• Transactions on Electrical and Electronic Materials
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• 제16권4호
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• pp.194-197
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• 2015

La_9.33(Si₅V₁)O₂₆ ceramics were fabricated by the mixed oxide method for solid oxide electrolytes. La_9.33(Si₅V₁)O₂₆ specimens showed the hexagonal, space group P63 or P63/m, and the unit cell volume increased when the sintering temperature increased. The specimen sintered at 1,400℃ showed the X-ray patterns of the homogeneous apatite single phase without the second phase, such as La₂SiO₅ and SiO₂. The specimen sintered at 1,400℃ showed the maximum sintered density of 4.93 g/cm³. When the sintering temperature increased, the electrical conductivities increased, the activation energy decreased and the values were 7.83×10⁻⁴ S/cm, 1.61 eV at 600℃, respectively.

• Nuclear Engineering and Technology
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• 제48권5호
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• pp.1140-1153
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• 2016

Since the inception of nuclear power as a commercial energy source, safety has been recognized as a prime consideration in the design, construction, operation, maintenance, and decommissioning of nuclear power plants. The release of radioactivity to the environment requires the failure of multiple safety systems and the breach of three physical barriers: fuel cladding, the reactor cooling system, and containment. In this study, nuclear reactor containment pressurization has been modeled in a large break-loss of coolant accident (LB-LOCA) by programming single-cell and multicell models in MATLAB. First, containment has been considered as a control volume (single-cell model). In addition, spray operation has been added to this model. In the second step, the single-cell model has been developed into a multicell model to consider the effects of the nodalization and spatial location of cells in the containment pressurization in comparison with the single-cell model. In the third step, the accident has been simulated using the CONTAIN 2.0 code. Finally, Bushehr nuclear power plant (BNPP) containment has been considered as a case study. The results of BNPP containment pressurization due to LB-LOCA have been compared between models, final safety analysis report, and CONTAIN code's results.

• 대한안전경영과학회지
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• 제16권4호
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• pp.159-165
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• 2014

For the hydrogen economy system being tried starting with the 21st century, the fields that was not dealt with so far, such as the safety measure for large leakage accidents, the safety problem at infrastructures like a hydrogen station, the safety problem in terms of automobiles depending on introduction of hydrogen cars, the safety problem in a supply for homes like fuel cells, etc., are being deeply reviewed. In order to establish a safety control system, an essential prerequisite in using and commercializing hydrogen gas as an efficient energy source, it is necessary to conduct an analysis, such as analysis of hydrogen accident examples, clarification of physical mechanisms, qualitative and quantitative evaluation of safety, development of accident interception technologies, etc. This study prepared scenarios of hydrogen gas leakage that can happen at hydrogen stations, and predicted damage when hydrogen leaks by using PHAST for this.

• Korean Membrane Journal
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• 제10권1호
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• pp.20-25
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• 2008

Proton conducting composite membranes were prepared by solution blending of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(sulfopropyl methacrylate) (P(VDF-CTFE)-g-PSPMA) graft copolymer and heteropolyacid (HPA). The P(VDF-CTFE)-g-PSPMA graft copolymer was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of P(VDF-CTFE). FT-IR spectroscopy revealed that HPA nanoparticles were incorporated into the graft copolymer via hydrogen bonding interactions. The water uptake of membranes continuously decreased with increasing HP A concentration up to 45wt%, after which it slightly increased. It is presumably due to the decrease in number of water absorption sites due to hydrogen bonding interaction between the HP A particles and the polymer matrix. The proton conductivity of membranes increased with increasing HPA concentration up to 45wt%, resulting from both the intrinsic conductivity of HP A particles and the enhanced acidity of the sulfonic acid of the graft copolymer.

• Journal of Electrochemical Science and Technology
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• 제7권4호
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• pp.277-285
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• 2016

There is a growing demand for simple, cost-effective, and accurate analytical tools to determine the concentrations of biological and environmental compounds. In this study, a stable electroactive thin film of cobalt hexacyanoferrate (Cohcf) was prepared as an in situ chemical precipitant using electrostatic adsorption of $Co^{2+}$ on a silicate sol-gel matrix (SSG)-modified indium tin oxide electrode pre-adsorbed with $[Fe(CN)_6]^{3-}$ ions. The modified electrode was characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical techniques. Electrocatalytic oxidation of hydrazine on the modified electrode was studied. An electrochemical sensor for hydrazine was constructed on the SSG-Cohcf-modified electrode. The oxidation peak currents showed a linear relationship with the hydrazine concentration. This study provides insight into the in situ growth and stability behavior of Cohcf nanostructures and has implications for the design and development of advanced electrode materials for fuel cells and sensor applications.

• 한국지열·수열에너지학회논문집
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• 제8권2호
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• pp.27-35
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• 2012

Five zero energy house models developed in Korea for the purpose of the energy performance were compared and analyzed in the study. The standard passive house model applying common technology and efficient energy performance elements was proposed. Standard passive house 5 models have been developed commonly aiming at 100% energy saving, applying high-performance and high-efficiency exterior thermal insulation, using 3 low-e coated window system, and targeting average 0.65 ACH to enhance privacy. Energy recovery ventilators and dry and cold radiant heating floor has been partially applied. Eco-design techniques such as the awning device, heat insulating door, using natural light have been used. Solar and geothermal systems as the application of renewable energy technologies have been commonly applied. And fuel cells were applied to a partial model. The standard model based on common technical elements and average performance of each element and obtained from five model analysis has been proposed in the study.

• 한국세라믹학회지
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• 제43권12호
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• pp.798-804
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• 2006

Co-planar type single chamber solid oxide fuel cell with patterned electrode on a surface of electrolyte has been fabricated by robo-dispensing method and microfluidic lithography. The cells were composed of NiO-GDC-Pd or NiO-SDC cermet anode, $(La_{0.7}Sr_{0.3})_{0.95}MnO_3$ cathode, and yttria stablized zirconia electrolyte. The cell performance at $900^{\circ}C$ was investigated as a function of electrode geometries, such as anode-to-cathode distance, numbers of electrode pairs. Relationship between OCV and I-V characteristics at the optimized operation condition was also studied by DC source meter under the mixed gas condition of methane, air, and nitrogen. An increase of anode-facing-cathode area leads to lower OCV due to intermixing between product gases of anode and cathode, which in turn decreases the oxygen partial pressure difference.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.434-441
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• 2018

The pore size of nickel (Ni) bottom electrode layer (BEL) for low-temperature solid oxide fuel cells embedded with ultrathin-film electrolyte was controlled by changing the substrate surface morphology and deposition process parameters. For ~150-nm-thick Ni BEL, the upper side of an anodic aluminum oxide (AAO) substrate with ~65-nm-sized pores provided ~1.7 times smaller pore size than the lower side of the AAO substrate. For ~100-nm-thick Ni BEL, the AAO substrate with ~45-nm-sized pores provided ~2.6 times smaller pore size than the AAO substrate with ~95-nm-sized pores, and the deposition pressure of ~4 mTorr provided ~1.3 times smaller pore size than that of ~48 mTorr. On the AAO substrate with ~65-nm-sized pores, the Ni BEL deposited for 400 seconds had ~2 times smaller pore size than the Ni BEL deposited for 100 seconds.

• 한국추진공학회지
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• 제13권6호
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• pp.56-63
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• 2009

본 논문에서는 PAV 추진기관에 대한 현황 및 전망을 조사하고 검토하였다. 현재의 수송교통 체계가 포화상태로 가고 있기 때문에 그 대안으로 개인용 항공기(PAV, Personal Air Vehicle)의 출현이 강하게 요구되고 있다. 왕복엔진의 경우 효율과 경제적 측면에서 우수하다는 장점을 지니고 있어 큰 출력을 필요로 하지 않는 PAV에 적합하나 소음이 심하다는 단점이 있다. 터보샤프트 엔진은 비추력이 크고 운용범위가 넓어 수직이착륙을 하는 VTOL PAV에 적합하나 가격이 비싸다는 단점이 있다. 최근 전 세계적으로 친환경 시장이 급격히 성장하고 있어 기존 왕복엔진이나 가스터빈엔진 기술의 발전과 더불어서 연료전지와 배터리를 이용하는 친환경적인 추진기관을 선호하는 추세가 높아지고 있다.

• 대한기계학회논문집B
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• 제33권8호
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• pp.604-612
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• 2009

Water management has been recognized as a crucial factor for achieving better performance and stability in polymer electrolyte membrane fuel cells (PEMFCs). Proper water management should provide favorable water conditions, including the local humidity, membrane water content, and liquid water saturation in PEMFCs, thereby leading to more uniform electrochemical reaction and current generation. In this study, computational fluid dynamics (CFD) simulation was conducted to investigate the effects of the cathode relative humidity (RH) on the performance of a 3 by $3\;cm^2$ PEMFC with serpentine flow fields. The CFD results showed that the best performance of the PEMFC was obtained for the cathode RH of 80%, but the performance variation was small for the cathode RH range of $60{\sim}100%$. However, the loss of the PEMFC performance was significant when the cathode RH was reduced below 40%. The reason for such performance variation was investigated through the detailed inspection of ohmic loss, activation and concentration overpotential, and water and current distributions.