• Title/Summary/Keyword: Functional matrix

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Preparation and Characterization of Polyimide/Carbon-Nanotube Composites

  • Kim, Bong-Sup;Bae, Sang-Hoon;Park, Young-Hwan;Kim, Ji-Heung
    • Macromolecular Research
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    • v.15 no.4
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    • pp.357-362
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    • 2007
  • Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.

Tailoring and Control of The Micro (Nano) Structure of Functional CMSs and MMCs

  • Colomban
    • The Korean Journal of Ceramics
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    • v.5 no.1
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    • pp.55-72
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    • 1999
  • A cheallenge in the aerospace field is to design new composites satisfying specific and sometimes conflicting properties. The key steps are ⅰ)the understanding and the control of the reaction between the reinforcement and the embedding matrix, ⅱ) the achievement of a coherent and robust matrix. The problems encountered to prepare particulate, 1D, 2D and 3D reinforced composites using polymeric are discussed. Emphasis is given to the control of the micro/nanostructure using Raman microspectrometry and depth-sensing microindentation, in order to get information on the micromechanics and fiber structure simultaneously, within ceramic (CMC's) and metal matrix (MMC's) composites.

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Application of Stiffness Matrix Element for Finite Element Analysis of Spine (척추의 유한 요소 해석을 위한 강성 행렬 요소의 적용)

  • 정일섭;안면환
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.10
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    • pp.226-232
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    • 2003
  • Difficulties in the finite element modeling of human spine are evaded by using a stiffness matrix element whose properties can be characterized from experimentally measured stiffness of functional spinal units. Relative easiness is in that inter-vertebral discs, ligaments, and soft tissues connecting vertebrae do not need to be modeled as they are. The remarkable coupling effect between distinct degrees of freedom induced by the geometric complexity can be accommodated without much effort. An idealized block model with simple geometry for vertebra is employed to assess the feasibility of this method. Analyses are performed in both levels of motion segment and spinal column, and the result is compared with that from detail model. As far as the global behavior of spine is concerned, the simplification is found not to aggravate inaccuracy only if sufficient experimental data is provided and interpreted properly.

Conservation of matrix protein genes in rabies viruses circulating in South Korea since 1999

  • Lee, Young-Ae;Kim, Ha-Hyun;Yang, Dong-Kun;Cho, In-Soo
    • Korean Journal of Veterinary Research
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    • v.57 no.4
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    • pp.249-252
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    • 2017
  • Rabies virus (RABV) causes a neurological disease in warm-blooded animals that is nearly always fatal. In this study, we analyzed the matrix (M) genes in 10 Korean street RABV strains isolated from two Provinces during 2011-2013. The M genes in these 10 Korean strains were highly conserved during 1999-2013. Phylogenetic analysis revealed they were closely related to the M genes of RABVs isolated in northeastern China. Specific amino acid substitutions were identified in the KRVB1206, KRVF1301, and BV9901PJ strains. However, functional domains, including those involved in virus production and pathogenicity, were conserved in all 10 strains.

Observation of Elusive CF2Cl…Cl in Matrix Infrared Spectra and Density Functional Calculations

  • Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3274-3278
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    • 2013
  • $CF_2Cl{\cdots}Cl$, an elusive photo-isomer of $CF_2Cl_2$, has been observed in matrix IR spectra from the precursors exposed to radiation from laser ablation of transition-metals. Other plausible products, $CFCl_2{\cdots}F$ and $FClC{\cdots}F-Cl$ are not detected due to their considerably higher energies. Parallel to its previously reported analogues, the C-X bonds are considerably stronger than those of the reactant, and particularly the Cl atom that is weakly bound to the residual Cl atom forms an unusually strong carbon-halogen bond. NBO analysis reveals that the C-Cl bond is a true double bond, and the weak $Cl{\cdots}Cl$ bond is largely ionic, $F_2C=Cl^{\delta+}{\cdots}Cl^{\delta-}$. IRC computation reproduces smooth inter-conversion between the reactant and product, and the transition state is energetically close to the product, consistent with its prompt disappearance in the early stage of photolysis.

Effect of Temperature on Frequency and Damping Properties of Polymer Matrix Composites

  • Colakoglu, M.
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.111-124
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    • 2008
  • The effect of temperature on natural frequency and damping is investigated in two different composite materials, Kevlar 29 fiber woven and polyethylene cloth, used especially to design ballistic armor. A damping monitoring method is used experimentally to measure the frequency response curve and it is also modeled numerically using a finite element program. The natural frequencies of a material, or a system, are a function of its elastic properties, dimensions and mass. This concept is used to calculate theoretical vibration modes of the composites. The damping properties in terms of the damping factor are determined by the half-power bandwidth technique. Numerically analyzed and experimentally measured time response curves are compared. It is seen that polymer matrix composites have temperature dependent mechanical properties. This relationship is functional and they have different effects against temperature.

Matrix Infrared Spectra and DFT Computations of CH2CNH and CH2NCH Produced from CH3CN by Laser-Ablation Plume Radiation

  • Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1361-1365
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    • 2013
  • The smallest ketenimine and hydrogen cyanide N-methylide ($CH_2CNH$ and $CH_2NCH$) are provided from the argon/acetonitrile matrix samples exposed to radiation from laser ablation of transition-metals. New infrared bands are observed in addition to better determination of the vibrational characteristics for the previously reported bands, and the $^{13}C$ substituted isotopomers ($^{13}{CH_2}^{13}CNH$ and $^{13}CH_2N^{13}CH$) are also generated. Density functional frequency calculations and the D and $^{13}C$ isotopic shifts substantiate the vibrational assignments. $CH_2CNH$ is probably produced through single-step conversion of $CH_3CN$, whereas $CH_2NCH$ through two-step conversion via 2H-azirine. Inter-conversions between these two products evidently do not occur during photolysis and annealing.

Axiomatic Approach for desing Appraisement and Development DVD (II) (DVD 설계평가 및 개선을 위한 공리적 접근 (II))

  • Moon, Yong-Rak;Cha, Sung-Woon;Heo, Bo-Seog
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.9
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    • pp.82-88
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    • 1999
  • In order to execute the major role as the high density large capacity data storage device, which is one of the major characteristics of DVD(Digital Versatile Disk), there must be a method to effectively absorb the external impact or internal vibration. The DVD which has been developed until now tries to control two different types of vibrations, using only one absorber. But this goes against the independence Axiom of Axiomatic Approach which makes the design to be coupled. And in fat most of the malfunctions occurring during DVD data input/output is due to impact or vibration. Therefore in this paper, the vibration absorption system and operation reliability of DVD will be evaluated with the Axiomatic Approach and plans and feasibility to design an improved vibration absorption system will be provided also based on the Axiomatic Approach.

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Functional Polymeric Materials for Biomedical Application (생체의료용 기능성 고분자 재료의 개발)

  • Sung, Yong-Kiel;Song, Dae-Kyung;Sung, Jung-Suk
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.1-9
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    • 2006
  • The development of functional polymeric materials for biomedical application has progressed on the basis of functionality, biocompatibility and biodegradability. In this paper we review the functional polymeric biomaterialsbased systems and propose a range of biomedical applications in the near future. These systems include the functional biodegradable polymers synthesized in our research laboratory, biodegradable polymeric materials, thermosensitive polymeric materials, cationic polymeric materials, non-condensing polymeric biomaterials, bio-polymeric DNA matrix for tissue engineering, and polymeric biomaterials for RNA interference (RNAi) technology.

Korean native wild herbal-based functional ingredient for skin health: Agatri® (Agastache rugosa extract) (피부 건강을 위한 국내 자생 천연 식물 원료: Agatri® (배초향 추출물))

  • Kim, Sang Woo
    • Food Science and Industry
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    • v.53 no.4
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    • pp.382-389
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    • 2020
  • "Eating cosmetic" market comes to prominence worldwide. Inner Beauty has established itself as the top trend nowadays and is leading the health functional food market. Another noticeable trend other than beauty-from-within is that products using "plant-based" natural botanical raw material are increasing. Based on these trends above, we have developed a plant extract named Agatri® for skin health using Agastache rugosa. By ingesting Agatri®, it is expected that the formation of skin wrinkles is suppressed, and skin elasticity is increased by suppressing the decrease in collagen content caused by ultraviolet rays. At the same time, it is possible to prevent skin aging by improving skin hydration and trans-epidermal water loss (TEWL). The studies show that it significantly increased production of hyaluronic acid and collagen, and decreased production of matrix metalloproteinases (MMPs). And Agatri® has been approved as an "Individually recognized functional ingredient for skin health by the Ministry of Food and Drug Safety, Korea in 2020. As a result, Agatri® is a good solution for those who are in need of skin protection from exposure to UV and aging.