the building's semi-active tuned mass system to reduce the seismic response. Furthermore, the control system parameters have been adjusted to yield the maximum reduction in the structural displacements at different floor levels. The response of the structure has been studied with a variety of ground motions with low, medium and high frequency contents to investigate the performance of the semi-active tuned mass damper in comparison to that of a passive tuned mass damper. It has been shown that the semi-active control system modifies structural response more effectively than the classic passive tuned mass damper in both mitigation of maximum displacement and reduction of the settling time of the building.

• 한국유체기계학회 논문집
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• 제16권3호
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• pp.5-9
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• 2013

In this study, operational vibration experiment and analysis have been conducted for the 4-blade small vertical-axis wind turbine (VAWT) including the effect of tower elastic behavior. Computational structural dynamics analysis method is applied to obtain Campbell diagram for the VAWT with elastic tower. An open type wind-tunnel is used to change and keep the wind velocity during the ground test. Equivalent elastic tower is used to support the VAWT so that the effect of elastic stiffness of the tower can be considered in the present vibration experiment. Various excitation conditions with wind loads are considered and the dominant operating vibration phenomena are physically investigated in detail.

• 한국소음진동공학회논문집
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• 제21권9호
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• pp.858-867
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• 2011

As applying an active control technique to a pneumatic vibration isolation system, the settling time for the payload excitation could be remarkably reduced as well as the improvement of isolation performance for the ground vibration. Some previous researches were dealt with the settling time through the simulation or experiment but, the discussion on the simulation or experimental results including moving parts, such as a XY-stage, on the isolation table rarely exists. As considering the moving part, the dynamic model could be time varying system and in such a case the force imposed on pneumatic vibration isolation table could be described by inertial forces of moving parts according to Newton's 3rd law, the action and reaction law. In this paper, the simulation procedure of the 3-DOF active pneumatic vibration isolation system including moving parts by TDC(time delay control) technique is proposed and the effectiveness through simulation results are also shown.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2006년도 추계학술대회논문집
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• pp.893-897
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• 2006

Structures with additional frictional damping system have strong nonlinearity that the dynamic behavior is highly affected. by the relative magnitude between frictional force and excitation load. In this study, normalized response spectra of the structures with non-dimensional friction force are obtained through nonlinear time history analyses of the mass-normalized single degree of freedom systems using 20 ground motion data recorded on rock site. The variation of the control performance of frictional damping system is investigated in terms of the dynamic load and the structural natural period, of which effects were not considered in the previous studies. Least square curve fitting equations are presented for describing those normalized response spectrum and optimal non-dimensional friction forces are obtained for controlling the peak displacement and absolute acceleration of the structure based on the derivative of the curve fitted design spectrum.

• 전산구조공학
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• 제5권3호
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• pp.127-137
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• 1992

해양 가이드 타워를 대상으로 하여 지진하중에 대한 심해용 구조물의 비정상 거동해법에 대하여 연구하였다. 지반운동의 비정상 특성을 정상과정 성분에 시간포락함수가 곱해진 형태로 모형화하였으며, 구조물의 비정상 거동은 시간종속 분산함수로 구하였다. 지진의 시간포락함수와 정상과정 성분의 자기상관함수를 지수함수로 수식화하여 나타냄으로써, 구조물 거동의 시간종속 분산값을 해석적인 방법으로 구할 수 있는 기법을 개발하였다. 시간에 따른 거동의 분산값을 기본자료로 하여 지진의 발생기간 동안 예상되는 최대거동을 구하였으며, 이 값을 구조물 거동을 정상과정으로 가정하여 산정한 결과와 비교 분석하였다.