• Title/Summary/Keyword: Gas-phase Analysis

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Numerical Analysis of Plume Characteristics and Liquid Circulation in Gas Injection Through a Porous Plug

  • Choi, Choeng-Ryul;Kim, Chang-Nyung
    • Journal of Mechanical Science and Technology
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    • v.14 no.12
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    • pp.1365-1375
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    • 2000
  • Two phase flows have been numerically calculated to analyze plume characteristics and liquid circulation in gas injection through a porous plug. The Eulerian approach has been for formulation of both the continuous and dispersed phases. The turbulence in the liquid phase has been modeled using the standard $textsc{k}$-$\varepsilon$ turbulence model. The interphase friction coefficient has been calculated using correlations available in the literature. The turbulent dispersion of the phase has been modeled by the "dispersion Prand시 number". The predicted mean flows is compared well with the experimental data. The plume region area and the axial velocities are increased with the gas flow rate and with the decrease in the inlet area. The turbulent intensity also shows the same trend. Also, the space-averaged turbulent kinetic energy for various gas flow rates and inlet areas has been obtained. The results are of interest in the design and operation of a wide variety of materials and chemical processing operations.

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Rapid Gas Chromatographic Screening of Saliva Samples for Organic Acids (기체크로마토그래피법에 의한 타액내 유기산의 신속한 스크리닝)

  • 김경례;김정한;박영준;김정옥
    • YAKHAK HOEJI
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    • v.39 no.3
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    • pp.283-288
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    • 1995
  • Rapid gas chromatographic profiling method was applied to saliva from healthy subjects for the analysis of free organic acids. Saliva samples were first saturated with NaHCO$_{3}$ and extracted with diethyl ether. The aqueous phase was solid-phase extracted using Chromosorb P as the adsorbent and diethyl ether as the eluent after the acidification and NaCl saturation, followed by triethylamine treatment. The resulting tiiethylammonium salts of acids were directly converted into stable tert.-butyl-dimethylsflyl derivatives, with subsequent analysis by dual-capiuary column gas chromatography and gas chromatograpy -mass spectrometry. From the ten saliva samples studied, twenty eight free organic acids including various fatty acids, hydroxy acids, dicarboxylic acids, md aromatic acids were tentatively identified. Among the acids identified , the concentration of lactic acid was highest for five saliva samples while $\alpha$-hydroxyisocaproic acid was most abundant for me sample, and succinic acid and glycolic acid for two samples. respectively. When the GC profiles were simplified to the corresponding acid retention index spectra of bar graphical form, they presented characteristic patterns for each individual.

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Characterization of Gas Phase Etching Process of SiO2 with HF/NH3

  • Kim, Donghee;Park, Heejun;Park, Sohyeon;Lee, Siwon;Kim, Yejin;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.45-50
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    • 2022
  • The etching with high selectivity of silicon dioxide over silicon nitride is essential in semiconductor fabrication, and gas phase etch (GPE) can increase the competitiveness of the selective dielectric etch. In this work, GPE of plasma enhanced chemical vapor deposited SiO2 was performed, and the effects of process parameters, such as temperature, partial pressure ratio, and gas supply cycle, are investigated in terms of etch rate and within wafer uniformity. Employing multiple regression analysis, the importance of each parameter elements is analyzed.

Computations of Compressible Two-phase Flow using Accurate and Efficient Numerical Schemes

  • Kim, Chong-Am
    • 한국전산유체공학회:학술대회논문집
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    • 2006.10a
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    • pp.13-17
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    • 2006
  • RoeM and AUSMPW+ schemes are two of the most accurate and efficient schemes which are recently developed for the analysis of single phase gas dynamics. In this paper, we developed two-phase versions of these schemes for the analysis of gas-liquid large density ratio two-phase flow. We adopt homogeneous equilibrium model (HEM) using mass fraction to describe different two phases. In the Eulerian-Eulerian framework, HEM assumes dynamic and thermal equilibrium of the two phases in the same computational mesh. From the mixture equation of state (EOS), we derived new shock-discontinuity sensing term (SDST), which is commonly used in RoeM and AUSMPW+ for the stable numerical flux calculation. The proposed two-phase versions of RoeM and AUSMPW+ schemes are applied on several air-water two-phase test problems. In spite of the large discrepancy of material properties such as density, enthalpy, and speed of sound, the numerical results show that both schemes provide very satisfactory solutions.

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Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Conformational Preferences of Glycerol in the Gas Phase and in Water

  • Jeong, Keun-Hong;Byun, Byung-Jin;Kang, Young-Kee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.917-924
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    • 2012
  • The conformational study of glycerol has been carried out using the M06-2X/cc-pVTZ level of theory in the gas phase and the SMD M06-2X/cc-pVTZ level of theory in water in order to understand its conformational preferences and solvation effects. Most of the preferred conformers of glycerol have two $C_5$ hydrogen bonds in the gas phase, as found by the analysis of calorimetric data. It has been known that the solvation drove the hydrogen bonds of glycerol to be weaker and its potential surface to be fatter and that glycerol exists as an ensemble of many feasible local minima in water. The calculated populations of glycerol in the gas phase and in water are consistent with the observed values, which are better than the previously calculated ones at the G2(MP2), CBS-QB3, and SM5.42 HF/6-31G(d) levels of theory.

Particulate Two-Phase Flow Analysis for Fouling Prediction(I)-Design of Hot Wind Tunnel and Its Performance Experiment- (파울링 예측을 위한 가스-입자 이상 유동 해석(1)-고온 풍동 설계 및 성능실험-)

  • Ha, Man-Yeong;Lee, Dae-Rae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.11
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    • pp.3695-3705
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    • 1996
  • We designed the hot wind tunnel to reproduce the conditions of utility boiler and carried out its performance test, in order to investigate the particulate two-phase flow behaviour, the fouling and heat transfer characteristics to the heat exchanger. The hot wind tunnel introduces the control system to control the temperature in the test section. The particle is injected into the hot gas stream. The fouling probe (cylindrical tube) is positioned normal to the particulate gas-particle two-phase flow and cooled by the air. The temperature of gas and cooling air, and temperature in the fouling probe are measured as a function of time, giving the local and averaged heat transfer and fouling factor. The shape of particulate deposition adhered to the fouling probe is also observed.

Three-dimensional Analysis for Three-phase Spacers in Gas Insulated System (3차원 전계해석 기법을 이용한 GIS 삼상 일괄형 스페이서 고찰)

  • Kang, J.S.;Lee, B.W.;Kang, S.M.;Oh, I.S.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1620-1622
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    • 2003
  • Recently, as the technology for the development of high voltage power apparatus using SF6 gas has made remarkable progress, it became possible to develop more compact power apparatus adopting single body substation system. In these gas insulated power apparatus, it is impossible to achieve perfect and safe insulation using only SF6 gas, because some solid insulation parts should be installed to support current-carrying conductor parts for electrical and mechanical safety. When spacers were installed in SF6 gas insulation system, they were exposed to severe electrical intensification which could reduce system insulation performance and restrict the rated operating voltage So, it is necessary to clarify the dielectric characteristics of spacers by analytically and experimentally, in order to design and develop more compact and optimum gas insulated systems. In this paper, the field distribution of three-phase spacers were investigated using three dimensional electrostatic field analysis tool adopting BEM method. And the obtained results were compared to the conventional two dimensional computations. According to these three dimensional calculations, it was possible to find out weak points in the spacer more clearly and these results could be applied to design more compact and optimum three phase spacer developments.

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Complex Analyses for Gas Hydrate Seismic Reflection Data (가스하이드레이트 탄성파 자료의 복소분석)

  • Hien, D.H.;Jang, Seong-Hyung;Kim, Young-Wan;Suh, Sang-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.208-212
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    • 2008
  • Gas hydrate has been paid attention to study for because: 1) it can be considered as a new energy resources; 2) one of reasons causing the instability of sea floor slope and 3) a factor to the climate change. Bottom simulating reflector (BSR) defined as seismic boundary between the gas hydrate and free gas zone has been considered as the most common evidence in the seismic reflection data for the gas hydrate exploration. BSR has several characteristics such as parallel to the sea bottom, high amplitude, reducing interval velocity between above and below BSR and reversing phase to the sea bottom. Moreover, instantaneous attribute properties such as amplitude envelop, instantaneous frequency, phase and first derivative of amplitude of seismic data from the complex analysis could be used to analyze properties of BSR those would be added to the certain properties of BSR in order to effectively find out the existence of BSR of the gas hydrate stability zone. The output of conventional seismic data processing for gas hydrate data set in Ulleung basin in the East sea of Korea will be used for complex analyses to indicate better BSR in the seismic reflection data. This result of this analysis implies that the BSR of the analyzed seismic profile is clearly located at the two ways time (TWT) of around 3.1 seconds.

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A Study on Kinetics in One-Phase Anaerobic Digestion (단상 혐기성 소화공정에서의 동력학적 연구)

  • 조관형;조영태
    • Journal of Environmental Science International
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    • v.9 no.1
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    • pp.75-80
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    • 2000
  • Kinetic data for the acid phase anaerobic digestion were presented in this study and the constants were determined with acid production rate and gas production rate. Process models based on continuous culture theory were used to describe the characteristics of the acid forming microorganisms and to enable further development toward utilization of the process in a more rational manner. Acid phase digestion can be separated with appropriate manipulation of hydraulic retention time in anaerobic digestion. Kinetic analysis of data from the various hydraulic retention times using a phase specific model obtained form the acid phase indicated maximum specific growth rate of 0.40/h, saturation constant of 2,000mgCOD.$\ell$, yield coefficient of 0.35 mgVSS/msCOD utilized and decay constant of 0.04/h for the acid production rate. Similar analysis of data for the gas production rate indicated maximum specific growth rate of 0.003/h, saturation constant of 2,200mgCOD/$\ell$, yield coefficient of 0.035 mgVSS/mgCOD utilized and decay constant of 0.06/h.

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