• Title/Summary/Keyword: Gold surfaces

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EFFECT OF CASTING PROCEDURE ON SCREW LOOSENING OF UCLA ABUTMENT IN TWO IMPLANT-ABUTMENT CONNECTION SYSTEMS

  • Ha, Chun-Yeo;Kim, Chang-Whe;Lim, Young-Jun;Kim, Myung-Joo
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.3
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    • pp.246-254
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    • 2008
  • STATEMENT OF PROBLEM: The cast abutment has advantages of overcoming angulation problem and esthetic problem. However, when a gold-machined UCLA abutment undergoes casting, the abutment surfaces in contact with the implant may change. PURPOSE: The purpose of this study was to compare the detorque values of prefabricated machined abutments with gold-premachined cast-on UCLA abutments before and after casting in two types of internal implant-abutment connection systems: (1) internal hexagonal joint, (2) internal octagonal joint. Furthermore, the detorque values of two implant-abutment connection systems were compared. MATERIALS AND METHODS: Twenty internal hexagonal implants with an 11-degree taper and twenty internal octagonal implants with an 8-degree taper were acquired. Ten prefabricated titanium abutments and ten gold-premachined UCLA abutments were used for each systems. Each abutment was torqued to 30 N㎝ according to the manufacturer's instructions and detorque value was recorded. The detorque values were measured once more, after casting with gold alloy for UCLA abutment, and preparation for titanium abutments. Group means were calculated and compared using independent t-test and paired t-test (${\alpha}$=0.05). RESULTS: The results were as follows: 1. The detorque values between titanium abutments and UCLA-type abutments showed significant differences in internal octagonal implants (P<0.05), not in internal hexagonal implants (P>0.05). 2. In comparison of internal hexagonal and octagonal implants, the detorque values of titanium abutments had significant differences between two connection systems on the initial analysis (P<0.05), not on the second analysis (P>0.05) and the detorque values of UCLA-type abutments were not significantly different between two connection systems (P>0.05). 3. The detorque values of titanium abutments and UCLA-type abutments decreased significantly on the second analysis than the initial analysis in internal hexagonal implants (P<0.05), not in internal octagonal implants (P>0.05). CONCLUSION: Casting procedures of UCLA-type abutments had no significant effect on screw loosening in internal implant-abutment connection systems, and UCLA-type abutments showed higher detorque values than titanium abutments in internal octagonal implants.

Bioelectrocatalyzed Signal Amplification for Affinity Interactions at Chemically Modified Electrodes

  • Hyun C. Yoon;Kim, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.9 no.2
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    • pp.107-111
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    • 2004
  • A comparative study was performed to evaluate the signal amplification strategies in electrochemical affinity sensing, which included the direct electron transfer and diffusible-group mediated electron transfer between label enzymes that were specifically bound to target proteins and chemically modified electrode surfaces. As a platform surface for affinity recognition reactions, a double functionalized poly(amidoamine) dendrimer monolayer that was modified with ferrocene and biotin groups was constructed on a gold surface. With the chemically modified electrode, a model affinity sensing with avidin was investigated. The advantages of adopting the diffusible-group mediated signaling strategy were demonstrated in terms of signal sensitivity and stability.

A Study on Space Charge of Organic Pentacene/metal Interface (유기물 Pentacene 박막과 금속 계면에서의 Space Charge 연구)

  • Yoon, Young-Woon;Babajayan, Arsen;Lee, Hoo-Neung;Kim, Song-Hui;Lee, Kie-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.41-46
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    • 2007
  • Surface potential properties at the interface of pentacene thin films on gold (Au) and aluminum (Al) surfaces were investigated by using a near-field scanning microwave microprobe (NSMM). The surface potential formed across the pentacene film was observed by measuring the microwave reflection coefficient $S_{11}$ and compared with the result of a Kelvin-probe method. The obtained reflection coefficient ${\Delta}S_{11}$ of the pentacene thin films on Al was decreased as the pentacene film thickness increased due to the increased accumulation of negative space charges, while for Au ${\Delta}S_{11}$ was essentially constant.

Nano-scale Au nanopaticles Pattern and Application by Using NSOM Lithography (근접상 주사 현미경(NSOM)을 이용한 금(Au)나노입자의 패터닝과 기술응용)

  • Huh K.S.;Chang W.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1539-1542
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    • 2005
  • Self-assembled monolayers (SAMs) formed by the adsorption of alkanethiols, $HS(CH_2)_nX$, where X is an organic functional group, onto gold surfaces have attracted widespread interest as templates for the fabrication of molecular and biomolecular microstructures. Previously photopatterning has been thought of as being restricted to the micron scale, because of the wellknown diffraction limit. So, we have explored a novel approach to nanofabrication by utilizing a femtosecond laser coupled to a near-field scanning optical microscope (NSOM).

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Influence of Unsteady Wake on Flow Characteristics and Heat Transfer from Linear Turbine Cascade (비정상후류가 선형터빈익렬의 유동 특성 및 익형의 열전달에 미치는 영향에 관한 연구)

  • Yoon, Soon-Hyun;Sim, Jae-Kyung;Lee, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.1061-1064
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    • 1998
  • To examine the influence of unsteady wake on the flow and heat transfer characteristics, an experiment has been conducted in a four-vane linear cascade. Flow and heat transfer measurements are made for the inlet Reynolds number of 66000(based on chord length and free-stream velocity). Turbulent intensity and stress were measured using hot wire anemometer, and to measure the convective heat transfer coefficients on the blade surfaces liquid crystal/gold film Intrex technique was used. The disturbance by the unsteady wake is characterized by the unresolved unsteadiness. The unsteady wake enhances the turbulent motion of flow in the cascade passage. It also promotes the boundary layer development and transition. The results show that heat transfer coefficients on the suction surface increase with increasing unresolved unsteadiness.

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A STUDY ON THE ELECTRICAL CHARACTERISTICS IMPROVEMENTS OF PENTACENE-BASED ORGANIC THIN FILM TRANSISTORS (Pentacene을 이용한 유기 TFT의 전기적 특성 향상에 관한 연구)

  • Lee, Jong-Hyuk;Park, Jae-Hoon;Ryu, Se-Won;Kim, Hyung-Joon;Choi, Jong-Sun
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1515-1517
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    • 2001
  • In this work the electrical characteristics of organic TFTs with the semiconductor-insulator interfaces have been interested. Pentacene is used as an active semiconducting layer. The semiconductor layer of pentacene was thermally evaporated in vacuum at a pressure of about $2{\times}10^{-6}$ Torr and at a deposition rate of 0.3$\AA$/sec. Aluminium and gold were used for gate and source/drain electrodes. before pentacene is deposited on the insulator, the gate dielectric surfaces of two samples were rubbed with lateral and perpendicular to direction of the channel length respectively.

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Control the Au(111) Work Function by Substituted Aromatic Thiol Self-Assembled Monolayers

  • Gang, Hun-Gu;Ito, Eisuke;Okabayashi, Youichi;Hara, Masahiko;No, Jae-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.243-243
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    • 2012
  • Self-assembled monolayers (SAMs) prepared by aromatic thiols on gold surfaces have much larger potential for electronic device applications due to their electronic properties. In this study, the formation and structures of SAMs prepared by benzenethiol (BT), toluenethiol (TT), 2-fluorobenzenethiol (2-FBT), 3-fluorobenzenethiol (3-FBT), 4-fluorobenzenethiol (4-FBT), 4-chlorobenzenethiol (4-CBT), 4-fluorobenzenemethanethiol (4-FBMT), and 4-chlorobenzenemethanethiol (4-CBMT) on Au(111) were examined using scanning tunneling microscopy (STM) and Kelvin probe (KP) to explore the structure and electronic interface properties of eight differently substituted aromatic thiol SAMs on Au(111). And these values are compared with gas phase dipole moments computed by quantum chemical calculations for individual thiol molecules. It was revealed that all eight thiol-molecules form uniform SAMs on Au(111) at $75^{\circ}C$ compared to lower solution temperature by STM observation. The work function change obtained in the KP measurements and calculated molecular dipole moments have the linear relationship while the 4-FBMT and 4-CBMT deviate from this tendency.

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Electronic Structures of Graphene Intercalated by Oxygen on Ru(0001): Scanning Tunneling Spectroscopy Study

  • Jang, Won-Jun;Jeon, Jeung-Hum;Yoon, Jong-Keon;Kahng, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.114-114
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    • 2011
  • Graphene is the hottest topic in condensed-matter physics due to its unusual electronic structures such as Dirac cones and massless linear dispersions. Graphene can be epitaxially grown on various metal surfaces with chemical vapor deposition (CVD) processes. Such epitaxial graphene shows modified electronic structures caused by substrates. In the method for removal of the effect of substrate, there are bi, tri-layer graphene, gold intercalation, and oxygen intercalation. Here, We will present the changes of geometric and electronic structure of graphene grown on Ru(0001) by oxygen intercalation between graphene and Ru(0001). Using Scanning tunneling microscopy (STM) and spectroscopy (STS), we observed the aspect that the band gap features near the fermi level of graphene on Ru(0001) system is shifted and narrow. Based on the observed results, two effects by intercalated oxygen were considered.

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A SCANNING ELECTRON MICROSCOPIC STUDY OF THE EFFICACY OF ROOT CANAL IRRIGATION (근관세척(根管洗滌)에 관(關)한 주사전자현미경적(走査電子顯微鏡的) 연구(硏究))

  • Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
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    • v.8 no.1
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    • pp.147-153
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    • 1982
  • The purpose of this study is to observe the effect of cleansing action of irrigation solutions which are 3% hydrogen peroxide, 5% sodium hypochlorite and 15% EDTA solution on the root canal wall. After the root canal wall is enlarged with K-file in distilled water, the canal wall which is irrigated with each irrigant for 2 minutes, is compared with the. control group without using any irrigants. Each sample is dehydrated, and coated with 200-250${\AA}$ of gold, and observations are made with the use of scanning electron microscope. The results are as follows: 1. The canal walls irrigated with 3% hydrogen peroxide, 5% sodium hypochlorite and 15% EDTA solution are cleaner than the walls without using irrigants. 2. There are no significant difference of cleansing effect among 3% hydrogen peroxide, 5% sodium hypochlorite and 15% EDTA. 3. After using 3% hydrogen peroxide and 5% sodium hypochlorite solution, large debris are removed on root canal walls, but micro debris remain on the canal walls. 4. The root canal walls irrigated with 15% EDTA solution are decalcifed slightly and show clean surfaces.

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Influence of Unsteady Wake on Flow Characteristics and Heat Transfer from Linear Turbine Cascade (비정상후류가 선형터빈익렬의 유동 특성 및 익혀의 열전달에 미치는 영향에 관한 연구)

  • Yoon, Soon-Hyun;Sim, Jae-Kyung;Lee, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.713-716
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    • 1998
  • To examine the influence of unsteady wake on the flow and heat transfer characteristics, an experiment has been conducted in a four-vane linear cascade. Flow and heat transfer measurements are made for the inlet Reynolds number of 66000(based on chord length and free-stream velocity). Turbulent intensity and stress were measured using hot wire anemometer, and to measure the convective heat transfer coefficients on the blade surfaces liquid crystal/gold film Intrex technique was used. The disturbance by the unsteady wake is characterized by the unresolved unsteadiness. The unsteady wake enhances the turbulent motion of flow in the cascade passage. It also promotes the boundary layer development and transition. The results show that heat transfer coefficients on the suction surface increase with increasing unresolved unsteadiness.

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