• 한국연소학회지
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• 제15권3호
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• pp.8-14
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• 2010

Fuel processing systems which convert fuel into rich gas (such as stream reforming, partial oxidation, autothermal reforming) need high temperature environment ($600{\sim}1,000^{\circ}$). Generally, anode-off gas or mixture of anode-off gas and LNG is used as input gas of fuel reformer. In order to make efficient and low emission burner system for fuel reformer, it is necessary to elucidate the combustion and emission characteristic of fuel reformer burner. The purpose of this study is to develop a porous premixed flat ceramic burner that can be used for 1~5 kW fuel cell reformer. Ceramic burner experiments using natural gas, hydrogen gas, anode off gas, mixture of natural gas & anode off gas were carried out respectively to investigate the flame characteristics by heating capacity and equivalence ratio. Results show that the stable flat flames can be established for natural gas, hydrogen gas, anode off gas and mixture of natural gas & anode off gas as reformer fuel in the porous ceramic burner. For all of fuels, their burning velocities become smaller as the equivalence ratio goes to the lean mixture ratio, and a lift-off occurs at lean limit. Flame length in hydrogen and anode off gas became longer with increasing the heat capacity. In particular, the blue surface flame is found to be very stable at a very lean equivalence ratio at heat capacity and different fuels. The exhausted NOx and CO measurement shows that the blue surface flame represents the lowest NOx and CO emissions since it remains very stable at a lean equivalence ratio.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2181-2185
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• 2008

Fuel processing systems which convert HC fuel into $H_2$ rich gas (such as stream reforming, partial oxidation, auto-thermal reforming) need high temperature environment($600-1000^{\circ}C$). Generally, anode-off gas or mixture of anode-off gas and LNG is used as input gas of fuel reformer. In order to make efficient and low emission burner system for fuel reformer, it is necessary to elucidate the combustion and emission characteristic of fuel reformer burner. The purpose of this study is to develop a porous premixed flat ceramic burner that can be used for 1-5kW fuel cell reformer. Ceramic burner experiments using natural gas, hydrogen gas, anode off gas were carried out respectively to investigate the flame characteristics by heating capacity and equivalence ratio. Results show that the stable flat flames can be established for natural gas, hydrogen gas, anode off gas and mixture of natural & anode off gas as reformer fuel. For all of fuels, their burning velocities become smaller as the equivalence ratio goes to the lean mixture ratio, and a lift-off occurs at lean limit. Flame length in hydrogen and anode off gas became longer with increasing the heat capacity.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.129-136
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• 2017

Characteristics of $ZrO_2$ felt supported Cu/Zn catalysts have been investigated for the production of hydrogen via methanol steam reforming. Cu and Zn in different weight percent were loaded using wet impregnation over $ZrO_2$ felt support. The catalysts were characterized with BET and FE-SEM. The performance of these synthesized catalysts were investigated at SCR=1.5, $GHSV=2000h^{-1}$, temperature=$300{\sim}400^{\circ}C$, and pressure=2.5~19.5 barA. The results showed that the $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst was most active in terms of methanol conversion and hydrogen production. The methanol conversion in steam reforming of methanol was 84.6% at 19.5 barA and furnace $400^{\circ}C$ over $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst. The catalysts prepared using $ZrO_2$ felt show higher reactor temperature than the pellet type catalyst at same furnace temperature.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.601-607
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• 2019

Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

• 한국수소및신에너지학회논문집
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• 제32권3호
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• pp.149-155
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• 2021

Most of the reformer experiments have been conducted only in high-temperature operation conditions above 700℃. However, to design high efficiency solid oxide fuel cell, it is necessary to test actual reaction performance in mid-temperature (550℃) operation areas. In order to study the operation characteristics and performance of commercial reforming catalysts, a reforming performance experiment was conducted on mid-temperature. The catalysts used in this study are Ni-based FCR-4 and Ru-based RuA, RuAL. Experiments were conducted with a Steam-to-carbon ratio of 2.0 to 3.0 under gas hourly space velocity (GHSV) 2,000 to 5,000 hr-1. As a result, RuA and RuAL catalysts showed similar gas composition to the equilibrium regardless of the reforming temperature. However, the FCR-4 catalyst showed a lower hydrogen yield compared to the equilibrium under high GHSV conditions.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.267-270
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• 2014

Since contaminants of syngas obtained from the biomass gasification are removed, the syngas is clean fuel. In this study a high-efficiency energy production system is developed. The system produces electricity using a waste pressure and feeds a low-pressure steam to Dyeing industrial complex. Also, iron oxide derived from dyeing sludge is utilized as a self-catalyst to reform a tar and reduce a tar emission from gasifier. This system increases the amount of syngas and finally achieves a highly efficient gasification.

• 한국세라믹학회지
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• 제47권1호
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• pp.66-70
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• 2010

This article presents a brief review of our recent studies on flowerlike nanostructured $CeO_2$ materials. These materials are monodispersed microspheres with peony appearance, open mesoporous structure, large specific surface area and nano-crystalline feature. The applications of this type of novel material to SOFC, ethanol steam reforming and CO oxidation are introduced.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.105-113
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• 2014

Performance tests on $Ni/Ce-ZrO_2/Al_2O_3$ catalysts with additives (MgO, $La_2O_3$) were investigated in the combined reforming processes (SCR, ATR, TRM) in order to produce hydrogen and carbon monoxide (it is called "syngas".). The catalyst characterization was conducted using the BET surface analyzer, X-ray diffraction (XRD), SEM, TPR and TGA. The combined reforming process was developed to adjust the syngas ratio depending on the synthetic fuel (methanol, DME and GTL) manufacturing processes. Ni-based catalysts supported on alumina has been generally recommended as a combined reforming reaction catalyst. It was found that both free NiO and complexed NiO species were responsible for the catalytic activity in the combined reforming of methane conversion, and the $Ce-ZrO_2$ binary support employed had improved the oxygen storage capacity and thermal stability. The additives, MgO and $La_2O_3$, also seemed to play an important role to prevent the formation of the carbon deposition over the catalysts. The experimental results were compared with the equilibrium data using a commercial simulation tool (PRO/II).

• 한국수소및신에너지학회논문집
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• 제29권6호
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• pp.559-569
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• 2018

Catalytic supports made of carbon have many advantages, such as high coking resistance, tailorable pore and surface structures, and ease of recycling of waste catalysts. Moreover, they do not require pre-reduction. In this study, ash-free coal (AFC) was obtained by the thermal extraction of carbonaceous components from raw coal and its performance as a carbon catalytic support was compared with that of well-known activated carbon (AC). Nickel was dispersed on the carbon supports and the resulting catalysts were applied to the steam reforming of toluene (SRT), a model compound of biomass tar. Interestingly, nickel catalysts dispersed on AFC, which has a very small surface area (${\sim}0.13m^2/g$), showed higher activity than those dispersed on AC, which has a large surface area ($1,173A/cm^2$). X-ray diffraction (XRD) analysis showed that the particle size of nickel deposited on AFC was smaller than that deposited on AC, with the average values on AFC ${\approx}11nm$ and on AC ${\approx}23nm$. This proved that heteroatomic functional groups in AFC, such as carboxyls, can provide ion-exchange or adsorption sites for the nano-scale dispersion of nickel. In addition, the pore structure, surface morphology, chemical composition, and chemical state of the prepared catalysts were analyzed using Brunauer-Emmett-Taylor (BET) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and temperature-programmed reduction (TPR).

• 에너지공학
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• 제20권4호
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• pp.298-302
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• 2011

In this study, Catalytic reforming with vapor and biomass gasification was simultaneously performed in a same fixed bed reactor at $600-800^{\circ}C$. Light gases were produced from reformation of the tar (fuel gases) in biomass gasification by using limonite and dolomite, as catalysts. Hydrogen and carbon dioxide are main components in light gases. Hydrogen yields increased with temperature increasing in the range of $650-800^{\circ}C$, because the water shift reaction was promoted by catalyst. The yield of hydrogen gas was increased about 160% under catalyst with the mixture of limonite and dolomite comparing to limonite only.