• Title/Summary/Keyword: Graphite powder

Search Result 244, Processing Time 0.025 seconds

Performance of carbon fiber added to anodes of conductive cement-graphite pastes used in electrochemical chloride extraction in concretes

  • Pellegrini-Cervantes, M.J.;Barrios-Durstewitz, C.P.;Nunez-Jaquez, R.E.;Baldenebro-Lopez, F.J.;Corral-Higuera, R.;Arredondo-Rea, S.P.;Rodriguez-Rodriguez, M.;Llanes-Cardenas, O.;Beltran-Chacon, R.
    • Carbon letters
    • /
    • v.26
    • /
    • pp.18-24
    • /
    • 2018
  • Pollution of chloride ion-reinforced concrete can trigger active corrosion processes that reduce the useful life of structures. Multifunctional materials used as a counter-electrode by electrochemical techniques have been used to rehabilitate contaminated concrete. Cement-based pastes added to carbonaceous material, fibers or dust, have been used as an anode in the non-destructive Electrochemical Chloride Extraction (ECE) technique. We studied the performance of the addition of Carbon Fiber (CF) in a cement-graphite powder base paste used as an anode in ECE of concretes contaminated with chlorides from the preparation of the mixture. The experimental parameters were: 2.3% of free chlorides, 21 days of ECE application, a Carbon Fiber Volume Fraction (CFVF) of 0.1, 0.3, 0.6, 0.9%, a lithium borate alkaline electrolyte, a current density of $4.0A/m^2$ and a cement/graphite ratio of 1.0 for the paste. The efficiency of the ECE in the traditional technique using metal mesh as an anode was 77.6% and for CFVF of 0.9% it was 90.4%, with a tendency to increase to higher percentages of the CFVF in the conductive cement-graphite paste, keeping the pH stable and achieving a homogeneous ECE in the mass of the concrete contaminated with chlorides.

Thermal Stability of Furfuryl Alcohol/Graphite Powder Mixtures for Impregnation of Carbonaceous Composite (탄화복합재료 함침을 위한 퍼퓨릴알콜/흑연분말 혼합물의 열안정성)

  • An, Yeong-Seok;Jo, Dong-Hwan
    • Korean Journal of Materials Research
    • /
    • v.8 no.4
    • /
    • pp.299-303
    • /
    • 1998
  • We examined, using thermoanalytical methods, the effects of $2000^{\circ}C$ heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnant but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30wt% graphite powders to furfuryl alcohol and the heating rate of $35^{\circ}C$/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above $1000^{\circ}C$ was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization-impregnation-cure-re-carbonization) required to densify a carbonaceous composite.

  • PDF

Fabrication and characterization of graphite nanofiber reinforced aluminum matrix composites (탄소나노섬유 강화 알루미늄 복합재료의 제조 및 특성)

  • Jang J.H.;Oh K.H.;Han K.S.
    • Proceedings of the Korean Society For Composite Materials Conference
    • /
    • 2004.10a
    • /
    • pp.35-38
    • /
    • 2004
  • Graphite nanofiber (GNF) and carbon nanotube (CNT) are novel fiber reinforcing materials which have outstanding physical and mechanical properties. Aluminum matrix composites reinforced graphite nanofiber were fabricated by conventional powder metallurgy (PM) method. The composites were prepared through ultrasonication, ball milling, and hot isostatic pressing. A uniform distribution of GNF in aluminum matrix could be obtained. To measure the mechanical properties of GNF-Al composites testings were done in indentation and compression. The compressive strength was enhanced according to reinforcing graphite nanofiber while the hardness was decreased. This study makes the high performance composites for future applications.

  • PDF

Electrical Resistivity of Natural Graphite-Fluorine Resin Composite for Bipolar Plates of Phosphoric Acid Fuel Cell(PAFC) Depending on Graphite Particle Size (인산형 연료전지 분리판용 천연흑연-불소수지계 복합재료의 흑연입도에 따른 전기비저항 변화)

  • Lee, Sang-Min;Beak, Un-Gyeong;Kim, Tae-Jin;Roh, Jae-Seung
    • Korean Journal of Materials Research
    • /
    • v.27 no.12
    • /
    • pp.664-671
    • /
    • 2017
  • A composite material was prepared for the bipolar plates of phosphoric acid fuel cells(PAFC) by hot pressing a flake type natural graphite powder as a filler material and a fluorine resin as a binder. Average particle sizes of the powders were 610.3, 401.6, 99.5, and $37.7{\mu}m$. The density of the composite increased from 2.25 to $2.72g/cm^3$ as the graphite size increased from 37.7 to $610.3{\mu}m$. The anisotropy ratio of the composite increased from 1.8 to 490.9 as the graphite size increased. The flexural strength of the composite decreased from 15.60 to 8.94MPa as the graphite size increased. The porosity and the resistivity of the composite showed the same tendencies, and decreased as the graphite size increased. The lowest resistivity and porosity of the composite were $1.99{\times}10^{-3}{\Omega}cm$ and 2.02 %, respectively, when the graphite size was $401.6{\mu}m$. The flexural strength of the composite was 10.3MPa when the graphite size was $401.6{\mu}m$. The lowest resistance to electron mobility was well correlated with the composite with lowest porosity. It was possible the flaky large graphite particles survive after the hot pressing process.

The Impact fracture Behaviors of Low Density LD Carbon/Carbon Composites by Drop Weight Impact Test (낙하 충격 시험에 의한 저밀도 2-D탄소/탄소 복합재의 충격파괴거동)

  • 주혁종;손종석
    • Polymer(Korea)
    • /
    • v.26 no.2
    • /
    • pp.270-278
    • /
    • 2002
  • In this study, the fracture behavior by low velocity impact damage and the tendencies of impact energy absorption were investigated. Low velocity impact tests were performed using a mini tower drop weight impact tester, and graphite powder, carbon black and milled carton fiber were chosen as additives. Addition of graphite powder increased the maximum load and maintained the stress long until the total penetration happened. At the content of 9 vol%, they showed the maximum of 42% improvement in impact strength compared composites containing no additives. At the test with low impact energy of 0.4 J, impact energy was consumed by delamination in the composite containing no additives, however, as graphite contents increased, the tendency of failure changed to the penetration of the specimen.

Development of Carbon Nanotubes and Polymer Composites Therefrom

  • Jain, P.K.;Mahajan, Y.R.;Sundararajan, G.;Okotrub, A.V.;Yudanov, N.F.;Romanenko, A.I.
    • Carbon letters
    • /
    • v.3 no.3
    • /
    • pp.142-145
    • /
    • 2002
  • Multiwall carbon nanotubes (MWNT) were produced using the arc-discharge graphite evaporation technique. Composite films were developed using MWNT dispersed in polystirol polymer. In the present work, various properties of the polymeric thin film containing carbon nanotubes were investigated by optical absorption, electrical resistivity and the same have been discussed.

  • PDF

An Experimental Study on the Exothermic Properties of Cement Mortar Containing Conductive Materials (전도성 재료를 혼입한 모르타르의 발열특성에 관한 실험적 연구)

  • Song, Dong-Geun;Hong, Chul-Ho;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2014.11a
    • /
    • pp.131-132
    • /
    • 2014
  • In this study, an experiment was carried out using graphite, conductive nickel powder, copper bar, carbon fiber for evaluate the exothermic properties and heating reproducibility of the cement mortar containing conductive material. As a result, the conductive materials that interfere with heating reproducibility are present, and the optimal conductive materials exist in each input voltage.

  • PDF

Study on Decarburization and Its Prevention of SM50C Steel Casted by the Ceramic Mold Process (세라믹 주형법에 의하여 주조된 SM50C 강의 탈탄과 그 방지에 관한 연구)

  • Lee, Seon-Ho;Lee, Kyong-Hwan;Kang, Choon-Sik
    • Journal of Korea Foundry Society
    • /
    • v.12 no.4
    • /
    • pp.298-304
    • /
    • 1992
  • Decarburization phenomena of SM50C steel casted in ceramic mold was investigated. As result, decarburized depth increased by increased by increasing the volume-to-surface area ratio and mold temperature. And the relations between them is $y(cm)=(1.96{\times}10^{-5}T+0.0135)\;{\times}M-1.05{\times}10^{-5}T+9.73{\times}10^{-3}$. When mold is controlled by Ar ags, reducing atmosphere, decarburized depth is decreased. In case of adding graphite powder in the mold, decarburization is decreased more. Specially, when graphite powder is added on the mold materials and the wax is layed on the mold, decarburization is almost prevented.

  • PDF

Effects of binder type and heat treatment temperature on physical properties of a carbon composite bipolar plate for PEMFCs

  • Kang, Dong-Su;Roh, Jea-Seung
    • Carbon letters
    • /
    • v.14 no.2
    • /
    • pp.110-116
    • /
    • 2013
  • This study investigated a developed process for producing a composite bipolar plate having excellent conductivity by using coal tar pitch and phenol resin as binders. We used a pressing method to prepare a compact of graphite powder mixed with binders. Resistivity of the impregnated compact was observed as heat treatment temperature was increased. It was observed that pore sizes of the GCTP samples increased as the heat treatment temperature increased. There was not a great difference between the flexural strengths of GCTP-IM and CPR-IM as the heat treatment temperature was increased. The resistivity of GPR700-IM, heat treated at $700^{\circ}C$ using phenolic resin as a binder, was $4829{\mu}{\Omega}{\cdot}cm$ which was best value in this study. In addition, it is expected that with the appropriate selection of carbon powder and further optimization of process we can produce a composite bipolar plate which has excellent properties.