• 제목/요약/키워드: Grad

검색결과 425건 처리시간 0.026초

종이 바이오매스의 열분해에서 니켈 촉매에 의한 수소제조특성 (Production of $H_2$ Gas in Pyrolysis of Paper Biomass using Ni-based Catalysts)

  • 최용근;차토패드히야제이타;김철호;김래현;손재익;박대원
    • 한국수소및신에너지학회논문집
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    • 제19권6호
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    • pp.514-519
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    • 2008
  • In the present study, biomass pyrolysis was done using five different kinds of catalysts with change in the support species and their compositions. Ni was loaded on alumina, ceria and alumina-ceria supports using co-precipitation method. In all the catalysts, 30wt% of nickel was loaded on the support materials. The paper used in daily writing purposes was taken into account as biomass sample. In the experiment, 19 of biomass was mixed with o.1g of each catalyst separately. Thermogravimetric analysis (TGA) was performed with all the catalysts diminished the initial degradation temperature of paper biomass sample considerably. During the pyrolysis process, the temperature was raised from room temperature to $800^{\circ}C$ with the heating rate of $10^{\circ}C$/min in the furnace. The cumulative $H_2$ volume had reached the best value of l4.02ml with the Ni/$Al_2O_3-CeO_2$ 30wt%/(50wt%-50wt%) catalysts. In presence of all the catalysts, the highest amount of $H_2$ was produced at $800^{\circ}C$, 10min. of residence time.

EPDM 가스켓의 장시간 운전에 따른 기계적 성능변화 (Mechanical Properties of EPDM Gasket after Long-Term Operations)

  • ;김선학;천승호;김진수;현덕수;김병헌;이성근;정재훈;지덕진;오병수
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.488-494
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    • 2011
  • Gasket plays an important role on sealing of the polymer electrolyte membrane fuel cell (PEMFC) stack. Stack requires gaskets in each cell to keep the hydrogen and air/oxygen within their respective regions. The failure of the gasket creates the problems of fuel leakage, mixing, damage on parts and can be a direct reason for the degrading the efficiency of fuel cell. The purpose of this paper researches on how mechanical properties of EPDM gasket in PEMFC are changed after long-term operations. The EPDM (ethylenepropylene-diene monomer) gaskets are obtained from the stack after long-term operations. DMA (dynamic mechanical analysis) is conducted to access the change of mechanical properties of the EPDM gasket. SEM/EDS (scanning electron microscope/energy dispersive spectroscopy) was used to show the surface topography and chemical characterization on the sample surface.

직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구 (An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell)

  • 안성율;이영훈;엄성용;성연모;문철언;강기중;최경민;김덕줄
    • 한국수소및신에너지학회논문집
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    • 제23권5호
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

Reproducibility Between two physicians of fMRI study on the Brain Activity Induced by Acupuncture (at BL62)

  • Yeo, S.;Kim, Y.;Choe, I.H.;Rheu, K.H.;Choi, Y.G.;Hong, Y.M.;Lim, S.
    • Korean Journal of Acupuncture
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    • 제26권2호
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    • pp.39-51
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    • 2009
  • 목적 : 신맥 혈위 자극이 뇌활성화 변화에 미치는 영향에 있어 자침 시술자간의 재현성을 fMRI 영상을 통해 평가하고자 하였다. 방법 : 본 연구는 건강한 성인 남자 15명을 대상으로 실시하였으며, 15명의 피험자 중 7명은 각각 2회 방문하였으며, 두 시술자에 의해 침을 맞고 총 4개의 데이터를 얻었다. 나머지 8명은 1회 방문하여 두 시술자에게 침을 맞아 2개씩의 데이터를 얻어 총 44개의 fMRI 데이터를 얻었다. 실험자간의 차이를 줄이기 위해 자침의 깊이와 회전, 강도 등을 동일하게 하였으며, 우측 신맥혈에 자침하였다. 침에 의해 활성화되는 영역을 확인하기 위해 블록디자인을 사용하여 fMRI를 촬영하였다. 결과 : 다른 날에 실시한 같은 시술자내의 재현성은 24 %, 같은 날 실시한 다른 시술자간의 재현성은 64 % 로, 다른 시술자간의 재현성이 서로 다른 날 실시한 같은 시술자내의 재현성보다 높게 나타났다. 결론 : 침을 이용한 fMRI의 실험에서 시술자에 의한 차이 외에도 실험하는 날짜의 차이, 피험자 인체의 생리적인 변화 등에 의한 차이가 크다는 것을 본 실험을 통하여 확인하였다. 그리고 자침의 깊이와 회전, 자극의강도 등을 동일하게 함으로써 다른 시술자간의 재현성을 높일 수 있다는 것을 확인했다. 추후 침실험에 있어서 여러 변수들에 의한 차이를 극복하고 재현성을 높일 수 있는 방법에 관한 더욱 심도 있는 연구가 필요하다.

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자유 피스톤 스털링엔진/발전기의 설계 인자 연구 (A Study on the Design of the Free-Piston Stirling Engine/Alternator)

  • 박성제;홍용주;고준석;김효봉;염한길;인세환;강인수;이청수
    • 한국수소및신에너지학회논문집
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    • 제25권6호
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    • pp.648-655
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    • 2014
  • This paper describes the continuing effort to develope a single acting free-piston Stirling engine/alternator combination for use of the household cogeneration. Free piston Stirling engines(FPSE) use variations of working gas pressure to drive mechanically unconstrained reciprocating elements. Stirling cycle free-piston engines are driven by the Stirling thermodynamic cycle which is characterized by an externally heated device containing working gas that is continuously re-used in a regenerative, reversible cycle. The ideal cycle is described by two isothermal process connected by two constant volume processes. Heat removed during the constant volume cooling process is internally transferred to the constant volume heating process by mutual use of a thermal storage medium called the regenerator. Since the ideal cycle is reversible, the ideal efficiency is that of Carnot. Free-piston Stirling engine is have no crank and rotating parts to generate lateral forces and require lubrication. The FPSE is typically comprised of two oscillating pistons contained in a common cylinder. The temperature difference across the displacer maintains the oscillations, and the FPSE operate at natural frequency of the mass-spring system. The power is generated from a linear alternator. The purpose of this paper is to describe the design process of the single acting free-piston Stirling engine/alternator. Electrical output of the single acting free-piston Stirling engine/alternator is about 0.95 kW.

무력정자증 환자에서 인간 난포액과 SpermGrad를 이용한 정자처리법의 비교 (Comparison between Human Follicular Fluid and SpermGrad for Sperm Preparation in Asthenozoospermia)

  • 정연경;이정렬;문정희;김현준;한상훈;지병철;구승엽;서창석;김석현;최영민;김정구;문신용
    • Clinical and Experimental Reproductive Medicine
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    • 제33권1호
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    • pp.53-60
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    • 2006
  • 목 적: 보조생식술에서의 정자처리법으로서 인간 난포액을 이용한 swim-down 방법의 유용성을 확인해 보고자 하였다. 연구방법: 분당서울대학교병원 산부인과에서 불임평가 목적으로 정액검사를 시행할 때 정자무력증 (asthenozoospermia, sperm motility < 50%)을 보이는 12명의 남성을 대상으로 하였다. 이들에서 검사 후 남은 정액을 100% 인간 난포액을 이용한 swim-down법과 SpermGrad를 이용한 밀도차 분리법을 적용하여 각각 처리하고 컴퓨터 정액분석기를 이용하여 정액검사를 시행하였다. 결 과: 두 군 모두에서 운동성과 빠른 운동성 정자의 비율, VCL (curvilinear velocity), ALH (amplitude of lateral head displacement)치 및 과활동성 정자의 비율이 통계적으로 유의하게 상승하였고 LIN (mean linearity)치는 유의하게 감소하였다. 100% 인간 난포액을 이용한 swim-down법에서 정자의 운동성이 SpermGrad를 이용한 밀도차분리법에 비하여 유의하게 높게 나타났으며 ($81.2{\pm}4.7$ vs. $67.6{\pm}2.3$, p=0.02), 다른 변수들은 두 군에서 차이를 보이지 않았다. 결 론: 100% 인간 난포액을 이용한 swim-down법은 정자무력증을 보이는 경우 유용한 정자 처리법으로 사료된다.