• 한국세라믹학회지
• /
• 제53권3호
• /
• pp.376-380
• /
• 2016

A composite electrode made of iron oxide nanoparticles/multi-wall carbon nanotube (iNPs/M) delivers high specific capacity and cycle durability. At a rate of $200mAg^{-1}$, the electrode shows a high discharge capacity of ${\sim}664mAhg^{-1}$ after 100 cycles, which is ~ 70% of the theoretical capacity of $Fe_3O_4$. Carbon black, carbon nanotube, and graphene as anode materials have been explored to improve the electrical conductivity and cycle stability in Li ion batteries. Herein, iron oxide nanoparticles on acid treated MWCNTs as a conductive platform are combined to enhance the drawbacks of $Fe_3O_4$ such as low electrical conductivity and volume expansion during the alloying/dealloying process. Enhanced performance was achieved due to a synergistic effect between electrically 3D networks of conductive MWCNTs and the high Li ion storage ability of $Fe_3O_4$ nanoparticles (iNPs).

• Carbon letters
• /
• 제12권4호
• /
• pp.223-228
• /
• 2011

In this present work, the effect of additional heat-treatment (AHT) in the range from $1800^{\circ}C$ to $2400^{\circ}C$ on the chemical composition, morphology, microstructure, tensile properties, electrical resistivity, and thermal stability of commercial polyacrylonitrile (PAN)-based carbon fibers was explored by means of elemental analysis, electron microscopy, X-ray diffraction analysis, single fiber tensile testing, two-probe electrical resistivity testing, and thermogravimetric analysis (TGA). The characterization results were in agreement with each other. The results clearly demonstrated that AHTs up to $2400^{\circ}C$ played a significant role in further contributing not only to the enhancement of carbon content, fiber morphology, and tensile modulus, but also to the reduction of fiber diameter, inter-graphene layer distance, and electrical resistivity of "as-received" carbon fibers without AHT. The present study suggests that key properties of commercial PAN-based carbon fibers of an intermediate grade can be further improved by proprietarily adding heat-treatment without applying tension in a batch process.

• Composites Research
• /
• 제29권4호
• /
• pp.138-144
• /
• 2016

최근 유해한 전자파 문제에 대응하여 사용되는 전자파 차폐 물질에 대한 관심이 대두되고 있다. 우선, 전통적으로 사용되는 전도성이 높은 금속 기반 물질들이 있지만, 무겁고 부식성에 대한 한계가 있기에 이를 극복할 수 있는, 가볍고 기계적 강도가 우수하고, 부식에 대한 내구성이 있으며 전기 전도성이 높은 탄소계 물질들이 대두되었다. 탄소계 물질을 phase별로 나누어, 그래핀, CNT와 같은 1-phase 단일계 탄소계 물질부터 단일계 탄소물질에 금속이 추가되거나, 서로 다른 탄소계 물질이 혼합된 2-phase 탄소계 물질, 서로 다른 탄소계 물질에 기능성 금속이 추가된 3-phase 탄소계 물질순으로 각각의 특징을 소개하였다.

• 한국분말재료학회지
• /
• 제25권5호
• /
• pp.435-440
• /
• 2018

In the present study, we develop a conductive copper/carbon nanomaterial additive and investigate the effects of the morphologies of the carbon nanomaterials on the conductivities of composites containing the additive. The conductive additive is prepared by mechanically milling copper powder with carbon nanomaterials, namely, multi-walled carbon nanotubes (MWCNTs) and/or few-layer graphene (FLG). During the milling process, the carbon nanomaterials are partially embedded in the surfaces of the copper powder, such that electrically conductive pathways are formed when the powder is used in an epoxy-based composite. The conductivities of the composites increase with the volume of the carbon nanomaterial. For a constant volume of carbon nanomaterial, the FLG is observed to provide more conducting pathways than the MWCNTs, although the optimum conductivity is obtained when a mixture of FLG and MWCNTs is used.

• Nuclear Engineering and Technology
• /
• 제52권10호
• /
• pp.2387-2393
• /
• 2020

In this study, a gradient material for shielding neutrons and gamma rays was developed, which consists of epoxy resin, boron carbide (B₄C), lead (Pb) and a little graphene oxide. It aims light weight and compact, which will be applied on the transportable nuclear reactor. The material is made up of sixteen layers, and the thickness and components of each layer were designed by genetic algorithm (GA) combined with Monte Carlo N Particle Transport (MCNP). In the experiment, the viscosities of the epoxy at different temperatures were tested, and the settlement regularity of Pb particles and B₄C particles in the epoxy was simulated by matlab software. The material was manufactured at 25 ℃, the Pb C and O elements of which were also tested, and the result was compared with the outcome of the simulation. Finally, the material's shielding performance was simulated by MCNP and compared with the uniformity material's. The result shows that the shielding performance of gradient material is more effective than that of the uniformity material, and the difference is most noticeable when the materials are 30 cm thick.

• 멤브레인
• /
• 제26권5호
• /
• pp.351-364
• /
• 2016

최근 폴리아마이드 선택층에 나노물질을 혼합하여 해수담수화 성능을 높이고자 하는 연구가 활발히 이루어지고 있다. 본 총설은 역삼투 분리막 해수담수화 공정에서의 에너지 효율 향상을 위한 우수한 성능을 가진 폴리아마이드 기반 나노복합막을 소개하고자 한다. 그래핀 옥사이드 및 탄소나노튜브와 같은 탄소나노물질 및 제올라이트, 실리카 나노입자 등의 다양한 나노물질들이 기존 폴리아마이드의 투과분리성능을 높이기 위해 적용되고 있다. 본 총설에서는 최근 연구 중인 각 나노소재별 성능향상 특장점을 소개하고, 더 높은 성능을 갖는 나노복합막 제조를 위한 연구방향을 제시하고자 한다.

• Nano
• /
• 제13권11호
• /
• pp.1850135.1-1850135.8
• /
• 2018

A one-step high-temperature solvothermal approach to the synthesis of monolayer or bilayer $MoS_2$ anchored onto reduced graphene oxide (RGO) sheet (denoted as $MoS_2/RGO$) is described. It was found that single-layered or double-layered $MoS_2$ were synthesized directly without an extra exfoliation step and well dispersed on the surface of crumpled RGO sheets with random orientation. The prepared $MoS_2/RGO$ composites delivered a high reversible capacity of $900mAhg^{-1}$ after 200 cycles at a current density of $200mAg^{-1}$ as well as good rate capability as anode active material for lithium ion batteries. This one-step high-temperature hydrothermal strategy provides a simple, cost-effective and eco-friendly way to the fabrication of exfoliated $MoS_2$ layers deposited onto RGO sheets.

• Structural Engineering and Mechanics
• /
• 제76권5호
• /
• pp.561-578
• /
• 2020

The present work addresses the surface integrity and chip morphology in finish hard turning of AISI D3 steel under nanofluid assisted minimum quantity lubrication (NFMQL) condition. The surface integrity aspects include microhardness, residual stress, white layer formation, machined surface morphology, and surface roughness. This experimental investigation aims to explore the feasibility of low-cost multilayer (TiCN/Al2O3/TiN) coated carbide tool in hard machining applications and to assess the propitious role of minimum quantity lubrication using graphene nanoparticles enriched eco-friendly radiator coolant based nano-cutting fluid for machinability improvement of hardened steel. Combined approach of central composite design (CCD) - analysis of variance (ANOVA), desirability function analysis, and response surface methodology (RSM) have been subsequently employed for experimental investigation, predictive modelling and optimization of surface roughness. With a motivational philosophy of "Go Green-Think Green-Act Green", the work also deals with economic analysis, and sustainability assessment under environmental-friendly NFMQL condition. Results showed that machining with nanofluid-MQL provided an effective cooling-lubrication strategy, safer and cleaner production, environmental friendliness and assisted to improve sustainability.

• Steel and Composite Structures
• /
• 제37권6호
• /
• pp.695-709
• /
• 2020

The buckling properties of a single-layered graphene sheet (SLGS) are examined using nonlocal integral first shear deformation theory (FSDT) by incorporating the influence of visco-Pasternak's medium. This model contains only four variables, which is even less than the conventional FSDT. The visco-Pasternak's medium is introduced by considering the damping influence to the conventional foundation model which modeled by the linear Winkler's coefficient and Pasternak's (shear) foundation coefficient. The nanoplate under consideration is subjected to compressive in- plane edge loads per unit length. The impacts of many parameters such as scale parameter, aspect ratio, the visco-Pasternak's coefficients, damping parameter, and mode numbers on the stability investigation of the SLGSs are examined in detail. The obtained results are compared with the corresponding available in the literature.

• Journal of Electrochemical Science and Technology
• /
• 제14권3호
• /
• pp.231-242
• /
• 2023

Li₂O-based cathodes utilizing oxide-peroxide conversion are innovative next-generation cathodes that have the potential to surpass the capacity of current commercial cathodes. However, these cathodes are exposed to severe cathode-electrolyte side reactions owing to the formation of highly reactive superoxides (O^x-, 1 ≤ x < 2) from O^2- ions in the Li₂O structure during charging. Succinonitrile (SN) has been used as a stabilizer at the cathode/electrolyte interface to mitigate cathode-electrolyte side reactions. SN forms a protective layer through decomposition during cycling, potentially reducing unwanted side reactions at the interface. In this study, a composite of Li₂O and Ni-embedded reduced graphene oxide (LNGO) was used as the Li₂O-based cathode. The addition of SN effectively thinned the interfacial layer formed during cycling. The presence of a N-derived layer resulting from the decomposition of SN was observed after cycling, potentially suppressing the formation of undesirable reaction products and the growth of the interfacial layer. The cell with the SN additive exhibited an enhanced electrochemical performance, including increased usable capacity and improved cyclic performance. The results confirm that incorporating the SN additive effectively stabilizes the cathode-electrolyte interface in Li₂O-based cathodes.