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Production of $H_2$ Gas in Pyrolysis of Paper Biomass using Ni-based Catalysts  

Choi, Yong-Keun (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Chattopadhyay, Jeeta (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Kim, Chul-Ho (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Kim, Lae-Hyun (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Son, Jae-Ek (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Park, Dea-Won (Grad. School of Energy and Environment, Seoul National Univ. of Technology)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.19, no.6, 2008 , pp. 514-519 More about this Journal
Abstract
In the present study, biomass pyrolysis was done using five different kinds of catalysts with change in the support species and their compositions. Ni was loaded on alumina, ceria and alumina-ceria supports using co-precipitation method. In all the catalysts, 30wt% of nickel was loaded on the support materials. The paper used in daily writing purposes was taken into account as biomass sample. In the experiment, 19 of biomass was mixed with o.1g of each catalyst separately. Thermogravimetric analysis (TGA) was performed with all the catalysts diminished the initial degradation temperature of paper biomass sample considerably. During the pyrolysis process, the temperature was raised from room temperature to $800^{\circ}C$ with the heating rate of $10^{\circ}C$/min in the furnace. The cumulative $H_2$ volume had reached the best value of l4.02ml with the Ni/$Al_2O_3-CeO_2$ 30wt%/(50wt%-50wt%) catalysts. In presence of all the catalysts, the highest amount of $H_2$ was produced at $800^{\circ}C$, 10min. of residence time.
Keywords
Catalyst; Biomass; Hydrogen; Pyrolysis; Paper;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
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