Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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An Electrochemical Sensor for Hydrazine Based on In Situ Grown Cobalt Hexacyanoferrate Nanostructured Film

  • Kang, Inhak (Electrochemistry Laboratory for Sensors & Energy (ELSE), Department of Chemistry, Incheon National University) ;
  • Shin, Woo-seung (Electrochemistry Laboratory for Sensors & Energy (ELSE), Department of Chemistry, Incheon National University) ;
  • Manivannan, Shanmugam (Electrochemistry Laboratory for Sensors & Energy (ELSE), Department of Chemistry, Incheon National University) ;
  • Seo, Yeji (Electrochemistry Laboratory for Sensors & Energy (ELSE), Department of Chemistry, Incheon National University) ;
  • Kim, Kyuwon (Electrochemistry Laboratory for Sensors & Energy (ELSE), Department of Chemistry, Incheon National University)
  • Received : 2016.09.23
  • Accepted : 2016.10.10
  • Published : 2016.12.31
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Abstract

There is a growing demand for simple, cost-effective, and accurate analytical tools to determine the concentrations of biological and environmental compounds. In this study, a stable electroactive thin film of cobalt hexacyanoferrate (Cohcf) was prepared as an in situ chemical precipitant using electrostatic adsorption of $Co^{2+}$ on a silicate sol-gel matrix (SSG)-modified indium tin oxide electrode pre-adsorbed with $[Fe(CN)_6]^{3-}$ ions. The modified electrode was characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical techniques. Electrocatalytic oxidation of hydrazine on the modified electrode was studied. An electrochemical sensor for hydrazine was constructed on the SSG-Cohcf-modified electrode. The oxidation peak currents showed a linear relationship with the hydrazine concentration. This study provides insight into the in situ growth and stability behavior of Cohcf nanostructures and has implications for the design and development of advanced electrode materials for fuel cells and sensor applications.

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