• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.76.2-76.2
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• 2010

The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

• 마이크로전자및패키징학회지
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• 제11권4호
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• pp.29-35
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• 2004

암모니아 펄스플라즈마를 이용하여 $WF_6$ 가스와 $NH_3$ 가스를 교대로 흘려줌으로써 Si 기판위에 질화텅스텐 확산방지막을 증착하였다. $WF_6$ 가스는 Si과 반응하여 표면침식이 과도히 발생하였으나 암모니아 ($NH_3$)가스를 펄스 플라즈마를 인가하여 $WF_6$와 같이 사용하면 Si 표면을 질화처리 함으로써 표면침식을 막아주며 질화텅스텐 박막을 쉽게 증착할 수 있었다. 그 이유는 암모니아 가스의 분해를 통한 Si 기판의 흡착을 용이하게 하여 질화텅스텐 박막 증착이 가능하기 때문이다. 이러한 증착 미케니즘과 암모니아 펄스 플라즈마 효과에 대하여 조사하였다.

• Korean Chemical Engineering Research
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• 제50권3호
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• pp.556-561
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• 2012

본 연구에서는 고분자형 연료전지(PEMFC) 내의 기체확산층(GDL)에서의 물질 거동 전산해석을 통하여 GDL 물성이 전지성능에 미치는 영향을 알아보았다. GDL 내에서 기상의 산소와 액상의 물의 거동을 계산하기 위하여 multi-phase mixture($M^2$) 모델을 사용하였다. GDL의 접촉각, 기공도, 기체투과도, 두께에 변화를 주며 계산을 실시하여 GDL 내에서의 물질 거동의 변화를 확인 하였고, GDL 물성이 전지성능에 미치는 영향을 파악하였다. 전산해석 결과, GDL의 접촉각과 기공도가 커지고, 두께가 얇아짐에 따라 물질전달 저항이 감소하여 GDL과 촉매층 사이의 계면에서의 물포화도가 낮아지고 산소농도는 증가하여 전지성능이 향상되는 것을 확인하였다.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권2호
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• pp.55-58
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• 2003

This paper examines the electrical characteristic of single oxide layer due to various diffusion conditions, substrate orientations, substrate resistivity and gas atmosphere in a diffusion furnace. The oxide quality was examined through the capacitance-voltage characteristic due to the annealing time after oxidation process, and the capacitance-voltage characteristics of the single oxide layer by will be described via semiconductor device simulation.

• 오토저널
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• 제4권2호
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• pp.35-46
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• 1982

This paper deals with residual stress characteristics of ion-nitrided metal which is primarilly concerned with the effects of added carbon content in gas atmosphere. A small optimal amount of carbon content in gas atmosphere increase compound layer thickness, as well as to increase diffusion layer thickness and hardness. The residual stress and deflection of the specimens was measured in various elevated temperature at the surface of ion-nitrided metal and the internal stress distribution was calculated. It is found that compressive residual stress at the compound layer is largest at the compound layer, and decreases as the depth from the surface increases.

• 한국재료학회지
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• 제12권6호
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• pp.447-451
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• 2002

Pulsed DC-plasma nitriding has been applied to form nitride layer having only a diffusion layer. The discharge current with the variation of discharge gases is proportional to the intensity of $N_2^+$ peak in optical emission spectroscopy during the plasma nitriding. The discharge current, microhardness in surface of substrate and depth of nitride layer increased with the ratio of $N_2\;to\;H_2$ gas in discharge gases. When the ratio of $N_2\;to\;H_2$ is lower than 60% in the discharge gases, high microhardness value of 1100Hv nitride layer which contains no compound layer has been formed.

• 한국전산유체공학회지
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• 제6권4호
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• pp.15-25
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• 2001

Numerical prediction of the diffusion controlled transition in a turbine gas pass is important because it can change the local heat transfer rate over a turbine blade as much as three times. In this study, the gas flow over turbine blade is simplified to the flat plate boundary layer, and an adaptive grid scheme redistributing grid points within the computation domain is proposed with a great emphasis on the construction of the grid control function. The function is sensitized to the second invariant of the mean strain tensor, its spatial gradient, and the interaction of pressure gradient and flow deformation. The transition process is assumed to be described with a κ-ε turbulence model. An elliptic solver is employed to integrate governing equations. Numerical results show that the proposed adaptive grid scheme is very effective in obtaining grid independent numerical solution with a very low grid number. It is expected that present scheme is helpful in predicting actual flow within a turbine to improve computation efficiency.

• 전기전자학회논문지
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• 제23권3호
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• pp.793-799
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• 2019

본 연구에서는 웨어러블 Fabric(Nylon) + MWCNT 가스센서 내부에서 열확산을 해석하기 위해서 요소해석 프로그램(comsol)을 이용하여 센서 내부에서의 열용량의 확산 과정과 열용량 분포 경도를 확인하였다. 열용량의 확산과정을 해석하기 위해서 가스센서의 구조체에 대하여 이차원으로 모델링을 진행하였으며, 제시된 모델링에 대해서 센서 구성 부분에 대한 특성값을 제시하여 메시 요소법(FEM)을 이용하여 설계된 웨어러블 가스센서에 대해서 열용량이 확산되는 정도와 열용량 경도를 구하기 위해서 지배방정식으로 1계 편미분방정식을 제안하여 해석하였으며, 열속도 전달식을 제안하여 전극층과 가스 검출부의 10[K/mm] 온도 경도를 구하였다.

• 열처리공학회지
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• 제1권1호
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• pp.8-12
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• 1988

This study has been carried out to evaluate gaseous nitrocarburizing treatment undertaken for pure iron at $570^{\circ}C$ in an atmosphere containing 50% endothermic gas, generated from natural gas, and 50% ammonia. The results obtained from the experiment are as follows ; 1) The microstructure of gaseous nitrocarburized pure iron consists of the compound layer on the surface and the diffusion zone beneath it. The compound layer progresses uniformly into ferrite with a thickness of $20{\mu}$ obtained after treating for 3 hours. 2) Chemical analysis has shown that the compound layer has a C/N ratio of 0.19 and that the average combined interstitial content of the compound layer is about 30 atomic percent, which is close to the lower limit of the ${\varepsilon}$-carbonitride phase field in Fe-C-N phase diagram. 3) X-ray diffraction analysis has revealed that the compound layer consists mainly of the c.p.h. phase, ${\varepsilon}-Fe_3$(C.N) and a small amount of $Fe_4N$ and traces of ferrite are also present in the compound layer. 4) The microhardness of the compound layer is about 600 V.H.N and shows a relatively sharp fall-off at the compound layer/diffusion zome interface. 5) The average actual degree of ammonia dissociation is calculated to be 27% for a gaseous nitrocarburizing treatment carried out at $570^{\circ}C$.

• Tribology and Lubricants
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• 제13권2호
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• pp.96-104
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• 1997

This paper was focused on the wear characteristics of ion-nitrided metal and with ion-nitride processing, which is basically concerned with the effects of carbon content in workpiece and added carbon content gas atmosphere on the best wear performance. Increased carbon content in workpiece increases compound layer thickness, but decreases diffusion layer thickness. On the other hand, a small optimal amount of carbon content in gas atmosphere increase compound layer thickness as well as diffusion layer thickness and hardness. Wear tests show that the compound layer of ion-nitrided metal reduces wear rate when the applied wear load is small. However, as the load becomes large, the existence of compound layer tends to increase wear rate. Compressive residual stress at the compound layer is the largest at the compound layer, and decreases as the depth from the surface increases. It is found in the analysis that under small applied load, the critical depth where voids and cracks may be created and propagated is located at the compound layer, so that the adhesive wear is created and the existence of compound layer reduces the amount of wear. When the load becomes large, the critical depth is located below the compound layer and delamination, which may explained by surface deformation, crack nucleation and propagation, is created and the existence of compound layer increases wear rate. For the compound layer, at added carbon contents of 0 percent and 0.5 at. percent, the $\varepsilon$ monophase is predominant. But at 0.7 at. percent added carbon, the $\varepsilon$ monophase formation tends to be severely inhibited and r' and $Fe_3C$ polyphase formation becomes dominant. This increased hard $\varepsilon$ phase layer was observed to be more beneficial in reducing friction and wear.